PARTS CLEANING TECHNICAL-CONTENT

An Overview of Cemented Carbide Sintering

Source: TAV Vacuum Furnaces

Cemented carbide is often used interchangeably with other terms in the industry to describe a popular material for tool production. However, the specifics of what makes up a cemented carbide, and how this material can be processed, are not so widely discussed.

In this best of the web article, discover the composition, applications, and processes involved in sintering cemented carbide, as well as how vacuum furnaces play an essential role for this material. You will encounter helpful diagrams and resourceful images depicting each step of the process.

An Excerpt:

“Hard metal, or cemented carbide, refers to a class of materials consisting in carbide particles dispersed inside a metal matrix. In most cases, the carbide of choice is tungsten carbide but others carbide forming element can be added, such as tantalum (in the form of TaC) or titanium (in the form of TiC).
The metal matrix, often referred as ‘binder’ (not to be confused with wax and polymers typically used in powder metallurgy) is usually cobalt, but nickel and chromium are also used. This matrix is acting as a ‘cement,’ keeping together the carbide particles (hence the ‘cemented carbide’ definition).”

Read the entire article from TAV Vacuum Furnaces, written by Giorgio Valsecchi, by clicking here: Sintering of Cemented Carbide: A User-Friendly Overview- Pt. 1


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Obliterate Quench Contaminates

OC

Sludge, scale, and dirt are all undesirables in quench oils that can cause detrimental effects during quenching. Bag filtration and centrifuge filtration are put to the test in this investigation. Compare the results before you make your next purchase.

This Technical Tuesday article, written by Greg Steiger, senior account manager, and Michelle Bennett, quality assurance specialist, at Idemitsu Lubricants America, was originally published in November 2023’s Vacuum Heat Treat magazine.


Introduction

The primary role of a quench oil is to dissipate the heat from a quenched load safely, quickly, and uniformly. Both sludge and heat scale have a higher heat transfer coefficient than quench oil and dissipate heat more than this quench medium. This can affect the performance of a quench oil.

To obtain the desired metallurgical results, the operation of a quench system must be both consistent and uniform. The presence of sludge from quench oil oxidation and scale within the quench oil, pump, and heat exchangers can lead to variability in key parameters such as grain size, hardness, case depth and surface finish. The best way to minimize the detrimental effects of sludge and scale is to remove these contaminants by filtration. This article will compare the two most popular types of commercial filtration available for oil quench systems: bag filters vs. centrifuge filtrations.

This article will compare the two most popular types of commercial filtration available for oil quench systems: bag filters vs. centrifuge filtrations.

Test Methods

To simulate a two-stage bag filter, the following lab procedure was followed.

A 300-mL sample of used quench oil was passed through a 75-micron filter paper. The filtrate from the 75-micron filter was then filtered through a 25-micron filter paper. To simulate the pressure typically found in an industrial bag filter, the filtration in both the 75-micron and 25-micron papers was aided by a vacuum pump that pulled used quench oil through the filter paper.

To simulate the effects of centrifugal separation, a benchtop centrifuge was used. A 300-mL sample of used quench oil was placed in a centrifuge tube and centrifuged for 25 minutes at a speed of 3,500 RPM. An additional 300-mL sample was placed in an identical centrifuge tube and centrifuged for 180 minutes at 3,500 RPM as well.

In addition to the lab testing of dirty quench oil samples, we monitored the particle count and pentane insolubles in samples from an in-use heat treating furnace. This study began with charging the furnace with clean quench oil that was filtered using a single stage 25-micron filter and collected after each filtration. At the conclusion of each timed centrifuge session, the filtrate and the centrifuged sample were tested across five tests, see Table 1.

Table 1. Tested parameters after simulated bag or centrifuge filtration (Source:
Idemitsu Lubricants America)
Note on Table 1: Pentane insolubles measure sludge and scale present in the quench oil after the filtration through the barrier filter or after the centrifuge. Millipore testing is a measure of the overall cleanliness of the quench oil after either filtration or centrifuging. Carbon residue testing measures the Conradson carbon in the filtered or centrifuged quench oil and is designed to determine if any of the quench speed improver additive in the quench oil has been removed via filtration or centrifuging. By measuring the total acid number (TAN) of the quench oil, it is possible to determine if the quench oil is becoming oxidized and beginning to create unwanted sludge. The ISO Particle Count tests for solids contamination, providing a quantitative value for the number of particles that are larger than 4 μm, 6 μm, and 14 μm.

Filtration Results

Because industrial quench oil filters are under a slight pressure, it would be very difficult to replicate this in a laboratory setting. To simulate the slight pressure found in industrial oil filters, we used a Buchner funnel connected to a vacuum pump to simulate the industrial pressure vessel. A similar setup is depicted in Figure 1.

Figure 1. Buchner funnel and laboratory vacuum pump (Source: Idemitsu Lubricants America)

The results post-filtration are depicted in Table 2 and Table 3.

Table 2. Tested parameters after filtering 300 mL of quench oil through 75-micron filter
(Source: Idemitsu Lubricants America)
Table 3. Tested parameters after filtering 300 mL of quench oil through 25-micron filter
(Source: Idemitsu Lubricants America)

Another popular method of filtration in a heat treating facility is through a centrifuge. While it is impractical to use a full-size industrial centrifuge in a lab, the same results can be achieved through the use of a smaller sample size and a benchtop centrifuge. A benchtop centrifuge similar to the one seen in Figure 2 was used to produce the results in Tables 4 and 5 (below).

Figure 2. Benchtop centrifuge (Source: Idemitsu Lubricants America)

Understanding the Test Methods: Bag/Barrier Filtration

Figure 3. Polyethylene felt filter bag and filter canister (Source: SBS Corporation)

Bag (or barrier) filtration is the most common type of filtration used in quench oil filtration. For the heat treater, there are many different size filters available, as well as different configurations varying in the number of canisters and filters. The filter creates a barrier that particles greater than the pore size in the barrier cannot pass. The primary reasons for its popularity are economics, simple operation, and design. A typical polyethylene bag filter and filter cannister can be seen in Figure 3.

The most common filter sizes are 50-micron and 25-microns. Both 5-micron and 25-micron filters were used in this investigation because the test sample contained a high level of pentane insoluble. Additionally, since it is commonly thought that using a 50-micron filter will cause blinding and clogging, we chose a 75-micorn filter and a subsequent filtration step of using a 25-micron filter to simulate a common two-stage quench oil filter.

Understanding the Test Methods: Centrifuge Filtration

Using a centrifuge to filter out sludge and scale is also commonly used in many heat treating operations. The difference between centrifugal filtration and barrier filtration is centrifugal filtration relies on gravity, friction, and centrifugal force to separate the particles from a quench oil instead of a physical barrier (Figure 4).

Figure 4. Horizontal centrifugal filtration (Source: SBS Corporation)

In the horizontal centrifugal filtration diagram, the dirty oil enters the tangential opening (section #1) and is forced into a spinning motion. A centrifugal force (occurring in section #2) is based on the spinning pentane insolubles, scale, and any other solids contained in the dirty oil.

In section #3, the friction created by the flow of the solids, scale, and other undesirables encountering the steel body of the centrifugal separator creates a low viscosity shear layer. In section 4, the clean liquid travels through a vortex and leaves through a side discharge. The slowing velocity of the undesirables allows gravity to pull them into the debris collection area in section #5. The now cleaned oil regains its velocity and continues through the vortex created by the centrifugal forces acting on the solids to a center discharge and back to the quench tank. As the debris fills section 6, a light will illuminate, indicating the receptacle is full and needs to be emptied.

Once the undesirables fill the debris collection area, an indicator light signals the receptacle is full and a gate knife control valve (section #7), is manually closed so the debris collector can be opened via the closure (section #8).

Discussion

Table 4. Tested parameters after centrifuging 300 mL of quench oil sample @ 3,500 RPM for 25 minutes (Source: Idemitsu Lubricants America)
Table 5. Tested parameters after centrifuging 300 mL of quench oil sample @ 3,500 RPM for 3 hours (Source: Idemitsu Lubricants America)

As seen in Tables 2 and 3, filtration does improve the overall cleanliness of the dirty quench oil. The weight percent of the pentane insolubles showed a significant improvement when filtered through the 25-micron fi lter. However, the level of pentane insolubles was still outside of the suggested limits for the quench oil.

This was not seen when the quench oil was filtered through a 75-micron filter. The 75-micron filter had little or no effect on the Millipore results. The Millipore results increased when filtered through a 75-micron filter. This leads us to believe some of the particles within the dirty oil were forced through the 75-micron filter and not through the 25-micron filter, as the 25-micron filter showed an improvement in Millipore results.

An ISO particle count was not possible on the original used samples or the filtered samples because the filter clogged on all three test samples.

The largest difference in results lies in the carbon residue testing. The level of carbon residue is essentially the same after both the 75-micron and 25-micron filter samples. Both of the carbon residue levels are within the normal suggested limits. However, the high level of sludge in the original dirty sample is likely removing some of the quench speed improver from the quench oil. The removal of the quench speed improver changes the performance of the quench oil over time.

In examining the results of the centrifuge testing in Tables 4 and 5, it is clear centrifuging for 25 minutes has better effect on the cleanliness of the oil sample than filtering through a 25-micron filter. The level of pentane insolubles after centrifuging for 25 minutes at 3,500 RPM is still outside of the suggested limit. However, running the centrifuge for three hours under the same conditions not only brings the pentane insolubles within the suggested limits, the Millipore and particle counts also see an improvement over the virgin oil sample results. The carbon residue
levels behave much the same as they do in the filtration tests.

What is significant is the year-long study we conducted using actual customer data. In this study, a furnace was dumped, cleaned, and then filled with clean virgin oil. The authors then tested the ISO particle counts and pentane insolubles for one year after the furnace was charged with clean oil. These results are seen in Table 6. These data show essentially no change in the particle counts and a slight improvement in the level of pentane insolubles over the one-year period.

Table 6. Particle count and pentane insolubles on a clean quench oil (Source: Idemitsu Lubricants America)

Conclusion

From the testing conducted, it is clear the filtration through a 75-micron filter has little to no effect upon the tested parameters and the performance of the quench oil. The high levels of pentane insolubles will likely clog heat exchangers, pumps, and valves within the quench system. The dirty oil will also likely cause metallurgical issues such as isolated soft spots due to the slower heat transfer of the dirty oil. The results of filtering a dirty oil through a 25-micron filter show some improvement in the pentane insoluble levels. However, the result is still outside of the recommended limits for the oil. Additionally, the ISO particle counts were not able to be tested due to the overall dirty condition of the filtered sample.

In contrast to the bag filter samples, the centrifuge samples showed a marked improvement over the dirty sample. While the pentane insoluble level was slightly out of the recommended limit for the 25-minute centrifuge sample, all results were within the recommended specifications for the three-hour centrifuge sample. In some cases, such as the particle count, the centrifuge sample had better results than the virgin sample.

While the centrifuge and filter results both show how hard it is to effectively clean a dirty quench oil, the results from the year-long study show very little difference in particle counts and a slight decrease in pentane insolubles, which can be explained through the normal addition of virgin make up oil to the quench system.

It is clear both centrifuge separation and bag filtration can improve the overall condition of a dirty quench oil. However, if your level of dirt, sludge, and scale reaches near the levels of the tested sample, a centrifuge is better at removing these than filtration. Overall, the data show the most important and efficient method is to begin filtering a clean quench oil as soon as the quench tank is charged.

About The Authors

Greg Steiger is the senior account manager at Idemitsu Lubricants America. Previous to this position, Steiger served in a variety of technical service, research and development, and sales and marketing roles for Chemtool Incorporated, Witco Chemical Company, Inc., D.A. Stuart Company, and Safety-Kleen, Inc. He obtained a BS in Chemistry from the University of Illinois at Chicago and recently earned a master’s degree in Materials Engineering at Auburn University. He is also a member of ASM International.

Michelle Bennett is the quality assurance specialist at Idemitsu Lubricants America, supervising the company’s I-LAS used oil analysis program. Over the past 12 years, she has worked in the quality control lab and the research and development department. Her bachelor’s degree is in Chemistry from Indiana University. Michelle is a recipient of Heat Treat Today’s 40 Under 40 Class of 2023 award.

For more information:
Contact Greg at gsteiger.9910@idemitsu.com
Contact Michelle at mbennett.8224@idemitsu.com.


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Induction and Sustainability Tips Part 1: Cleaning and Maintenance

OC

Discover expert tips, tricks, and resources for sustainable heat treating methods Heat Treat Today's recent series.  And, if you're looking for tips on combustion, controls systems, or induction in general, you'll find that too! Part 1, today's tips, digs into cleaning and maintenance

This Technical Tuesday article is compiled from tips in Heat Treat Today's May Focus on Sustainable Heat Treat Technologies print edition. If you have any tips of your own about induction and sustainability, our editors would be interested in sharing them online at www.heattreattoday.com. Email Bethany Leone at bethany@heattreattoday.com with your own ideas!


1. Maintenance of Induction Coils Used in Hardening Applications

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Soap and hot water will remove sticky quench and debris.
Source: Induction Tooling, Inc.

How should you maintain induction coils used in hardening applications? Elbow grease — a little goes a long way. After each use, a simple solution of soap and hot water will remove sticky quench and debris. Scrub hardened dirt with a Scotch-Brite pad. Check for pitting, arcing, and insulator damage. If all is good, use a hot water rinse, and it’s ready for use. If the inductor is to remain on the machine for an extended period, it is advised to wash it and the associated bus daily. Check for damage. Following this simple procedure will reduce business waste.

Source: William Stuehr, President/CEO, Induction Tooling, Inc.

#partscleaning #inductorcoil #hardening

2. Maintaining Tooling Fixtures for Induction Hardening

Tooling fixtures are usually maintained simply by storing them inside a mandrel and a box. This system will prevent coils from getting distorted.

Most tooling should be rinsed in hot water to wash off the polymer and then dried and stored away for future use.

It is a good practice to use deionized water for cooling the power supplies.

Source: Madhu Chatterjee, President, AAT Metallurgical Services LLC

#partscleaning #toolingfixtures

3. Switch to Aqueous

As industry tries to become more “green,” a number of companies are switching from lubricants that are petroleum or mineral oil-based to water-based (“aqueous”) lubricants instead. However, some of these companies then make the mistake of not changing their degreasing fluids that they use to remove these lubricants prior to their next processing operations, and stay with their standard degreasing fluids, such as acetone or alcohol, which are not effective at fully removing water-based lubricants. Instead, they need to run tests to find an appropriate alkaline-based degreasing fluid for such water-based lubricants, since alkaline-based degreasers will be effective at removing such lubricants. Commonly available dish-detergents (alkaline-based) have been shown to be highly effective for such use.

Source: Dan Kay, Owner, Kay & Associates

#aqueouscleaner #gogreen #lubricants


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How Clean is Clean Enough?

OC

How clean is clean enough? Insufficient cleaning before heat treating can interfere with results; insufficient cleaning after heat treating can impact perception of the part. Discover four methods of measuring part cleanliness that can take place within your heat treat operations in this article provided by SAFECHEM Europe GmbH.

This Technical Tuesday article is drawn from Heat Treat Today's March Aerospace Heat Treating print edition. If you have any information of your own about cleaning after heat treating, our editors would be interested in sharing it online at www.heattreattoday.com. Email Bethany Leone at bethany@heattreattoday.com with your own ideas!


Previously we talked about the importance of cleaning for demanding heat treat applications — in particular gas nitriding, or ferritic nitrocarburizing (FNC), low pressure carburizing (LPC), and brazing. So, if cleaning is a nonnegotiable for certain heat treatment processes, one might ask: how clean is clean enough?

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The basic definition of clean is removing unwanted substances, particles, and contaminations. However, when applied to surface cleaning, “clean enough” is determined by what you want to do next in your processing. Parts are generally clean enough if satisfying outcomes can be achieved in the subsequent application.

First, Do You Know the Expectations?

Unlike measuring hardness, monitoring or determining part cleanliness is by no means a straightforward matter.

There are two different kinds of contaminations to consider:

  1. Particle contaminations
  2. Film-type contaminations

Types of contamination
Source: SAFECHEM Europe GmbH

Whereas there are industry definitions or standards for particle contaminations (e.g., VDA-19 or ISO-16232 for the automotive industry), standards for film-type contaminations are not yet fully established.

This inadequacy also explains why many companies do not fully know what to expect when it comes to cleanliness, and they do not fully grasp the potential impact that insufficient cleaning could cause.

Especially when it comes to the heat treat industry, it is important to differentiate between the component cleanliness requirements before and after heat treatment.

Film-type contaminations are the primary factor which could negatively impact heat treat results. Requirements on particle contaminations (VDA-19) usually come from the automotive industry and need to be ensured/monitored after heat treatment.

Therefore, a distinction must be made between a) surface requirements for heat treatment and b) client cleanliness requirements on the final components.

What Is the Right Measurement Method?

The analysis of film-type contaminations and particle contaminations are two different subject matters. Measurement methods for one cannot replace the measurement methods for the other. Often, it is quite common for companies to have requirements on both film-type contaminations (e.g., surface energy in dyne/cm or mN/m) and particle contaminations (e.g., max. particle load) in their component drawings.

Some common measurement methods for determining contaminations include:

  1. White wipe test: A simple visual inspection test using a clean and dry white wipe to wipe across the surface for the detection of colored residues. Because contaminations can negatively impact heat treat results, inspection should take place prior to heat treatment. The test is limited to colored particles whose size can be perceived by the eye.
  2. Water break free test: An easy test to check if oil droplets might be present on the surface is when parts are rinsed with clean water at an angle. If there are contaminations, water will separate around those areas, showing a “break” in the water surface.
  3. Dyne testing: This method is commonly used for measurements of film-type contaminations. Dyne inks and fluids are applied to a substrate for measurement of its surface energy. The surface energy (measured in dyne/cm or mN/m) can be identified as the highest dyne solution that wetted out the substrate surface. The higher the dyne level, the better the adhesion of the surface for painting, coating, or bonding. However, the test does not provide information on the types of contaminations present.
  4. Millipore filter measurements/solvent extraction test: This measures surface contamination on parts as a weight per 0.1 m2. Samples are obtained by flushing the cleaned part with an organic solvent where particulates are collected on a filter disc (solvent will be evaporated off later). The test can determine the nature, number, sizes of particles, and if there are reflecting/ non-reflecting metallic particles. Moreover, oil film on parts can be measured after evaporation of the extraction solvent. For automotive, aerospace, or electrical, the level of cleanliness typically ranges between 0.01–0.001g per cm2.

In general, these methods differ in their complexity and informative value, and also if they can be carried out on site or off site (e.g., in a laboratory). The table below provides an overview of common measurement methods:

Cleanliness measurement methods
Source: SAFECHEM Europe GmbH

Determining Cleanliness — An Art and a Science in Itself

As you now see, the variances and potential limitations of different measurement methods can add to the complexity of cleaning validation. Consider the following:

  • Should you measure a specific surface area, or the entire part? And how do you measure pre-assembled components with different parts molded together?
  • It might be easy enough to measure surface cleanliness, but what about blind holes and crevices?

Visual inspections have many shortcomings. It is subjective, time consuming, and does not cover total level of contamination. The quality of inspection will very much depend on the operator. While automated particle counting is efficient and objective, it does not offer insights on specific contaminants.

Extraction methods targeting nonvolatile residues (NVR) can help determine a total level of contamination, but not spot contamination. It does not account for inextricable contaminants either, which could impact part functionality.

Meaningful Measurement Begins with Understanding the Big Picture

This is why, in order to measure and monitor cleanliness in a meaningful and reliable way, you should consider:

  • What potential contaminations could come about in your process/facilities?
  • What contaminants are you looking to remove?
  • What are the next processing steps?
  • What are the risks involved in removing the contaminants?
  • What are the risks associated with the potential residue?

Since every test has its own limitations, you should be mindful of the test specifications, too — for example, how it is conducted, result variability and reproducibility, as well as biases.

Cleaning can be a crucial step in heat treat, but more cleaning does not always equal better. More cleaning also implies more costs, more time, more resource usage. What’s really key is understanding what you, or your clients, are trying to achieve.

As you see, cleaning and measurement require expertise and knowhow — context is everything. Reach out to a cleaning specialist or trusted cleaning solutions expert for advice. If insufficient component cleanliness seems to be affecting your heat treat results, our cleaning specialists, along with our partners, would be happy to advise.

For more information:

Contact SAFECHEM Europe GmbH at service@safechem.com or visit www.safechem.com


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Using a Data-Driven Approach To Operate Cleaners in a Heat Treatment Facility

OCWhen was the last time the parts washer was cleaned? For many heat treaters, answering this question and keeping data on cleaning schedules and outcomes may not be at the top of their priority list. Learn how a data-driven approach to cleaning heat treated parts can have an impact well beyond the cleaning phase. 

This Technical Tuesday article, written by Greg Steiger, senior account manager at Idemitsu Lubricants America Corp., was first published in Heat Treat Today's August 2022 Automotive print edition.


Greg Steiger
Senior Key Account Manager
Idemitsu Lubricants America

Introduction

For many years heat treaters have virtually ignored their washers. It was not uncommon for these washers to be dumped and recharged whenever someone thought about it. Often the question “When was the last dump and recharge?” was met with the “I don’t know” shoulder shrug or “When the parts were dirty.” So why do parts need to be cleaner than ever before? The easy answer is because it is what customers are demanding. The more difficult answer is because as quality standards have improved over the last several decades, the need for parts with tighter tolerances has also increased.

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Many readers will wonder what part cleanliness has to do with tighter tolerances. The answer is the quench oil residue that was once acceptable to leave on the parts affects the tolerances of the part. For example, a buildup of oil in the threads of a part will have an impact on how the part threads into its mating part. Cleanliness affects post heat treat processes such as plating and painting as many residues cannot be plated or painted over. Part cleanliness also influences the shop environment in a heat treat operation. A clean, oil free part will not produce smoke in temper like a part with oil residues will.

Furthermore, when asked how the washer was recharged the typical answer was to drain the cleaner solution and then replace the cleaner solution with fresh water and enough cleaner to bring the concertation to the desired level and then restarting the washer. There was virtually no thought to removing the sludge that had built up over the years since the washer was last thoroughly cleaned. Little time was spent mucking out the sludge, and even less time and thought were expended on determining if the spray nozzles were clogged or properly aimed at the load. When energy, labor, cleaner chemistry, and disposal costs were all very low, this was the typical method of operating washers.

Now (with labor, disposal, energy, and cleaner prices all increasing along with the nationwide labor shortage) is the time to change those old habits and recognize the preclean and post quench washers are two ways to improve part cleanliness and the bottom line. The method of change for these habits is to allow data to be the guide in operating the washers in a heat treatment operation. The data will determine what the optimal concentration range is to obtain the cleanest parts. The data will show when the soil loading in the washer is too high. The data will reveal the maximum tank life for the cleaner solution. In other words, data should be used to maximize the efficiency of the washers.

Basic Cleaner Chemistries

The term alkalinity in its most basic description is a pH above 7.0. At this pH, the cleaner efficacy is improved as is the overall rust protection of the parts in the quenched load and any mild steel used in the washer construction. All alkaline cleaners share several types of common raw materials. They are alkaline builders, surfactants, corrosion inhibitors, and sequestering agents. However, where the
cleaner chemistries differ is in the types of alkaline builders used to create the alkaline pH. Many older formulations and less expensive products use caustics, carbonates, phosphates, and silicates as their alkaline builders.

Figure 1. Hard residue of powdered alkaline builders
Source: Idemitsu Lubricants America

While these are now commonly used in the liquid form, they are all powder based. The biggest issue with using powder based alkaline builders lies in the residue they leave behind when the water evaporates. These residues are the hard white residues seen in Figure 1.

Additionally, when the water evaporates from cleaners using these alkaline builders the residue can clog the spray nozzles within the washer cabinet. More recent formulations have begun using a product called an amine as an alkaline builder. Amines are liquids mixed with water. Therefore, when the water evaporates a liquid is still left behind. The film from an amine is more uniform, does not leave a powdery residue, and does not clog the spray nozzles in the washer cabinet. Additionally, amines have better buffering capabilities and help keep the pH of the cleaner in the mild pH range of between 9.0 and 10.5. When water is sprayed on a warm piece of steel, the water beads up and forms droplets.

The purpose of the surfactants in an alkaline cleaner is to prevent this from happening. The surfactants help the cleaner to wet out over the load more evenly. Surfactants also assist in the cleaning process by providing detergency to the cleaner. To provide short-term indoor corrosion protection, alkaline cleaners also have a short-term corrosion inhibitor formulated into the cleaner. This short-term protection is only intended to provide work-in-process protection. This protection is typically no more than a few days of protected indoor storage. Lastly, sequestering agents are used to allow the alkaline cleaners to be used in hard water. The sequestering agents chemically react with the minerals in hard water preventing them from precipitating out as hard water soaps and salts.

Alkaline cleaners can also be distinguished by those that emulsify the oils they remove and those that separate the oil they remove. In a typical dunk spray post quench washer, the load enters the washer and is lowered into the cleaner solution where the solution is agitated. The agitation allows the surfactants or detergents to provide the cleaning. During this period of agitation, the cleaner and quench oil combine to form a mechanical emulsion and potentially, a chemical emulsion. (The difference between a mechanical and chemical emulsion is a chemical emulsion is a more permanent emulsion and a mechanical emulsion stops when the mechanical agitation stops.) Once the mechanical agitation stops, a still period, or dwell, should then occur. This will allow the mechanically emulsified oil to separate from the cleaner solution. After this dwell period is over, an air knife or a set of nozzles will blow the oil layer into a separate chamber where the oil can be skimmed and removed from the cleaner solution. The elevator then brings the load up and out of the cleaner solution and into the spray cabinet. At this point it becomes highly imperative as much oil as possible is removed from the top of the cleaner solution. If the oil is not removed, the elevator will simply bring the load through a layer of oil, which is redeposited throughout the load. Once the load is in the spray cabinet, the cleaner solution is pumped through the spray nozzles onto the load. This spraying action is to remove any lingering soils and remaining oils. The solution pick-ups for these nozzles are typically in the middle portion of the dunk tank.

Designers of the equipment chose this spot because any free-floating oil will not be picked up and sprayed through the nozzles. For cleaners emulsifying oils the cleaner and oil emulsion is then sprayed and redeposited back onto the load. This will create issues in the temper where the water evaporates, and the oil left behind will create smoke and other vapors.

Figure 2. A 5% cleaner solution heated to 160°F was
made of each cleaner to test oil separation abilities.
Source: Idemitsu Lubricants America Corp.

For cleaners not emulsifying oils, the oil is not redeposited on the parts and the smoke and other vapors from emulsifying cleaners are greatly reduced or eliminated in temper. Figure 2 shows the difference between emulsifying and non-emulsifying cleaners.

While the source of alkalinity does not create smoke and other vapor issues in temper, the alkalinity source does create issues in temper and in the spray portion of the washer. In the temper, cleaners using alkaline builders such as caustics, carbonates, phosphates, and silicates will leave behind a white powder residue as seen in Figure 1. This residue is caused when the water in the cleaner solution evaporates and leaves behind the powder of the alkaline builders. Water evaporation in cleaners with powder alkaline builders will cause spray nozzles to clog and heating elements to foul. Cleaners using an amine as the alkaline builders do not have these issues. The difference in heating elements can be seen in Figure 3.

Selecting a Cleaner

Figure 3. Heating element comparison of an amine cleaner vs. powdered alkaline builder cleaner
Source: Idemitsu Lubricants America

The proper selection of a cleaner can be the difference between a highly satisfied customer and a completely dissatisfied customer. The requirements for a cleaner are as follows:
• Part cleanliness that exceeds customer
expectations
• Long sump life
• No residue
• Ability to split quench oil from cleaner
• Rust-free parts
• Low foam
• Low to moderate pH
• Hard water stability

When selecting a cleaner, a heat treater typically has two opportunities to influence the overall part
cleanliness. The first opportunity lies before the heat treatment process begins with a precleaning step. The second opportunity is with the post quench cleaning operations. When choosing a cleaner for these operations it is important to know what soil will be removed during the cleaning. The answer to the post quench cleaning is obvious, a quench oil. However, the soils on the parts incoming to the heat treatment process vary greatly. These soils may include oil and water based rust preventatives, water soluble coolants, cutting oils, and mill oils.

Typically, the soils removed before the parts are placed into the furnace are easier to remove than the quench oil from the post quench washer. This allows for the same cleaner to be used in both operations. By using the same cleaner in both preclean washer and post quench washer, heat treaters don’t have to worry about purchasing two different cleaners or have the concern of mixing the cleaners by placing the incorrect cleaner in the wrong washer system.

Once the soils to be removed have been identified, the next criteria to look at in selecting a cleaner are the operating temperatures of the washer, the pH of the cleaner, and foaming characteristics of the cleaner. Typically, the foaming characteristics and the operating temperature of the washer are directly related.

The type of surfactants or detergent additive used in alkaline cleaners have a property called the cloud point. At operating temperatures below the cloud point, the cleaner will form a dense and heavy foam that inhibits the cleaning efficacy of the cleaner. At operating temperatures above the cloud point, the surfactants are soluble in water and work as detergents and do not create foaming. An operating temperature of 140°F–160°F is the ideal operating temperature to remain above the cloud point, maximize the efficacy of the detergents, and minimize foaming tendencies of the cleaner. The cloud point phenomena can be seen in Figure 4.

Figure 4. Demonstration of a surfactant cloud point
Source: Idemitsu Lubricants America

The higher the pH the easier it is to clean many soils from the parts. The pH of a cleaner plays multiple roles in the parts cleaning process. A pH above 8.0 also helps provide corrosion protection on mild and carbon steels. However, as the pH climbs, skin sensitivity becomes an issue. At a high caustic pH such as 12 or above chemical burns on skin can occur. At lower pH levels of between 9 and 10.5, such as those provided by amine-based chemistry, skin sensitivity is greatly reduced.

Another advantage to amine-based chemistry lies in the lack of a perceptible residue that is often seen on parts after temper or around the washer itself. Figure 5 shows a typical part residue after temper from an emulsifying caustic cleaner. Figure 6 shows the residue found on a washer using a caustic cleaner.

In addition to leaving the residues seen in Figures 5 and 6, caustic cleaners also have the potential disadvantage of clogging spray nozzles when the water evaporates leaving behind the same type of residue in the spray nozzle. The clogged spray nozzles will then reduce the efficacy of not only the cleaner, but also the oil skimmer as well as the spray nozzles that are used to push the floating oil into the quenchant tank where floating oil is removed via an oil skimmer.

A cleaner should be compatible with hard water. In many areas the aquifers and wells where water is drawn from contain high amounts of minerals and salts. These hard water minerals and salts exacerbate any residue issues and create an ideal environment for rust and corrosion to begin. If the minerals and salts are left unchecked, they will eventually form chloride ions and mini voltaic cells. These mini voltaic cells are the beginning stages of the corrosion process. The sequestering agents in an alkaline cleaner will chemically react with the minerals and salts thereby not allowing the free chloride ions and the mini voltaic cells to form.

Using Data To Efficiently Operate a Washer

There are many reasons heat treaters dump and recharge their parts washers. The most common reasons typically are: “we dump the washer once a month because we always have”; “we dump the washer whenever the parts get dirty”; or “we never dump the washer.” Very infrequently is the answer “the soil loading is too high.” That is because to know what the soil loading is, the washer has to be operated by using data. Using data, heat treaters can optimize the efficacy of the cleaner solution, maximize the dump interval of the cleaner, reduce the amount of sludge in the washer, and lessen downtime.

The key in establishing a dump cycle is to know when the cleaner has reached its soil loading limit. Typically, this is around 2%. Soil loading is the amount of soil that is mixed in with the cleaner. The soil consists of a mixture of the soils removed, dissolved salts, and soaps along with anything else that makes its way into the washer. The 2% limit will be reached quicker in the post quench washer than in the preclean washer as more soil is removed in the post quench washer. In addition to soil loading, the proper data approach should also include the cleaner concentration by an alkalinity titration, concertation by Brix, tramp oil, cast iron chip rust test, and chloride level.

A brief explanation of each test and the reasons for performing the test are individually listed below.

pH

A good pH range is between 9.2 and 10.5. Within this range, most people coming into contact with the cleaner solution will not have an issue with skin sensitivity. At a pH above 10.5 skin sensitivity dramatically increases. As the pH begins to trend lower and eventually becomes acid below 7, the corrosion protection properties of the cleaner decline.

Concentration by Brix

This test measures everything that is dissolved within the cleaner solution. This includes salts, soaps, and removed soils. The Brix% is measured with a handheld refractometer reading in Brix%. The Brix% is then compared to a chart specific to the cleaner being tested. The Brix% will typically be higher than the concertation when tested via an alkalinity titration as the Brix% captures the amount of cleaner dissolved in water, along with salts, soaps, and removed soils. The concertation limits for the Brix% should have a maximum no more than 2.0% above the concentration by alkalinity.

Concentration by Alkalinity

This is a titration that can be performed in a lab or at the washer. A weak acid such as 0.1N HCl and an indicator such as phenolphthalein is used. The method and concentration multiplier depends on the specific cleaner used. Many methods count drops of acid used, while others use milliliters used to change the color of the indicator. The supplier of the cleaner will likely provide an initial concentration test kit and instructions on how to use the kit. A good concentration range for a preclean washer is between 2% and 3% and a post quench washer should have a concertation range of between 4% and 5%.

Soil Loading

The difference between the concentration by Brix% and concentration by alkalinity is the soil loading. This value should not exceed 2%. When the soil loading exceeds 2% it is time for a dump and recharge of the cleaner solution.

Tramp Oil

A tramp oil test measures the ability of the skimmer to effectively remove the quench oil from the top of the cleaner. This test is simple to run and can be run by most heat treaters. Simply fill a 100 ml graduated cylinder with the cleaner solution from either the preclean or post quench washer and allow the cylinder to stand idle for 20 minutes. Then simply read the amount of oil that has separated from the cleaner. A maximum level of 2% tramp oil shows the oil skimmer is effectively removing the tramp oi from the cleaner.

Cast Iron Chip Rust Test

Running the cast iron chip test requires dry machined cast iron chips and is best left to your cleaner supplier. The purpose of running the cast iron chip test is to ensure the corrosion protection formulated into the cleaner is not being depleted. This test uses a scale published by ASTM with a rating system of 0 to 5, where 5 is the worst and 0 is the best. To successfully pass this test a result of no more than 1 should be achieved. It is important to remember, cast iron chips have more surface area than a steel part and cast iron is also more porous and prone to oxidation than steel. Therefore, a test result of 1 is not a reason for concern.

Chloride

The chloride test is another test that is best left up to your cleaner supplier because the easiest way to test is through expensive instrumentation. The purpose of testing for chlorides is to prevent the situation for a mini voltaic cell to form. If the chloride level exceeds 150 ppm in a cleaner solution a mini voltaic cell can form and the corrosion process begins. As this process begins, the pH will begin to fall as will the corrosion protection of the cleaner.

In Table 1 several commercially available cleaners were tested and evaluated using the criteria above. The cleaners tested were both those that emulsified oils and split the oils. Testing also includes both amine-based and caustic-based cleaners.

Discussion

Imagine if the dump cycle went from four weeks for a post quench washer to 10 weeks for the same washer by using a data-driven approach described in this paper. The savings would not only be in the cost of the cleaner used but would extend to less downtime and more efficient use of maintenance as employees no longer need to clean out a washer every month. Customer expectations for clean parts have changed over the past years. What was acceptable as little as five years ago is no longer acceptable today. What hasn’t changed is the way preclean and post quench washers have operated. While it is difficult to assign an economic value to exceeding the cleanliness standards of customers, it is not difficult to assign an economic value to parts not meeting your customer’s standards. That economic cost can be as high as lost business. By using a data-driven approach the decisions made in how to operate a washer are no longer kneejerk reactions. Instead, these decisions have a historical data-driven approach to them.

About the Author: Greg Steiger is the senior key account manager of  Idemitsu Lubricants America Corp. Previously, Steiger served in a variety of research and development, technical service, and sales marketing roles for Chemtool, Inc., Witco Chemical Corporation, D.A. Stuart, and Safety-Kleen. He obtained a BS in chemistry from the University of Illinois at Chicago and recently earned a master’s degree in materials engineering at Auburn University. He is also a member of ASM. Contact Greg at gsteiger.9910@idemitsu.com.


Find heat treating products and services when you search on Heat Treat Buyers Guide.com


 

Using a Data-Driven Approach To Operate Cleaners in a Heat Treatment Facility Read More »

Cleaning Quality and Economy for Heat Treated Parts

Source: Modern Machine Shop

Pre- or post-heat treat process cleaning might sound like an afterthought, especially when considering the expense. But this process can be effective and economical depending on the cleaning agent.

Learn about cleaning in this comprehensive best of the web. You'll walk away knowing what type of cleaning is best for your heat treated parts. Enjoy!

An excerpt:

"Chemical polarity makes it possible to fulfill a great variety of cleaning requirements. Polarity influences the characteristics of a substance such as its solubility, as well as its ability to function as a solvent."

Read more at "Cleaning Quality and Economy—Depending Upon the Cleaning Agent"


Find heat treating products and services when you search on Heat Treat Buyers Guide.com


 

Cleaning Quality and Economy for Heat Treated Parts Read More »

To Clean or Not To Clean? That’s the Question.

OCWhat's most important when heat treating: time, quality, costs, aesthetics?

With competing demands, you need to discern when cleaning parts pre- or post-heat treat is a beneficial, or even necessary, step. In today's Technical Tuesday, provided by SAFECHEM, dive into this topic -- to clean or not to clean -- and examine 6 easy questions you can ask yourself when planning any heat treat load.


Is Cleaning a Must in Heat Treat?

The answer is neither a simple "yes" nor a simple "no" – it depends.

In the past, cleaning has not been given much attention to in heat treatment, and the step is often bypassed. However, the attitude is slowly changing. On the one hand, product specifications and higher quality requirements are driving the demand for cleaner products – both visually and qualitatively. On the other hand, evolving materials used in upstream manufacturing has amplified the need for cleaning. Environment-friendly cutting fluids, for example, can go deep into the substrate where their complete removal is necessary to ensure successful thermal treatment.

Contact us with your Reader Feedback!

But still, the question remains: should you clean or not clean?

To answer that, we need to differentiate between cleaning pre-heat treat, and cleaning post-heat treat.

The main goal of cleaning pre-heat treat is to remove upstream contaminants such as cutting oils, coolants, chips and dust to ensure a clean, smooth surface. Their remnants could otherwise become baked on surfaces which might require costly processes to remove. Pre-cleaning is also key to protecting the furnaces. It prevents the formation of smoke and oil vapors resulting from burned oils, which in itself is also an environmental and worker safety issue.

Pre-Heat Treat Cleaning Key To Nitriding and Carburizing 

The reality is that the majority of heat treaters have not fully recognized the need for cleaning prior to heat treat (with the exception of brazing). And this is of particular concern for demanding applications such as nitriding and carburizing, where a cleaned surface is fundamental to achieving good heat treat results.

"Cleanliness conveys quality, standard and care, while also offering protection to critical furnace equipment. For certain heat treat applications, including gas nitriding, ferritic nitrocarburizing and low pressure carburizing, cleaning is almost non-negotiable. For others, cleaning could be a competitive advantage that helps differentiate your products."
Photo Credit: Adobe Stock

Insufficient cleaning can lead to challenges such as non-uniform layers, soft spots and stop-off paint issues. Particularly with nitriding, spotty nitriding layers may not be obvious to the eyes and can only be detected under microscope. Phosphate additives in corrosion inhibitors can also work themselves deep into the surface of deep drawn parts, which can cause spotty nitriding patterns if not removed properly.

When it comes to cleaning post-heat treat, cleaning is a standard step after oil quenching where most heat treaters rely on water-based systems to do the job. Of course, it is common knowledge that water and oil do not mix well, so residues could still remain. Therefore, how clean the parts need to be will depend very much on the end-use application (e.g., will the parts be shipped to clients? Will they be machined further?) as well as client quality requirements. Medical applications, for example, would have strict residual particle size limitations in place.

The Real (Hidden) Risk of Not Cleaning

Tackling a heat treat failure where cleaning is an apparent contributing factor needs not be problematic. The real challenge lies in cases where the heat treat process seems to have worked – while in fact it has not.

Complaints about unexpected nitriding/carburizing layers, or component problems with equipment, can arise when parts are in the final assembly, are already in use, or are even out there for many years. The link between these issues and (the lack of/insufficient) cleaning can become very hard to detect by then.

Hence, the pain point for heat treaters does not have to be “in the present.” Client claims issues that come back to bite in the future represent a far greater risk, precisely because of their unpredictability. Cleaning should not be taken lightly because it can mitigate future problems that heat treaters are not necessarily aware of at this point.

The Bottom Line Is This . . .

Cleaning is good housekeeping. Cleanliness conveys quality, standard and care, while also offering protection to critical furnace equipment. For certain heat treat applications, including gas nitriding, ferritic nitrocarburizing and low pressure carburizing, cleaning is almost non-negotiable. For others, cleaning could be a competitive advantage that helps differentiate your products.

When assessing your need to clean, consider these questions:

  1. What would be the cost of not cleaning? I.e., what damage could potential claims cause in terms of money, time, delays, client trust and corporate reputation?
  2. What are the costs to maintain/replace your furnace?
  3. What are the technical justifications?
  4. What are your client expectations in terms of quality, aesthetics, and applications?
  5. What are your corporate standards in terms of health, safety and the environment (HSE)?
  6. Are you producing parts for high-value manufacturing sectors such as aviation, automotive, or medical devices, where your product quality can make or break your business?

Needless to say, cost will be a key driving factor. Do you have a high enough utilization rate to justify the cost of investing in a cleaning system? If not, outsourcing to job shops could be a potential option.

If you do have the cost argument to invest in an in-house solution, do not cut corners! Don’t be tempted to choose the cheapest cleaning option available. Companies do that and realize years later that the system is not working properly and have to shell out another large sum to upgrade their equipment. Because it is not always obvious that your heat treat failures are a direct result of poor cleaning, as a best risk mitigation policy, take a step above rather than a step below – no one loves paying twice!

About the Author

SAFECHEM Europe GmbH

www.safechem.com

service@safechem.com

To Clean or Not To Clean? That’s the Question. Read More »

Have You Seen These 18 Heat Treat Technical Resources?

OCWelcome to another Technical Tuesday for 18 hard-hitting resources to use at your heat treat shop. These include quick tables, data sets, and videos/downloadable reports covering a range of heat treat topics from case hardening and thermocouples to HIPing and powder metallurgy.


Defining Terms: Tables and Lists

  1. Table #3 Suggested Tests and Frequencies for a Polymer Quench Solution (in article here)
  2. Case Hardening Process Equipment Considerations (bottom of the article here)
  3. Nitriding vs. FNC comparative table here
  4. 9 Industry 4.0 Terms You Should Know here
  5. Table 1: Limits of Error Thermocouple Wire (in article here)
  6. Table 2: Limits of Error Extension Grade Wire (in article here)
  7. Thermocouple Color Code Chart (in article here)
  8. International Thermocouple Lead Colors (in article here)

Free Downloadable Reports

  1. FREE ebook—High Pressure Heat Treatment: HIP here
  2. FREE ebook – On-site Hydrogen Generation here
  3. Forging, Quenching, and Integrated Heat Treat: DFIQ Final Report here

Visual Resources

  1. HISTORIC VIDEO: Aluminum Heat Treatment here
  2. Two simulations of a moving billet through heating systems (in article here)
  3. Fourier’s Law of Heat Conduction (in article here)
  4. Webinar on Parts Washing (link to full webinar at the top of the review article here)
  5. Materials 101 Series from Mega Mechatronics, Part 4, Heat Treatment/Hardening here
  6. Heat Treat TV: Press-and-Sinter Powder Metallurgy here

BONUS: 39 Top Heat Treat Resources

Heat Treat Today is always on the hunt for cutting-edge heat treat technology, trends, and resources that will help our audience become better informed. To find the top resources being used in the industry, we asked your colleagues. Discover their go-to resources that help them to hone their skills in the 39 Top Heat Treat Resources on this page of the September print magazine.

 

Have You Seen These 18 Heat Treat Technical Resources? Read More »

Parts Cleaning: What the Experts Are Saying

OCIn the past, the topic of parts cleaning was not one that garnered much attention in the heat treating industry, but today, things have changed. Interest in parts cleaning is at an all-time high and that makes the need for parts cleaning discussion of vital importance in all types of heat treatment processes.

This article appears in Heat Treat Today's 2021 Automotive August print edition. Go to our digital editions archive to access the entire print edition online!


Heat Treat Today wanted to discover why parts washing is such an important step in the heat treat process and about its growing value, so we contacted respected industry experts for an in-depth analysis of the growing popularity of this important step in heat treating.

The following experts contributed to this analysis: Fred Hamizadeh, American Axle & Manufacturing (AAM); Mark Hemsath, Nitrex Heat Treating Services (HTS); Tyler Wheeler, Ecoclean; Experts at Lindberg/MPH; Andreas Fritz, HEMO GmbH; Richard Ott, LINAMAR GEAR; and Professor Rick Sisson, Center for Heat Treating Excellence (CHTE) at Worchester Polytechnic Institute (WPI).

Heat Treat Today asked 13 questions regarding parts washing and encouraged the experts to answer as many as they wished. The following article is a compilation of their experienced insight.

What role does parts cleaning play in the heat treat process and component quality? What is the cost or consequence for heat treating when cleaning is not done correctly? Any anecdotes you can share with us?

Fred Hamizadeh
Director of
Heat Treat & Facilities Process
American Axle & Manufacturing

Fred Hamizadeh, the director of Heat Treat & Facilities Process at American Axle & Manufacturing (AAM), says, “As a captive heat treater (supplying parts that are used in a final assembly), cleanliness of parts is of paramount importance to the longevity and durability of the final product. Parts that are completely unclean prior to heat treating can cause non-uniform case; and uncleaned parts after quenching can cause a multitude of issues, from failure in post-heat treat operations to higher cost of tooling due to contaminated surface, to fi res in temper furnaces from burn-off of the remnant oils on the surface of parts.”

Mark Hemsath
Vice President
of Sales, Americas
Nitrex Heat
Treating Services

Mark Hemsath, the vice president of Sales, Americas, at Nitrex Heat Treating Services replies, “For many surface engineering treatments like gas nitriding and ferritic nitrocarburizing, surface cleanliness is very important. Various oils and organic substances can impede—selectively or broadly—diffusion and surface activity. Some surface contaminants will bake on or ‘varnish’. Some can be removed with slow heating and purging or vacuum, or even surface activation, but it is not a reliable science. Either way, by positively cleaning them beforehand, problems are avoided. The issues occur when the composition and/or concentration of surface contaminants are not well known or preannounced. Pre-washing and cleaning take time, cost money, and must be studied and discussed with customers prior to any start of production. When parts are promised ‘clean', but arrive coated in an unknown rust preventative or cutting/forming oils, they need to be cleaned.”

Tyler Wheeler
Product Line Manager
Ecoclean

Ecoclean’s Tyler Wheeler, a product line manager, shares, “Cleaning plays a critical role that will directly affect the success of the heat treating process. While sometimes looked at as a nonvalue-added process, the consequences of not cleaning correctly are many and can be costly. Depending on the method of heat treating, quality issues may range from staining, discoloration, inconsistent properties, and even damage severe enough to scrap entire batches. Not only are there consequences for the workpieces themselves, but these problems may extend to damaging the heat treating equipment itself, leading to downtime and expensive repairs.”

The experts at Lindberg/MPH report there are several benefits to cleaning parts prior to any heat treating. They say: “By washing the parts prior to heat treating, it assures that the furnace chamber will remain conditioned and free from vapors, resins, binders, or solvents that could attack the refractory lining or heating elements and cause pre-mature failure of those items.”

What about the cost or consequences when the cleaning is not done correctly? “Washing parts prior to any thermal process, removes any layer of machine or cutting oils etc., which can be baked on and require additional and costly processes such as grit blasting, machining, or grinding to remove the unwanted layer on the surface of the parts.”

The Lindberg/MPH experts had an interesting anecdote to share about the importance of parts cleaning: “A customer was using a simple spray washer to clean small sun gears with an inner spline. The parts were to be carburized afterwards. The spray washer didn’t remove the machine oil used in the broaching process. During the carburizing process, the machine oil acted as a shield and didn’t allow the carbon to penetrate the ID properly, thus causing part failure on the gears. Afterwards, a dunk washer with heated water and a dry-off was purchased to clean the parts.”

Andreas Fritz
CEO
HEMO GmbH

Andreas Fritz, CEO at HEMO GmbH, explains, “Cleaning has always played a role in heat treatment. The question was always, ‘How clean is enough to keep the cleaning process as cheap as possible?’ Nowadays, especially in LPC or nitriding processes, the cleaning quality is at least equal to the hardening quality, because heat treaters understand that these processes belong together. There are no good hardening results without good cleaning quality.”

Additionally, Fritz continues, “a cleaned surface lowers the risk of defective goods after heat treatment by helping to provide a very good hardening depth and compound layer.”

Fritz shares a company-altering anecdote: “In the mid-1990s, we sold the first machine to a Bosch automotive supplier which had a captive heat treatment department. They delivered the cleaned and then hardened goods to Bosch, and their QM sent the goods back stating they were not hardened.

“Our customer asked if they checked the hardening quality, and Bosch replied: no, because the parts were not black; therefore, coming to the conclusion that they had simply forgotten to harden them. The supplier invited them to see that the parts were cleaned in a new way with a solvent-based cleaning machine under full vacuum. Since they came out spot-free after cleaning, there was no oil left, which formerly cracked on the surface and left the black color. The result was that for a couple of years, Bosch wrote on drawings that the parts had to be HEMO-cleaned before hardening. This was our start in the heat treatment industry and today, we make 50% of our annual turnover there.”

LINAMAR GEAR’s Richard Ott, a senior process engineer, offers his perspective, “Pre-cleaning and post-washing are very important because all parts coming into our plant can’t have any contamination on them. After heat treating, all parts are washed and blown off before temper.”

Historically, cleaning has not received the attention it deserves in the heat treat process. Have you seen any positive changes in perception among heat treaters in recent years?

Wheeler of Ecoclean addresses the perception of value: “Historically, the cleaning process has been looked at as a non-value-added necessity of manufacturing. However, this attitude is becoming a thing of the past for companies who invest in a quality cleaning process. As of late, customers have placed a greater focus on their cleaning processes both before and after heat treating as quality and production demands continue to increase. A proper cleaning process can eliminate scrap, increase uptime, and lead to a better-quality product for the end customer, which may translate into additional orders. When considering the holistic benefits of a proper and robust clean process, the old mentality is starting to change.”

The experts at Lindberg/MPH reply, “For many years washing parts before or after heat treating was considered an optional process and often bypassed. Today, most commercial and captive heat treaters are using parts cleaning as a necessity, particularly in the growing vacuum heat treating sector, where any contamination is detrimental to the hot zone and pumping systems.”

HEMO’s Fritz explains, “Commercial heat treaters specifically, changed their minds very early because they saw the chance to cover the various cleanliness demands of all hardening methods and processes with one single cleaning system. The hybrid cleaning system which made it possible to clean with solvent or with water or in combination in the same machine, made it possible for them to ensure hardening quality for any incoming good, no matter which residue was on it.

“They were able to cut down costs by using only one cleaning system and by increasing the income per ton due to increased quality and less defective parts.

“The captive heat treaters changed when they sent parts outside to commercial heat treaters while they did annual maintenance or when they didn’t have enough of their own capacity. The returned parts were of much better quality; and they started introducing this kind of cleaning system as well.”

Hemsath of Nitrex agrees about rising standards: “Similar to other areas of heat treatment, OEMs continue to raise their standards for part cleanliness. Sometimes these standards are rooted in functional requirements such as minimizing the number of foreign particles in a closed system in the finished product and other times the requirements are purely aesthetic. In either case, the result is that, in recent years, heat treaters have been required to devote more resources to improve their cleaning processes proactively during the quoting/process design stages, or reactively as a result of non-conformance. Many commercial heat treaters have come to understand that evaluating the cleaning needs of a part and implementing a robust cleaning process before production begins results in a better customer experience as well as improved long-term profitability.”

AAM’s Hamizadeh concurs with a positive change in perception: “Yes! As automotive industry reliability demands are increased, more and more attention is placed on all aspects of cleanliness, which includes heat treat washers.”

Ott, of LINAMAR GEAR, shares evidence of the rise in parts cleaning importance, saying, “Yes, our washers are checked twice a day for concentration and cleanliness.”

How can heat treaters determine their cleaning needs?

Rick Sisson
George F. Fuller
Professor and Director of the Center
for Heating Excellence (CHTE)
Worchester Polytechnic Institute

Rick Sisson, the George F. Fuller Professor and director of the Center for Heating Excellence (CHTE) at Worchester Polytechnic Institute (WPI), explains, “The incoming materials should be carefully examined visually to identify the type and quantity of surface contamination. Look for heavy oil, light oil, cutting fluids and/or rust, and scales. The cleaning process should be selected to remove the type of surface contamination identified. In general, a cleaning process should be included prior to heat treating to ensure a predictable response to the heat treating or surface modification process.”

Sisson continues, “The heat treater must confer with their customer to determine the post-heat treat cleaning requirements. If the part will be ground or machined after heat treat, then post-heat treat cleaning is not required. However, if the part is ready to be shipped, then the appearance is important. For medical applications, any discoloration may be a cause for rejection. The surface finish may be important and should be discussed with the customer.

“The pre-heat treat cleaning requirements are determined by the effects of cleanliness on the heat treat performance. For surface treating, a dirty surface may affect the carburization or nitriding performance. Nitriding is very sensitive to the surface cleanliness. A fingerprint can inhibit the nitrogen uptake and result in soft spots. Carburizing is less sensitive to oils and grease, but corrosion products may inhibit the surface reactions and cause soft spots. However, it is best practice to examine the preheat treat parts and clean away the oils and grease. Corrosion products (aka rust) and cutting fluids ensure a uniform response to the heat treating process,” Sisson concludes.

Hamizadeh of AAM states, “Most customers should have a specification. Start by reviewing the provided prints and follow up with the final customer to determine if parts are further washed with dedicated process washers prior to installation in the final product.”

He concludes, “Nevertheless, heat treaters must provide a part which is clean, uniform in color, and free of quench oil on surfaces and cavities. Parts must also not exhibit any markings from oxidized quench oil (tiger stripes), either.”

“We are in-house heat treaters. Our customers require spotless parts and if they’re not, then we need to clean them,” explains Ott of LINAMAR GEAR.

Fritz from HEMO shares his perspective: “Heat treaters usually have their own labs to check the hardening quality. If the quality is not stable, the cleaning could be the reason. Additionally, they could send parts outside to be cleaned in a different way. Then do the hardening in their shop to see if there is a difference. In most cases, their customers tell them if the quality is not good. We are then the ones to offer our experience and take them to the next level.”

Ecoclean’s Wheeler describes their process in determining cleaning needs: “When determining the needs of a cleaning system, it is essential to understand the incoming contaminants on the part. In addition, one needs to understand which upstream manufacturing processes were used, the requirements of the heat-treating process, and which type of heat-treating process is being used. Not all cleaning systems are created equally, and not all approaches work in every scenario. For example, phosphate-coated parts coming from a stamping process will require a different cleaning system than a machined part. Working together closely with your cleaning equipment supplier is the best way to ensure that the best cleaning process is implemented for your specific application.”

How do the requirements for cleaning differ between pre- and post-heat treating?

The experts at Lindberg/MPH explain: “Pre-washing parts ahead of heat treating is needed to remove any oils or solvents that can remain on the parts. Also, some parts can hold wash water and some residue that can be carried into the furnace, and those must be blown-off or dried before the next operation.”

They continue: “Post-washing parts, particularly after oil quenching, is needed to remove any oil that might be trapped—parts such as pistons, valves, and gears with recessed areas. Most of those batch washers are fitted with a dunk or oscillation feature where the load is completely submerged, then drained and dried before moving to the tempering process. For many years, a single washer was used for both pre- and post-washing, but that practice has largely stopped.”

Nitrex’s Hemsath states, “When oil quenching in vacuum oil quench furnaces or standard integral quench furnaces, the oil is known, and it must be removed prior to temper operations. Quench oils are often difficult to remove completely, especially in hot oil quenching applications. Tempering can help with further removal of the oils, or it can make the situation worse by baking on quench oil residues into tough, difficult-to-remove deposits. With post-cleaning, the contaminants are well known, and they do not impede the heat treatment or surface engineering.” Hemsath continues, “Contaminants on the part’s pre-heat treatment must be removed for vacuum furnace operations to protect the equipment and prevent carbon pickup on the parts. Pre-contaminants must also be removed to help with processes such as gas nitriding, FNC, and low-pressure carburizing (LPC). Since LPC is a vacuum process, precleaning is more critical than with gas atmosphere carburizing, where the hot hydrogen gas can be effective at assisting with pre-cleaning of parts. However, even in atmosphere heat treating, minimizing the number of foreign substances entering the furnace on each part will help ensure a more consistent process and extend quench oil life.”

Wheeler of Ecoclean states, “Different goals and objectives drive the requirements of the pre-and post-heat treat cleaning systems. A pre-heat treat cleaning process aims to remove all contaminants produced by the upstream manufacturing process that could negatively affect the heat treating process. Without a proper pre-cleaning process, the heat treating may not be effective, parts could be damaged, and even the heat treating equipment itself could face damage. The goal of the post-heat treat cleaning system is to ensure that the final product meets the quality demands of the customer or end-use application. The needs of these systems may be driven by strict specifications which limit the number of allowable particulates and even the maximum size of each particle.”

Hamizadeh of AAM agrees that the processes are in no way similar. He says, “Drastically different. Pre-wash is intended to clean the product from any upstream contaminants, cutting fluids to provide a clean, uniform surface for process. Additionally, pre-wash is used to protect the heat treat equipment from contamination from oils and chemicals, which will have an adverse effect on lining or internal alloy components of the furnaces.”

He further explains, “Post-washers are historically built to remove the bulk quench oil from the part. However, it is more common that parts have irregular shapes, hidden holes, and geometries that make it difficult to remove trapped oils.”

“In the case of pre-cleaning, we make a difference between organic and inorganic residues,” Fritz of HEMO contends. “An old chemical says, ‘Similar dissolves similar.’ Hence, it is important to identify the residues of parts before pre-cleaning.”

He continues, “Water-based coolant should be cleaned with water and detergent because solvent would leave white spots caused by salts.”

“Oil is organic and should be removed by solvents like hydrocarbon or modified alcohol because water and oil are not a good mixture,” explains Fritz. “Anybody who first cleans an oily pan before a glass in the same bath knows that. Sometimes the parts have both kinds of residues on them due to several production processes before heat treatment. Then a hybrid cleaning machine is the perfect solution, because it first takes away the organics with solvent and then the inorganic spots with water.”

He concludes, “In the case of post-cleaning, we mainly talk about cleaning after oil quenching. In this case, water is the worst solution because the cleaning quality is not good, and the amount of wastewater is immense. A pure solvent machine is the best option for this scenario.”

How does cleaning differ between commercial heat treat shops and in-house/captive heat treat departments?

Sisson of CHTE describes the difference this way: “The need for cleaning remains the same. Captive heat treaters will have the benefit of heat treating the same parts over time and should document the contamination identified and the cleaning methods used. Frequently the parts will be coming from a machining or surface finishing operation. A discussion with the machine shop will identify the contamination.

“Commercial shops will see a wide variety of parts and should develop an incoming materials evaluation process to determine the type and extent of surface contamination. As part of this incoming material evaluation process a cleaning process should be specified for each incoming part. The process to remove grease and oil is different from corrosion products.”

How clean is clean anyway? How can one determine cleanliness? How can heat treaters identify the right cleaning method for their applications? What should they pay attention to?

“Specifications based on design and final function of the part will determine the cleanliness requirement,” Hamizadeh of AAM points out. “It is imperative to determine the cleanliness requirements prior to processing the parts. This could be surface chemical, oil contamination, or particulate allowed on part in terms of grams allowed per part or number of particles of determined size per part. Pay attention to customer contractual requirements based on RFQ or part print, or customer specs as stated in part drawings.”

“When answering this question, we need to ask ourselves: ‘What is the end goal of the cleaning process and what contaminants am I removing?’” Wheeler of Ecoclean begins. “Not all contaminants are created equally, nor will they successfully be removed using the same approach. The types of equipment, process steps, machine parameters, and chemicals used for cleaning need to be chosen carefully to ensure a successful and robust process.”

He explains: “Cleaning prior to heat treating is focused on preparing the parts for a successful heat treat, which means we need a surface free of oils, coolants, and particulates. In addition to the cleaning aspect, it is also crucial to sufficiently dry the parts before treating them to prevent damage during the heat treating process. A simple test to check for cleanliness prior to heat treat is to perform a ‘water break test,’ where clean water is rinsed across the surface with a goal of seeing a continuous film of water running across the whole part without being interrupted. A more scientific approach involves measuring the surface energy of the piece by using a contact angle measurement tool or Dyne pens.”

Wheeler clarifies: “When asking how clean the parts need to be post-heat treatment, there may be drastic differences based on customer quality requirements and the end-use of the workpiece. These requirements can range from simple visual cleanliness checks to strict maximum residual particle size limitations. The evaluation for conformity to these high-end specifications will require the use of multiple pieces of lab equipment, including expensive particle measuring and counting microscopes.” CHTE’s Sisson illustrates, “As we have seen in old movies, the butler wears white gloves and after rubbing the surface any contamination can be seen. There is a limited number of types of surface contamination for heat treaters to identify: heavy oils, light oils, cutting fluids, and corrosion products (rust and scales). Knowledge of the part history will help identify the contamination and therefore the cleaning method.

“The largest impact will be on nitriding and ferritic nitrocarburizing (FNC) processes. Surface contamination inhibits the absorption of nitrogen by interfering with the decomposition of ammonia on the steel surface. Even the grease from fingerprints can cause soft spots,” he concludes.

HEMO’s Fritz shares, “Clean can be visually clean or when you wipe a cleaned part or when a part is not dirty after the hardening process because it was cleaned well before.”

In determining cleanliness, Fritz continues, “Optically, for example, use an ink pen that shows the surface tension. A high surface tension shows a well cleaned surface.”

And finally, identifying the right cleaning method and focus: “First thing is to always identify the residues which are on the parts. If this is identified the cleaning process can be selected accordingly.”

What might be the impact for furnaces if components are not cleaned thoroughly?

Fritz of HEMO answers, “The residues vaporize and crack on the furnace walls. The walls then must be stained new in short intervals. This can be prevented by using a better cleaning system.”

“Heat treating oily parts will cause the oils to burn and fill the room with smoke and oil vapors. These gases and the smoke will deposit in the furnace and reduce performance and furnace life,” shares Sisson of CHTE.

The experts at Lindberg/MPH explain, “For many years unwashed parts were placed in tempering furnaces to burn-off the machine oils rather than washing. Over time, all that machine oil saturated the furnace brickwork or coated the heating elements, which had to be replaced much sooner than needed. Today, due to some environmental issues, that ‘smokebomb’ has become a problem, and the washer has become a sound solution and a proven benefit.”

AAM’s Hamizadeh says, “I’ve seen carburizing furnaces become contaminated with chemicals from prewash. They glazed the hard refractory into a glass and caused adhesion between silicon carbide rails and alloy base trays.” He continues: “We’ve also seen excessive smoking from temper progress to an occasional, but rare fire in a temper furnace or a more probable fire in exhaust ducts due to oil film build up.”

What cleaning options are available? What are their pros and cons?

“Traditional batch or continuous spray washers with or without dunk is an absolute minimum,” states Hamizadeh of AAM. “Other equipment such as Aichelin’s Flexiclean Vacuum washer can do a fabulous job without the use of solvents. Today—as a minimum—prewash systems should have a 3-tank system of wash, rinse & rinse, and blowoff. Post-washers should have 4-stages: 2-wash, followed by 2-rinse, and blowoff dry stage. Conventional washers are very cost-effective. Newer technology washers, with the use of advanced skimmers, multistage filtration, and ultrasonics to get the best agitation possible, will improve the capability of the machine. Dedicated and custom designed line washers perform the best, but also cost the most.”

HEMO’s Fritz shares, “I think the inline water-based dip and spray cleaners with hot air or vacuum drying are still fine for 50% of all applications in heat treatment. Anything else would be too expensive and simply not necessary. But for higher demands, more sophisticated systems are necessary. There you find top or front-loading full vacuum machines which can run water with detergent, solvents, or both.”

“For most washers, added features such as skimmers, oil traps, and dual-can type filters are very popular,” point out Lindberg/MPH experts. “These options help in keeping the washing media cleaner and free from loose metal, chips, and free carbon. The cost of these items is minimal compared to dumping several hundred gallons of water and many chemicals on a regular basis.”

They conclude, “Most washers, especially those fitted with the dunk features, are built with stainless steel tanks and all structures that are submerged in the washing solution. The extra cost for stainless steel far outweighs the cost of replacing a mild steel-lined tank or coated tank, which both have a much shorter life than the stainless-steel units.”

Apart from technical cleanliness, are there other aspects that heat treaters should consider in their choice of the right cleaning solution? Do certain materials demand specific cleaning precautions? What cleaning methods will be particularly suited to specific types of soils?

LINAMAR GEAR’S Ott says, “Washer chemistry that will remove oil and other surface contaminants and possibly leave a protective coating on the parts may be worth developing, so that flash rusting will not occur before the tempering operation.”

AAM’s Hamizadeh explains, “For specific parts and materials, specific washers with specific chemicals are needed. All parts should be compared to detergents used, temperatures, and agitation/spray pressures they can endure.”

“They should consider the quality of the final product,” Fritz of HEMO details. “They should consider environmental issues like wastewater, amount of detergent, heating energy, etc. They should consider cycle time and the degree of cleanliness required. Altogether it will lead them to a total cost of operation consideration, and they will find out that a high investment doesn’t mean higher operating cost over the lifetime of the equipment.”

He shares that “Copper and aluminum, especially, must be handled with care when selecting a way of cleaning.”

What common issues do heat treaters experience in the cleaning process? And how can these be avoided?

Nitrex’s Hemsath explains, “There are various methods for cleaning from vapor degreasing to ultrasonic methods. Each has benefits and negatives, such as environmental impact issues or cleaning of various contaminants completely. Another issue is part orientation and cost of parts handling. Continuous small parts cleaning can allow better part orientation, say, for cylinders. However, the labor content adds to costs for individual parts placement. No operation, especially commercial heat treat operations, can have all the cleaning options. It is not uncommon to hand-clean parts that are difficult to clean in a batch or continuous processes. The biggest problem is not knowing what the exact contaminants are.”

“Complex part geometries and pack density of the load are common load issues that are faced. Regular maintenance of washers—filters, skimmers, titration practices to maintain chemical balance—will all affect their performance. A regimented SPC and quality control specification should be required to ensure all work is completed and signed off by appropriate quality team members,” states Hamizadeh of AAM.

Fritz of HEMO cautions, “The biggest issue is the white layer or spots on the parts which result from inorganic residues. They pollute their water-based cleaning media with oil and other organics and then the media is not strong enough to additionally clean off the inorganics. This can cause soft spots on the surface after the hardening process. “The second big thing,” he says, “is that the cleaning quality is decreasing with every cycle. In a solvent machine with a good distillation device, you always have a constant quality.”

Have you noticed any changing requirements or expectations in terms of cleaning quality for heat treat processes over the last 5 years?

Hamizadeh of AAM answers affirmatively, “Yes. Tighter specs for amount of carry over oil or oil residue on parts.”

HEMO’s Fritz concurs, “The requirements change because the industry is changing. We go to electric vehicles, which means we need to harden new kinds of parts that are made of new kinds of materials, alloys, and composites. This means a modification of the hardening and of the cleaning process.”

Ott from LINAMAR GEAR has noticed, “Parts are compared to vacuum heat treat, so the cleanliness is very important, especially in automotive.”

What challenges do you think will confront heat treaters in the next 5 years, specifically regarding parts cleaning? Where do you see trends heading?

“Electric drive units will require a reexamination of the part washing and available technologies. It’s going to become more difficult. Not easier,” believes AAM’s Hamizadeh.

Fritz of HEMO predicts, “The main challenge will be to stay alive. With the rise of the electric car, fewer parts will be heat treated. Heat treaters must offer the best possible quality for reasonable prices in order to survive. This is not possible with the old way of cleaning.” He sees trends “. . . still going to vacuum. LPC is very strong and will be increasing. Additionally, gas and plasma nitriding will increase. Especially in those cases, a clean surface is the only way to have a reliable hardening process with consistent quality.”

Fritz concludes, “The other trend is small batches. That is the reason why we redesigned our small cleaning machines to also be able to survive in the heat treatment environment.”

“Totally clean parts,” is the challenge Ott of LINAMAR GEAR sees.

How can heat treaters balance the need for component cleanliness and cost-effectiveness for their operation?

Ecoclean’s Wheeler maintains, “When searching for the balance between cleanliness and cost, defining what costs are genuinely associated with cleaning is essential. Some of these costs may be obvious, while others may not be so clear at first glance. In too many instances, the actual lifecycle costs of owning and operating a cleaning system are not taken into consideration as the main focus is instead the upfront investment of the machine itself.

Utility costs, chemical usage, waste disposal, and maintenance are only some of the expenses that will add up over the life of a piece of equipment which may significantly impact its cost-effectiveness over an alternative solution. One example in this instance is using a vacuum solvent cleaning system over an aqueous-based machine. While the solvent system will typically come with a higher upfront purchase price, it is generally more cost effective to own in the long run when compared to the water-based system.”

Wheeler continues, “The other question that one should ask when deciding on how much to spend on a cleaning system is what the cost of purchasing the wrong system is. How much will be spent on scrapped parts, repairing damaged heat treating equipment, and downtime caused by the improper cleaning of parts? These may not always seem obvious upfront, yet they are actual costs that every manufacturer may face. While there is no one-size-fits-all approach for every company, it is essential to consider all obvious and hidden costs associated with the cleaning process when looking for the balance between price and quality.”

“For captive heat treaters,” Hemsath of Nitrex answers, “their contaminant stream is much better understood, and a solution can be custom engineered to provide repeatable results. For commercial heat treat facilities, cleaning operations have to satisfy many part sizes, orientations, and a multitude of contaminations that are often not well understood. So, the cleaning operation must be a process that gets most of the contaminants on most of the parts. Good communication with the part maker is essential to prevent problems, especially in long-term programs where the same parts are heat treated for many years.”

“They must do a total cost of operation examination of their whole process in order to find the right system,” encourages Fritz of HEMO.

These experts have spoken and offered much valuable insight into the world of parts cleaning. No longer can this process be viewed as “a non-value-added necessity of manufacturing,” as Tyler Wheeler of Ecoclean observed. Today, parts cleaning is proving to be an important component for success in heat treating.

 

For more information, contact the experts:

Fred Hamizadeh, Director of Heat Treat & Facilities Process, American Axle & Manufacturing, Fred.Hamizadeh@aam.com

Mark Hemsath, Vice President of Sales, Americas, Nitrex Heat Treating Services, mark.hemsath@nitrex.com

Tyler Wheeler, Product Line Manager, Ecoclean, Tyler.Wheeler@ecoclean-group.net

Lindberg/MPH, lindbergmph@lindbergmph.com, 269.849.2700

Andreas Fritz, CEO, HEMO GmbH, a.fritz@hemo-gmbh-de

Richard Ott, Senior Process Engineer, LINAMAR GEAR, Richard.Ott@Linamar.com

Rick Sisson, George F. Fuller Professor & Director of the Center for Heating Excellence, Worchester Polytechnic Institute, sisson@wpi.edu

technical Tuesday

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Four Key Questions to Ensure Effective Parts Cleaning in Heat Treat

OCWhy is parts cleaning an important step in heat treat? While a nice surface finish reflects quality, the importance of cleaning goes far beyond the aesthetic aspect. Parts cleaning can ensure against quality issues, especially when it comes to nitriding or brazing where high surface cleanliness is a prerequisite. Learn what questions you should be asking to achieve optimal parts cleaning.

This Technical Tuesday feature written by Michael Onken, market development manager at SAFECHEM, will be published in Heat Treat Today's  August 2021 Automotive print edition.


Michael Onken
Market Development Manager
SAFECHEM
SAFECHEM

There are two types of cleaning in heat treat. One is cleaning prior to hardening where residual metal working fluids on parts must be removed. Then there is cleaning after quenching. Residue oils left on parts after quenching may cause challenges in the next process steps, such as tempering.

Inadequate cleaning not only affects subsequent processes, but also parts quality. Contaminations on parts can also get into furnaces and fixtures, and thereby impact their functionalities.

Quality cleaning is costly, but necessary, if the goal is to achieve quality components. The important questions are: What cleaning solution should I choose? Is water-based cleaning better, or rather solvent cleaning? The answer is that it depends. We have briefly outlined 4 key questions you should consider.

What are your cleaning quality requirements?

Different industrial applications require varying degrees of surface energy of the metal surface, which is influenced by filmy contaminations. With nitriding, for example, a higher surface energy is required than with standard coating or assembling. The ability of the cleaning agent to remove the contamination should therefore match the required surface energy.

SAFECHEM

What is the affinity of the cleaning agent to the soils?

Effective cleaning is based on the principle “Equal dissolves equal.” For water-based types of contaminations, such as coolant and lubricant emulsions, aqueous cleaning agents are typically the first choice.

When removing mineral oil-based, non-polar contaminations, such as machining oils, greases, and waxes, solvent will commonly be the preferred cleaning agent.

The above contaminations can be classified as filmy contaminations that can be dissolved in a suitable cleaning agent. Another important category of contaminations is particles like chips, dust, and residues of polishing pastes. These contaminations cannot be dissolved in a cleaning agent. To remove these, sufficient mechanics are required in the cleaning machine to flush off particle contaminations.

What metal types are being cleaned and how are they configured?

In water-based processes, cleaning agents, which can be acidic, neutral, or alkaline, are usually matched to specific metal types. Simultaneous cleaning of different metals can therefore be problematic, and this can result in compatibility issues and in the worst case—corrosion. Solvents, in comparison, have universal compatibility with metals.

If the component parts are tiny or have complex geometry or small crevices, solvent is often recommended due to its lower surface tension and viscosity, which makes it easy to seep into and evaporate out of tight spaces.

What is the environmental impact?

The energy consumption in a water-based process can be significant, due to the energy requirement to operate high-pressure pumps, heat the cleaning water, dry the metal parts, as well as treat and purify used water for reuse or disposal. Depending on the cleaning agents, dirt and soil are emulsified and the contaminations are diluted in the water. As a result, aqueous baths that are not treated must be replaced frequently.

Solvent in a closed vacuum vapor degreaser can be recycled again and again via the built-in distillation unit. This can significantly increase solvent lifespan and cut down on waste volume. While energy is required to keep the closed cleaning machine under vacuum, this also lowers the boiling points of solvents, hence accelerating their evaporation and enabling quick drying of metal parts within a shorter cycle time.

The questions listed above are by no means exhaustive and there are many more key aspects to consider. The optimal cleaning decision should balance technical, economic, and environmental needs. Given the potential of parts cleaning to make or break heat treat processes, when done properly, it can deliver much more value than the mere technical function it fulfills.

Read more about parts cleaning in heat treat here.

About the Author: Michael Onken is a market development manager at SAFECHEM Europe Gmbh. For more information, contact Michael at m.onken@safechem.com or Phone: +49 211 4389-300

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