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Dr. Valery Rudnev on . . . Equipment Selection for Induction Hardening: Single-Shot Hardening, Part 1

This article continues the ongoing discussion on Equipment Selection for Induction Hardening by Dr. Valery Rudnev, FASM, IFHTSE Fellow. Six previous installments in Dr. Rudnev’s series on equipment selection addressed selected aspects of scan hardening and continuous/progressive hardening systems. This post continues a discussion on equipment selection for induction hardening focusing on single-shot hardening systems.

The first part on equipment selection for continuous and progressive hardening is here. The second part in this series on equipment selection for single-shot hardening is here; the third part is here. To see the earlier articles in the Induction Hardening series at Heat Treat Today as well as other news about Dr. Rudnev, click here. This installment continues a discussion on equipment selection for continuous and progressive hardening applications.


Why Single-Shot Hardening?

With the single-shot method, neither the workpiece (cylinder shaft, for example) nor the coil moves linearly relative to each other; the part typically rotates instead.¹ The entire region that is to be hardened is heated all at once rather than only a short distance, as is done with scan hardening.

With conventional scan hardening of cylindrical parts, induced eddy currents flow circumferentially. In contrast, a single-shot inductor induces eddy currents that primarily flow along the length of the part. An exception to this rule would be the half-moon regions (also called the crossover or bridge sections) of a single-shot inductor, where eddy current flow is circumferential.

Normally the single-shot method is better suited for hardening stepped parts where a relatively short (1.5–2 in. [38–50mm] long heated area is commonly minimum) or moderate length area is to be heat treated. This method is also better suited to cylindrical parts having axial symmetry and complex geometry including various diameters.

When scanning these types of parts, improper austenitization of certain areas may occur due to localized electromagnetic field distortion, for example. Insufficient quenching due to the deflection of quench flow not allowing it to properly impinge on the surface in various diameter regions may also occur. Both factors are considered undesirable and can cause low hardness, spotted hardness, or even cracking. For example, the use of scan hardening on stepped shafts with large shoulders, multiple and sizable diameter changes, and other geometrical irregularities and discontinuities (including fillets, flanges, undercuts, grooves, etc.) may produce severely non-uniform hardened patterns. In cases like this, a scan hardening inductor or progressive/continuous hardening system would be designed around the largest diameter that would have sufficient clearance for safe part processing.¹ However, variations in the shaft’s diameter, to a significant extent, will result in a corresponding substantial deviation in the workpiece-to-coil coupling in different sections of the shaft, potentially causing irregular austenization.

Besides that, sharp corners have a distinct tendency to overheat owing to the buildup of eddy currents, in particular when medium and high frequencies are used. The electromagnetic end and edge effects may also cause the shoulders to severely overheat while the smaller-diameter area near the shoulder (including undercuts and fillets) may have noticeable heat deficit. These factors may produce a hardness pattern that might grossly exceed the required minimum and maximum case depth range, making it unacceptable. Single-shot hardening is usually a better choice in such applications. As an example, Figure 1 shows some examples of components for which single-shot hardening would be a preferable method of heat treating.

Examples of components for which a single-shot hardening would be a preferable method of heat treating. (Courtesy of Inductoheat Inc., an Inductotherm Group company)

 

In some not so frequent cases, when hardening larger parts, there are advantages to the single-shot method over the scanning method, such as the reduction of shape/size distortion, enhanced metallurgical quality, and increased production rate.

Single-shot hardening may also be the preferred choice when shorter heat times/high production rates are desired. For example, in some applications, the time of heating for single-shot hardening can be as short as 2 s, though 4 to 8 s is more typical.

However, the single-shot method has some limitations as well. One of them is cost. Single-shot inductors are typically more expensive to fabricate compared to the coils used for scanning. This is because the single-shot inductor, to some degree, must follow the contour of the entire region required to be heated. Additionally, a single-shot inductor is usually able to harden only one specific part configuration, whereas a coil used for scanning may be able to harden a family of parts.

Besides that, in some case hardening applications using a scanning method, it is possible to apply certain pre-programmed pressure/force on a workpiece during heat treating. This allows distortion to be controlled. Single-shot hardening might also permit applying this technique but there might be some limitations.

Design Features of Single-Shot Inductors

Single-shot inductors are made of tubing, either 3-D printed or CNC-machined from solid copper to conform to the area of the part to be heated. This type of inductor requires the most care in fabrication because it usually has an intricate design and operates at high power densities, and the workpiece’s positioning is critical with respect to the coil copper profiling. Figure 2 shows several examples of induction heating of different components using single-shot inductors.

Several examples of induction heating of different components using single-shot inductors. (Courtesy of Inductoheat Inc., an Inductotherm Group company)

 

In order to provide the required temperature distribution before quenching, heat is sometimes applied in several short bursts (pulse heating) with a timed delay/soaking between them to allow for thermal conduction toward the areas that might be difficult to heat.

Single-shot inductors typically require higher power levels than used in scan hardening because the entire area of the workpiece that needs to be hardened is austenitized at once. This is the reason why single-shot hardening normally requires having a noticeably larger power supply compared to scan hardening, resulting in increased capital cost of power source. Additionally, the increased power usage and power densities combined with complex geometry can reduce the life of the inductor. For this reason, single-shot inductors often have shorter lives than scan inductors.

It is always important to keep in mind that, electrically speaking, the inductor is typically considered the weakest link in an induction system. For this reason, most single-shot inductors have separate coil-cooling and part-quenching circuits. The inductor will fail if power is increased to the point at which the water cannot adequately cool it. Additional cooling passages may be needed with high-power density, single-shot inductors. A high-pressure booster pump is also frequently required.

The next several installments of Dr. Valery Rudnev on . . . will continue the discussion on design features of single-shot inductors and equipment selection.

 

References

  1. Rudnev, D.Loveless, R.Cook, Handbook of Induction Heating, 2nd Edition, CRC Press, 2017.

 

Dr. Valery Rudnev on . . . Equipment Selection for Induction Hardening: Single-Shot Hardening, Part 1 Read More »

5th Generation Metals Heat Treat Manufacturer Partners with Furnace Supplier

A fifth-generation furnace manufacturer supporting the metals processing industry recently entered into a strategic partnership with a Florida-based furnace equipment supplier.

Gillespie & Powers Inc., headquartered in St. Louis, Missouri, will continue to offer Remelt Technologies’ homogenizing furnaces, DC casting machines, and DC casting automation to the North American aluminum industry.

“Gillespie & Powers Inc. is proud that Gary Bowden, president of Remelt Technologies, has entrusted them to continue providing equipment and services that will continue this legacy,” said Jack Gillespie, vice president of Gillespie & Powers.

Remelt Technologies, founded and owned by Bowden, has a 26-year history of supplying quality equipment and is involved in the design, manufacture, and installation of homogenizing furnaces and DC casting machines for secondary aluminum extrusion cast houses.

Gillespie & Powers is a 5th Generation family owned design, build, supplier of specialized furnaces supporting the metals processing industry. The company has over 80 years of experience in the design, supply, and installation of furnace equipment.

 

5th Generation Metals Heat Treat Manufacturer Partners with Furnace Supplier Read More »

10 Quick Heat Treat News Items to Keep You Current

10 Quick Heat Treat News Items to Keep You Current

Heat Treat Today offers News Chatter, a feature highlighting representative moves, transactions, and kudos from around the industry.

Personnel and Company Chatter

  • Roger Ross has been appointed the president of StandardAero‘s Airlines & Fleets division.  He will be located at the company’s Scottsdale, Arizona, headquarters office and be responsible for the largest division of StandardAero, with multiple sites in the U.S., Canada, Europe, Africa, and Australia.
  • An automotive wheel manufacturer based in Paris, Kentucky, announced the groundbreaking on its facility expansion to support plans to increase the production capacity of aluminum wheels. These expansions will introduce “cutting-edge technology and realization of high-level on-site capabilities” at Central Motor Wheel of America‘s manufacturing operations.
  • Greg Jennings has been appointed to the position of President and CEO at Thermal Product Solutions, LLC (TPS), a global manufacturer of thermal processing equipment. Jennings has held the position of Chief Financial Officer (CFO) at TPS since 2013. During his time as CFO, he was instrumental during the acquisition of Wisconsin Oven Corporation and Baker Furnace.
  • Work is now underway to expand the heat treatment capacity at Saar-Blankstahl to expand the annealing capacity of its subsidiary, Saarstahl AG is responding to an expected increase in worldwide demand for heat-treated bar material and higher-quality steels.
  • Six Gruenberg cleanroom ovens were shipped to the medical industry from Thermal Product Solutions.
  • An electrically heated top flow conveyor oven was sold by Wisconsin Oven Corporation to a global manufacturer in the machinery industry. The furnace will be used for curing “CPIG” material on plastic housings for electronic components.
  • An innovative contract manufacturer recently invested in a new aluminum extrusion press. Alexandria Industries will be able to increase its aluminum extrusion capabilities, extrude more complex product features, and hold tighter tolerances, while utilizing a variety of alloys. The press is made by Presezzi Extrusion Group (Vimercate, MB-Italy). Alexandria Industries will gain an extra 30 percent in extrusion capacity.
  • Dr. Rod Martin, vice president of technology at Element, has been awarded the 2019 Leslie Holliday Prize from the British Composites Society (BCS). The prize is in recognition of Dr. Martin’s significant contribution to the field of composite materials.
  • BEAMIT SpA, Fornovo di Taro, Italy, has successfully passed a Nadcap audit for heat treating, receiving Nadcap accreditation as a result. The Additive Manufacturing bureau provides services for the AM of both metal and ceramic parts, and as of January 2018 had installed two high vacuum furnaces conforming to standard AMS2750.
  • Thinker Ventures recently completed a new website for Diablo Furnaces at diablofurnaces.com. The new site features a mobile-friendly responsive design that adapts for viewing on desktops, smartphones, and tablets. Diablo Furnaces is a heat treating solution provider that is able to complete custom furnace design.

Heat Treat Today is pleased to join in the announcements of growth and achievement throughout the industry by highlighting them here on our News Chatter page. Please send any information you feel may be of interest to manufacturers with in-house heat treat departments especially in the aerospace, automotive, medical, and energy sectors to the editor at editor@heattreattoday.com

10 Quick Heat Treat News Items to Keep You Current Read More »

North American Steel Company Adds New Furnace, Expands Facility

As part of a second expansion to their facility, a North American steel company plans to install a second electric arc furnace with the assistance of a group of companies internationally active in plant construction and mechanical engineering for the steel and nonferrous metals industry.

North American steel producer Big River Steel (BRS) recently commissioned SMS Group with the expansion of its steel plant in Osceola, Arkansas. SMS Group will supply BRS with additional mechanical equipment, electrical and automation systems, and digitalization, which the group reports will increase the plant’s annual output.

David Stickler, CEO of Big River Steel
David Stickler, CEO of Big River Steel

“I have purchased several technologically advanced steel production facilities from SMS over the past twenty years and I am fully confident that SMS group will again deliver a high-quality mill that sets the standard in terms of product capability, energy efficiency and environmental sustainability,” commented David Stickler, CEO of Big River Steel.

Following this second expansion of their facility, the steel plant will house two electric arc furnaces and two twin-ladle furnaces. In addition, Big River Steel commissioned Systems Spray Cooled for the installation of furnace cooling equipment at Big River’s Osceola facility, including furnace sidewall, roof, elbow, and off-gas duct work. SMS reports that installing an additional gas cleaning system will ensure compliance with environmental legislation. A second strand, a second tunnel furnace, and a further downcoiler will also be added to the Big River Steel’s CSP® plant, which reportedly produces coils up to 1,930 millimeters wide.

Big River Steel produces high-quality steels, including tube grade sheet for pipeline construction, silicon steels for a wide variety of energy and electric motor applications, and advanced high-strength steels for the U.S. automotive industry.

The hot coils produced in the CSP® plant are processed into high-grade cold strip in the downstream coupled pickling line/tandem cold mill. The continuous galvanizing line (CGL) will receive an additional coiler. For all the newly installed plants, SMS group is going to supply the mechanical equipment and the X-Pact® electrical and automation systems, including level 3.

Big River Steel
Big River Steel

Also in the second construction stage, the PQA® (Product Quality Analyzer) system developed by SMS group company MET/Con will be a central module of the process automation system. By capturing and evaluating all relevant production data on a continuous basis, PQA® monitors, documents and assures the product quality down to the finished cold strip along the complete production process. The system uses stored rules defined on the basis of expert knowledge to assess the coil quality in a semi-automatic procedure and, based on these assessments, takes “ship” or “block” decisions for the downstream processing of the strip or its dispatch.

This system then sends instructions for action to the operators while production continues in order to make them aware of any onset of irregularities within the production process and suggest countermeasures to be taken. This allows the operators to predictively intervene in the process before an incident becomes a problem, reducing the occurrence of failures along the production process which otherwise might have resulted in poor quality and downtimes. Over time, the system is intended to provide higher yield while increasing product quality.

Burkhard Dahmen, Chairman of the Managing Board of SMS Group
Burkhard Dahmen, Chairman of the Managing Board of SMS Group

“Working closely with the management and staff of Big River Steel, we have succeeded in digitalizing a highly complex steel plant in a way that meets the targets of stable and resource-saving production,” said Burkhard Dahmen, Chairman of the Managing Board of SMS group. “We are very pleased about Big River Steel’s decision to also award us the order for the next expansion stage of the steel plant and to continue on the proven successful way with SMS group as their partner.”

Additional News Source: Big River Steel Expands Production

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Cleaning Workpieces: Vacuum Vapor Degreasing

Source: VAC AERO International

 

In order to maintain the cleanliness of workpieces and baskets or fixtures in the vacuum heat treating or brazing process, it is helpful to establish a pre-treating cleaning practice. Vapor degreasing has emerged as a cleaning process with the acting principle that the solvents will dissolve the contaminants on the workpiece and remove them by dripping off the part. In this week’s Technical Tuesday article, a Best of the Web feature, we bring you an article from VAC AERO International addressing the development of the process, the steps involved in vapor degreasing, and comparisons with other cleaning methods.

Cleaning in a solvent offers a level of simplicity and forgiveness not seen in aqueous methods. At one time, solvent cleaning was considered mandatory for successful vacuum processing but environmental concerns (VOC and other emissions) and improvements to aqueous systems including drying technology has seen the industry shift to aqueous cleaning as the norm. Today, however, with the advent of vacuum technology, vacuum vapor degreasing has emerged as a viable alternative to aqueous processing.”

A preview:

Vacuum vapor degreaser schematic with operational sequence steps. (“Removal of Entrained Moisture from Powdered Metal Parts Using High-Temperature Solvent and Vacuum” PM2TEC 2003, via VAC AERO International)
Main image photo credit/caption: Vacuum Processing Systems LLC (via VAC AERO International) / Typical vacuum vapor degreaser 

Read more: “Vacuum Vapor Degreasing”

Cleaning Workpieces: Vacuum Vapor Degreasing Read More »

Vacuum Heat Treatment Provider Adds Third All-Metal Hot Zone Furnace

A vacuum heat treatment provider recently installed an all-metal hot zone vacuum furnace at their Souderton, Pennsylvania, location.

Solar Atmospheres
Solar Atmospheres

Solar Atmospheres added a third all-metal hot zone furnace for its climate-controlled room at its facility in Souderton, Pennsylvania. The additional furnace increases Solar’s capacity for processing sensitive materials such as PH stainless, nickel-chrome based superalloys, titanium, and ferritic and austenitic stainless steels.

Vacuum levels lower than 5 x 10-6 Torr can produce clean, bright results without contamination. Solar reports that the unique placement of isolation valves, an all-metal moly/stainless steel hot zone, and a stainless steel chamber in its new furnace allow it to attain the level of cleanliness mandated by aerospace and medical markets. The furnace also incorporates Solar Manufacturing’s latest SolarVac Polaris HMI control system for complete process automation.

Jamie Jones, President, Solar Atmospheres in Eastern PA
Jamie Jones, President, Solar Atmospheres in Eastern PA

“The increasing demands for cleanliness levels in critical aerospace and medical applications, and the growth in these markets paved the way for Solar Atmospheres to add capacity through this investment,” said Jamie Jones, President of Solar Atmospheres in Eastern PA.

Vacuum Heat Treatment Provider Adds Third All-Metal Hot Zone Furnace Read More »

IHEA Economic Report Released With Split Indicators

IHEA New Orders PMI May 2019

The Industrial Heating Equipment Association (IHEA) released its 12-page monthly Executive Economic Summary which contains an analysis of 11 key heat treat industry economic indicators. The organization has been providing this monthly report as a service to its members for several years, and it is a valuable source of economic data and analysis for companies supplying equipment, components, or consumables to the heat treating industry.

This month’s report was nearly evenly split between the eleven indices, with five moving upward and six moving downward.

According to IHEA economist, Chris Kuehl of the Armada Corporate Intelligence, the underlying concerns about tariffs and trade wars seems to be the primary inhibitor of greater economic growth. While nearly all of the indices are in the “growth” range of their curves, more of them are getting closer to the “contraction” range and could easily slip into contraction with additional dampening economic news.

IHEA CapEx 2019 05
IHEA CapEx 2019 05

Three of the five gainers were housing starts, capital investment, and PMI new orders, each showing modest gains.

Among the sliders, new automobile and light truck sales, steel consumption, and capacity utilization.

Generally, downward movements were stronger than upward movements this month, contributing to longer-term concern about a possible slow down in the economy.

Anne Goyer, Executive Director of IHEA
Anne Goyer, Executive Director of IHEA

To receive a copy of the full, 12-page report, contact Anne Goyer, executive director of IHEA by clicking here.

IHEA Economic Report Released With Split Indicators Read More »

Heat Treater Expands Nitriding, Induction Hardening Capacity

A heat treat and metallurgical services company recently unveiled plans to expand two of their four facilities this summer to better process applications in the aerospace, gears, and firearms industries, among others.

AHT Burton
AHT Burton

Advanced Heat Treat Corp. (AHT) announced building expansions for their Monroe, Michigan, and Waterloo, Iowa locations. Michigan AHT plans to increase the size of their pit to accommodate two larger nitriding units, while AHT Burton intends to add square footage for new equipment and related services, such as two recently acquired induction units.

AHT has not expanded the Michigan and Burton facilities since 2006 and 2007, respectively, and hopes to complete the projects by mid-summer. The company also recently increased the shop floor at a third facility which serves as company headquarters in Waterloo, Iowa.

Mike Woods, President, AHT
Mike Woods, President, AHT

“We’re very excited about the growth AHT has seen

AHT Michigan
AHT Michigan

over the past few years,” said AHT President Mike Woods. “Because of this, we felt it was necessary to expand our facilities and invest in additional equipment to better serve our customers and capture more of the market.”

Heat Treater Expands Nitriding, Induction Hardening Capacity Read More »

Heat Treat Today’s Automotive Digital Edition Goes Live

Heat Treat Today has launched Automotive Heat Treating special edition in print and digital form, the third print magazine and the second in a series of industry-specific quarterlies.

The print edition of Automotive Heat Treating entered the mail stream on June 24 and landed in the mailboxes of 6,000 automotive manufacturing suppliers and OEMs with more being distributed at Thermprocess 2019. The digital edition is available by clicking here or on the image to the right.

In this special magazine, Heat Treat Today delivers quality content both new and original as well as a round up of past automotive-related news, technical articles, and tips, including:

  • “Making Sense of Trade Wars” / Understand the different types of tariffs, where they are coming from, and what effect they may have on the heat treating world.
  • Heat Treat Brain Trust on Industry Innovations That Have Enhanced Automotive Heat Treating in Recent Years” / Recent, innovative, or helpful enhancements that have advanced the automotive heat treat industry.
  • “Nitrocarburizing for Automotive and Large-Volume Production” / Advantages and disadvantages of batch vs. continuous processing for automotive nitrocarburized parts.
  • “Continuous and Progressive Hardening: Frequency Selection” / Frequency selection for induction hardening equipment.
  • “How to Join Industry 4.0” / An edited transcript from a recent Heat Treat Radio interview unpacks how manufacturers with in-house heat treating can take their first steps into Industry 4.0.
  • “Carburizing Trends in the Automotive Heat Treating World” / Where we have been, where we are now, and what we can expect in the future in automotive carburizing.
  • “Thermomechanical Processing for Creating Bi-Metal Bearing Bushings” / The potential for creating and heat treating bi-metal bearing bushings consisting of steel 20MnCr5 and aluminum AA-6082 by closed-die-forging.

In October, Heat Treat Today will be publishing another special edition, featuring reader favorites, the 40 Under 40 Class of 2019 and 101 Heat Treat Tips. It will be sent to 6,000+ industry contacts. If you have related editorial content or if you would like to have your promotional message in this issue, please email doug@heattreattoday.com or editor@heattreattoday.com as soon as possible.

If you haven’t done so already, you might want to join Heat Treat Today’s “Leaders in Automotive Heat Treat” LinkedIn Group. Click here or on the image to the left to be taken there. You’ll need to sign in to LinkedIn before you can join the group.

 

Heat Treat Today’s Automotive Digital Edition Goes Live Read More »

The Heat Treatment of Aerospace Fasteners

Dan Herring is recognized as the summa wizard of heat treating. This paper, originally published in the October 2014 issue of Fastener Technology International (FTI), then reprinted in Heat Treat Today’s March 2019 Aerospace print edition, addresses the critical issue of strength-to-weight in aerospace fastener applications and materials.

 

 


Figure 1: Critical performance application demanding exotic fastener alloys – Jet Engines (photograph courtesy of Performance Review Institute)
Figure 1: Critical performance application demanding exotic fastener alloys – Jet Engines
(photograph courtesy of Performance Review Institute)

When we deal with applications where strength-to-weight ratio is a critical consideration (Fig. 1[1]), we often turn to solutions involving the so-called “light metals”, namely aluminum, beryllium, magnesium, and titanium, to enhance engineering performance while minimizing the weight of components and structures.

It is important to remember that light metals possess other physical properties, which may be of importance in selection or service, such as the good electrical and thermal conductivity of aluminum, the machinability and noise dampening of magnesium, or the extreme corrosion resistance of titanium. Our heat treatment processes must retain and, in some cases, enhance these properties.

Aerospace Fastener Applications and Materials

There are many types of fasteners used in aerospace structural assembly, which include solid rivets, pins with collars, bolts with nuts, and blind fasteners. Other fastener types including latches, straight pins, head pins, lock pins, cotter pins, quick-release multiple piece fasteners, retaining rings, and washers are also commonplace. Aerospace fastener materials include aluminum (e.g. 2024, 6061, 7075), titanium (e.g. Ti-6Al-4V, Ti-6Al-2Sn-4Zr-2Mo), superalloys (e.g., Waspaloy, Hastalloy, Inconel 718) and in some instances steel, stainless steels, tool steels, and nickel alloys (e.g. K-Monel).

Aluminum is the most common fastener material used in the aerospace industry and in many other transportation systems as well. This is because aluminum alloys in addition to having an excellent strength-to-weight ratio can be heat-treated to achieve relatively high strength. Aluminum is easy to form and is relatively low cost. The heat treatable aluminum grades are the 2xxx, 6xxx, and 7xxx series. Aircraft manufacturers, for example, use high-strength alloy 7075 to fasten aluminum aircraft structures. This alloy has zinc and copper added for strength and machinability.

Titanium also has a number of attractive properties including low density and elastic modulus making it a good candidate material for aerospace fasteners, both of the internally and externally threaded varieties. The use of nuts with lower modulus than the male fastener is known to reduce the stress concentration effect at the first thread and improves the distribution of load over the length of the engaged threads. Titanium fasteners are used when a combination of strength and corrosion properties are important, such as when composite materials are involved.

Superalloys are used in applications requiring performance under high operating temperatures, extreme corrosion environments, demands for high creep strength and high fatigue strength, and in cryogenic applications. Superalloy fasteners are found on solid rocket motors, aircraft gas turbine engines, airframes, space shuttle structures, and the like. The superalloys fall into three basic groups: the iron-nickel-base superalloys; the nickel-base superalloys and the cobalt-base superalloys. The iron-nickel-base superalloys evolved from stainless steel technology and are generally wrought. Nickel-base and cobalt-base superalloys can be either wrought or cast. Nickel-base superalloys can be used at the very highest temperatures, just below their melting temperatures of about 2200°F to 2500°F (1205°C to 1370°C).

Heat Treatment of Aluminum Fasteners [2,3]

Aluminum alloys are classified as either heat treatable or not heat treatable, depending on whether the alloy responds to precipitation hardening, the key characteristic being that the alloying elements show greater solubility at elevated temperatures than at room temperature.

Solution Heat Treating

Table 1: Solution Heat Treatment Temperature Range and Eutectic Melting Temperature for 2xxx Alloys
Table 1: Solution Heat Treatment Temperature Range and Eutectic Melting Temperature for 2xxx Alloys

Solution heat treatment involves heating the aluminum and alloys to a temperature slightly below the eutectic melting temperature. The objective of solution heat treatment is to maximize the amount of solute in solid solution. This requires heating the material close to the eutectic temperature and holding the material at temperature long enough to allow the alloy to become a homogenous solid solution. After solution heat treatment, the material is quenched to maintain the solute in supersaturated solid solution. Temperature control is crucial because the solution heat treatment and the eutectic melting temperatures are so close, especially for 2xxx series alloys (Table 1[2]).

Figure 2: A typical solution heat treatment operation for aluminum (photograph courtesy of Wisconsin Oven Corporation)
Figure 2: A typical solution heat treatment operation for aluminum (photograph courtesy of Wisconsin Oven Corporation)

Solution heat treating problems include oxidation, incipient melting, eutectic melting, and under-heating and can be overcome by close control of process and equipment variability. Solution heat treating and quenching of these alloys is typically accomplished in large high-temperature ovens. In some applications, the oven is supported above the quench tank (Fig 2).

Quenching

The purpose of quenching is to create a supersaturated solid solution at room temperature so that the aging process can strengthen the material. The amount of precipitation occurring during quenching reduces the amount of subsequent hardening possible. This is because as solute is precipitated from solution during quenching, it is unavailable for any further precipitation reactions. This results in lower tensile strength, yield strength, ductility, and fracture toughness.

The cooling effect of quenchants has been extensively studied and the influence of quench rate on mechanical properties has been quantified. For example, it was determined that the critical quenching temperature range for 7075 aluminum alloy is 750°F to 550°F (400°C to 290°C). At quench rates exceeding 840°F/sec (450°C/s), it has been determined that maximum strength and corrosion resistance is obtained. At intermediate quench rates of 840°F/sec to 212°F/sec (450°C/s to 100°C/s), the strength obtained is lowered, but the corrosion resistance is unaffected. Between 212°F/sec and 68°F/sec (100°C/s and 20°C/s), the strength decreased rapidly, and the corrosion resistance is at a minimum. At quench rates below 68°F/sec (20°C/s), the strength decreases rapidly, but the corrosion resistance improved. However, for a given quenching medium, the cooling rate through the critical temperature range was invariant no matter the solution heat treat temperature.

Problems occurring during quenching are typically distortion or inadequate properties caused by a slow quench, resulting in precipitation during quenching and inadequate supersaturation.

Aging

The aging process for aluminum involves either natural aging or artificial aging. Natural aging involves the rapid formation of GP (Guinier-Preston) zones from the supersaturated solid solution and from quenched-in vacancies with strength increasing rapidly with properties becoming quasi-stable after approximately 4 to 5 days. These alloys will continue to exhibit changes in properties as the years go by.

Many heat treatable aluminum alloys are artificially aged after quenching. Precipitation hardening (aging) involves heating the alloyed aluminum to a temperature in the 200ºF to 450°F (95ºC to 230ºC) range. At this temperature, the supersaturated solid solution, created by quenching from solution heat-treating, begins to decompose and accelerates precipitation in heat treatable alloys. The aging curves for the alloys vary; however, generally the higher the aging temperature, the shorter the time required to attain maximum properties.

Heat Treatment of Titanium Fasteners

Titanium alloys are typically classified as pure titanium, alpha, beta, and alpha-beta alloys. There are also so-called near alpha and near beta (i.e. metastable beta) phase alloys. Under equilibrium conditions, pure titanium and alpha (α) phase have hexagonal close-packed structures up to 1620°F (882°C), above which they transform to beta (β) phase having a body-centered cubic structure up to the alloy’s melting point.

Near alpha alloys typically have a small amount (1 to 2 %) of the stabilizing beta phase present. In near beta alloys, significant additions of the beta-stabilizing phase suppress the Ms temperature below room temperature and the beta phase is retained at room temperature by rapid cooling or quenching from the alpha-beta phase. The inherent properties of all these structures are quite different.

Titanium alloys have a complex heat treatment process (Table 2[4], 3).

Table 3: Heat Treatments for Metastable Beta Titanium Alloys
Table 3: Heat Treatments for Metastable Beta Titanium Alloys
Table 2: Heat Treatments for Alpha-Beta Titanium Alloys
Table 2: Heat Treatments for Alpha-Beta Titanium Alloys
Figure 3: typical vacuum furnace (Photograph Courtesy of Solar Atmospheres, Inc.)
Figure 3: typical vacuum furnace (Photograph Courtesy of Solar Atmospheres, Inc.)

Most superalloys are hardened using a solution treating and aging process (Table 4[3]). Solution treating involves heating the alloy to a temperature in the range of 1800°F (982°C) or higher, followed by gas quenching. In most cases, superalloys are processed in a vacuum furnace (Fig. 3) and do not require a rapid quench. Pressures of two bar or less are often sufficient for quenching. This is followed by aging (age hardening) at intermediate temperatures for extended periods of time. Normally, the complete solution treat and aging cycles can be programmed into the furnace so that unloading is not required between cycles. Certain superalloys, however, require other special treatments to develop required properties.

Table 4: Typical Solution Heat Treating and Aging Cycles for Select Wrought Superalloys
Table 4: Typical Solution Heat Treating and Aging Cycles for Select Wrought Superalloys

Summary

Fasteners account for a significant amount of component parts in aircraft, rotocraft, and space vehicles where strength, corrosion, and weight of structural assemblies are important. Fasteners play a critical role in defining the longevity, structural integrity, and design philosophy of most metallic aerospace structures.

Notes:

  • Cooling nomenclature: FC = furnace cooling; AC = air cooling; RAC = rapid air cool; OQ = oil quench; PQ = gas pressure quench.
  • Air cooling equivalent is defined as cooling at a rate not less than 22°C/min (40°F/minute) to 595°C (1100°F) and not less than 8°C/min (15°F/minute) from 595°C to 540°C (1100°F to 1000°F). Below 540°C (1000°F) any rate may be used.
  • To provide adequate quenching after solution heat treatment, cool below 540°C (1000°F) rapidly enough to carbide precipitation. Oil or water quenching may be required on thick sections.

References

  1. Leigh, Joanna, New Checklist for Nadcap Audits, Industrial Heating, November 2011.
  2. Mackenzie, D. Scott, Heat Treating Aluminum, HOT TOPICS in Heat Treatment and Metallurgy, Vol. 2 No. 7, July 2004.
  3. Herring, D.H., Atmosphere Heat Treatment Volume I, BNP Media Group, 2014.
  4. Herring, D.H., Vacuum Heat Treatment, BNP Media Group, 2012.
  5. Herring, D.H., Metallurgy of Aluminum and Aluminum Alloys Parts One and Two, white paper, 2006.

About the Author: Daniel Herring, The Heat Treat Doctor®, is a metallurgist, designer, and materials scientist who takes seriously the initiative to educate current and future generations of heat treaters in the ways of the industry. More about The Heat Treat Doctor® can be learned from his Heat Treat Consultants page. This paper was originally published in the October 2014 issue of Fastener Technology International (FTI), then reprinted in Heat Treat Today’s  March 2019 Aerospace print edition. It is published here with permission from the author.

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