Dan Heat Treat Doctor

Ask The Heat Treat Doctor®: Why and How Do We Heat Treat Gears? Part Two

/ AEROSPACE HEAT TREAT TECHNICAL CONTENT, CARBURIZING TECHNICAL CONTENT, HARDENING TECHNICAL CONTENT, INDUCTION HEATING TECHNICAL CONTENT, OP-ED, QUENCHING TECHNICAL CONTENT, VACUUM FURNACES TECHNICAL CONTENT

Ask The Heat Treat Doctor® has returned to bring sage advice to Heat Treat Today readers and to answer your questions about heat treating, brazing, sintering, and other types of thermal treatments as well as questions on metallurgy, equipment, and process-related issues. In this installment, Dan Herring continues his discussion on gear heat treatment, exploring vacuum and induction hardening methods for gears — from low-pressure carburizing for advanced materials to single shot and tooth-by-tooth induction techniques — and how each can be matched to the specific demands of any gear application.

This informative piece was first released in Heat Treat Today’s March 2026 Annual Aerospace Heat Treating print edition.

In Part One of this discussion (Air & Atmospheres Heat Treating, February 2026), we discussed various gear types, materials, and how they can be atmosphere heat treated. This month, we are focusing on vacuum and induction heat treating methods. Let’s learn more.

Vacuum Heat Treatment Processing Methods

Table A. Advanced Materials Processed by LPC

Vacuum processing can be used for most of the atmosphere treatments mentioned in Part One including carburizing (Figure 1). Low pressure carburizing (LPC) is a proven technology and the choice for many advanced applications in aerospace, automotive, off-highway, and motorsports markets, as well as the development of carburizing cycles for high-performance materials (Table A).

Figure 1. Typical commercial heat treat load of gears for vacuum carburizing (Otto and Herring 2007) | Image Credit: Photo courtesy of Midwest Thermal-Vac
Figure 2. Pyrowear 675 – LPC – anneal – double normalize – harden – anneal – deep freeze – double temper | Image Credit: The HERRING GROUP, Inc.

The range of effective case depths for most of these grades can range up to 2.0–3.0 mm (0.080–0.120 inches) without significant sacrifice of microstructure (Figure 2). Furnace variables, such as temperature uniformity (± 3°C or ± 5°F), control of cycle parameters (boost/diffuse times, gas flow rate, pressure, hydrocarbon type) and surface carbon optimize the microstructure, producing case uniformities of ± 0.05 mm (± 0.002 inches). Where permitted, the range of carburizing temperatures now includes the use of high temperature (> 980°C, or 1800°F) techniques.

All these advanced materials required extensive development testing to produce custom designed recipes to optimize cycle parameters. Also, quenching methods (Otto and Herring 2002) have improved, allowing us to achieve desired core properties with quenching parameter selection (high-pressure gas or oil) for distortion-sensitive and distortion-prone part geometries (Otto and Herring 2005, 2008).

Induction Hardening Methods

Various methods of hardening via applied energy are used in manufacturing gears, including flame hardening, laser surface hardening, and induction hardening.

Of the various types of applied energy processing, induction hardening is the most common. Induction heating is a process that uses alternating electrical current that induces a magnetic field, causing the surface of the gear teeth to heat. The area is then quenched resulting in an increase in hardness within the heated area. This process is typically accomplished in a relatively short time. The final desired gear performance characteristics are determined not only by the hardness profile and stresses but also by the steel composition and prior microstructure. External spur and helical gears, bevel and worm gears, racks, and sprockets are commonly induction hardened. Typical gear steels include AISI/SAE grades 1050, 1060, 1144, 4140, 4150, 4350, 5150, and 8650.

Figure 3. Patterns produced by induction hardening (Rudnev 2000)

The hardness pattern produced by induction heating (Figure 3) is a function of the type and shape of inductor used, as well as the heating method. Quenching or rapidly cooling the workpiece can be accomplished by spray or submerged quench. The media typically used for the quench is a water-based polymer. The severity of this quenchant can be controlled by the polymer’s concentration. Cooling rates are usually somewhere in between what would be obtained from pure water and oil. In some unusual situations compressed air or nitrogen is used to quench the part.

The most common methods for hardening gears and sprockets are by single shot (Figure 4) or the tooth-by-tooth method (Figure 5). Single shot often requires large kW power supplies but results in short heat/quench times and higher production rates. This technique uses a circumferential copper inductor, which will harden the teeth from the tips downward.

Figure 4. Typical single shot induction hardening operation | Image Credit: Photo courtesy of Ajax-Tocco-Magnethermic
Figure 5. Tooth-by-tooth induction hardening of a helical gear | Image Credit: Photo courtesy of Ajax-Tocco-Magnethermic

The larger and heavier loaded gears (where pitting, spalling, tooth fatigue, and endurance are issues) need a hardness pattern that is more profiled like those produced by carburizing, which can be obtained by tooth-by-tooth hardening. This method is limited to gear tooth sizes with modulus 4.23–5.08 (6 or 5 DP) using frequencies from 2 to 10 kHz and about 2.54 (10 DP) using a range of 25 to 50 kHz.

The lower the frequency, the deeper the case depth. Tooth-by-tooth hardening is a slow process and usually reserved for gears and sprockets that are too large to single shot due to power constraints. The process involves heating the root area and side flanks simultaneously, while cooling each side of the adjacent tooth to prevent temper-back on the backside of each tooth. The induction system moves the coil at a pre-programmed rate along the length of the gear. The coil progressively heats the entire length of the gear segment while a quench follower immediately cools the previously heated area. The distance from the coil to the tooth is known as coupling or air gap. Any changes in this distance can yield variation in case depth, hardness, and tooth distortion. The gear is indexed after each tooth has been hardened, often skipping a tooth. This requires at least two full revolutions in the process to complete the hardening of all teeth. Straight, spur, and helical gears up to 5.5 m (210 inches) weighing 6,800 kg (15,000 lb) have been processed with this method. The entire process yields a repeatable soft tip of the tooth with hard root and flank. In other applications, the tip and both flanks can be hardened simultaneously and yield a soft root.

In Summary

Today’s design engineer has the good fortune of being able to choose from a number of heat treatment technologies for any given type of gear material and design. When selecting a gear hardening method, it is essential to specify not only the desired mechanical and metallurgical properties, but the critical dimensions that must be held and even the desired stress state of the gears themselves. The secret to success is understanding the advantages and limitations of each technology and taking these into consideration when determining the overall cost of gear manufacturing.

References

Herring, Daniel H. 2004a. “Gear Heat Treatment: The Influence of Materials and Geometry.” Gear Technology, March/April.

Herring, Daniel H. 2004b. “Reducing Distortion in Heat-Treated Gears.” Gear Solutions, June.

Herring, Daniel H. 2007a. “Oil Quenching Technologies for Gears.” With Steven D. Balme. Gear Solutions, July.

Herring, Daniel H. 2007b. “Heat Treating Heavy Duty Gears.” With Gerald D. Lindell. Gear Solutions, October.

Herring, Daniel H. 2012–2016. Vacuum Heat Treatment. Vols. 1–2. BNP Media Group.

Herring, Daniel H. 2014–2015. Atmosphere Heat Treatment. Vols. 1–2. BNP Media Group.

Herring, Daniel H., Gerald D. Lindell, D. J. Breuer, and B. Matlock. 2001. “Atmosphere vs. Vacuum Carburizing.” Heat Treating Progress, November.

Herring, Daniel H., Gerald D. Lindell, D. J. Breuer, and B. Matlock. 2002. “An Evaluation of Atmosphere and Vacuum Carburizing Methods for the Heat Treatment of Gears.” In Off-Highway Conference Proceedings. SAE International.

Otto, Frederick J., and Daniel H. Herring. 2002a. “Gear Heat Treatment: Today and Tomorrow, Part 1.” Heat Treating Progress, June.

Otto, Frederick J., and Daniel H. Herring. 2002b. “Gear Heat Treatment: Today and Tomorrow, Part 2.” Heat Treating Progress, July/August.

Otto, Frederick J., and Daniel H. Herring. 2005. “Vacuum Carburizing of Aerospace and Automotive Materials.” Heat Treating Progress, January/February.

Otto, Frederick J., and Daniel H. Herring. 2007. “Advancements in Precision Carburizing of Aerospace and Motorsports Materials.” Heat Treating Progress, May/June.

Otto, Frederick J., and Daniel H. Herring. 2008. “Improvements in Dimensional Control of Heat Treated Gears.” Gear Solutions, June.

Rudnev, V. 2000. “Gear Heat Treating by Induction.” Gear Technology, March/April.

About the Author

Dan Herring
“The Heat Treat Doctor”
The HERRING GROUP, Inc.

Dan Herring has been in the industry for over 50 years and has gained vast experience in fields that include materials science, engineering, metallurgy, new product research, and many other areas. He is the author of six books and over 700 technical articles.

For more information: Contact Dan at dherring@heat-treat-doctor.com.

For more information about Dan’s books: see his page at the Heat Treat Store.

Ask The Heat Treat Doctor®: Why and How Do We Heat Treat Gears? Part Two Read More »

Ask The Heat Treat Doctor®: Why and How Do We Heat Treat Gears? Part One

/ ATMOSPHERE AIR FURNACES TECHNICAL CONTENT, CARBURIZING TECHNICAL CONTENT, HARDENING TECHNICAL CONTENT, MANUFACTURING HEAT TREAT TECH, NITRIDING TECHNICAL CONTENT, NITROCARBURIZING TECHNICAL CONTENT, OP-ED

Ask The Heat Treat Doctor® has returned to bring sage advice to Heat Treat Today readers, answer questions about heat treating, brazing, sintering, and other types of thermal treatments, as well as metallurgy, equipment, and process-related issues. In this installment, Dan Herring examines the essential role of heat treatment in gear performance: exploring the key material and design considerations for power transmission gears, the difference between through hardening and case hardening, and the atmosphere heat treatment processes — from carburizing and carbonitriding to nitriding and nitrocarburizing — that determine how well a gear handles load, wear, and fatigue in heavy-duty applications.

This informative piece was first released in Heat Treat Today’s February 2026 Annual Air & Atmosphere Heat Treating print edition.

Have questions or feedback? We’d love to hear from you — reach out to our editorial team at editor@heattreattoday.com.

Gears play an essential role in the performance of many products that we rely on in our everyday lives. When we think about gears, we generally separate them into two categories: motion-carrying and power transmission. Motion-carrying gears are generally nonferrous alloys or plastics, while load bearing power transmission gears (Figure 1) are usually manufactured from ferrous alloys and are intended for heavy-duty service applications.

Figure 1. Typical off-highway truck power transmission gears | Image Credit: The Heat Treat Doctor®

Gear Materials & Engineering

Power transmission gears involve a wide variety of steels and cast irons. In all gears, the choice of material must be made only after careful consideration of the performance demanded by the application end-use and total manufactured cost, taking into consideration such issues as pre- and post-machining economics.

Key design considerations require an analysis of the type of applied load, whether gradual or instantaneous, and the desired mechanical properties, such as bending fatigue strength or wear resistance — all of which will define core strength and heat treating requirements.

Figure 2. Stress profile in a heavy-duty transmission gear | Image Credit: The Heat Treat Doctor®

It is important for the designer to understand that each area in the gear tooth profile sees different service demands (Figure 2). Consideration must be given to the forces that will act on the gear teeth with tooth bending and contact stress, resistance to scoring and wear, and fatigue issues being paramount. For example, in the root area, good surface hardness and high residual compressive stress are desired to improve endurance or bending fatigue life. At the pitch diameter, a combination of high hardness and adequate subsurface strength are necessary to handle contract stress and wear and to prevent spalling.

Some of the factors that influence fatigue strength are:

  • Hardness distribution, a function of:
    • Case hardness
    • Case depth
    • Core hardness
  • Microstructure, a function of:
    • Retained austenite percentage
    • Grain size
    • Carbide size, type, and distribution
    • Non-martensitic phases
  • Defect control, a function of:
    • Residual compressive stress
    • Surface finish and geometry
    • Intergranular toughness

In the total manufacturing scheme, a synergistic relationship must exist between the material selection process, engineering design, and manufacturing (including heat treatment). A balance of the priorities in each discipline must be reached to achieve the optimization necessary for the ultimate performance of the gear design. This is often not an easy task.

Various atmosphere heat treatment methods are used for most types of gears including pre-hardening steps (e.g., annealing, normalizing, stress relief) and hardening processes (e.g., neutral hardening and case hardening).

Hardening

Neutral (aka through hardening) refers to heat treatment methods that do not produce a case. Examples of commonly through-hardened gear steels are AISI/SAE grades 1045, 4130, 4140, 4145, 4340, and 8640. It is important to note that hardness uniformity should not be assumed throughout the gear tooth. Since the outside of a gear is cooled faster than the inside, there will be a hardness gradient developed. The final hardness is dependent on the amount of carbon in the steel. The depth of hardness depends on the hardenability of the steel.

Through hardening can be performed either before or after the gear teeth are cut. When gear teeth will be cut after the part has been hardened, machinability becomes an important factor based on final hardness. The hardness is achieved by heating the material into the austenitic range, typically 815°C–875°C (1500°F–1600°F), followed by quenching and tempering.

Case Hardening

By contrast, case hardening is used to produce a hard, wear resistant case (surface layer) on top of a ductile, shock resistant interior (core). The idea behind case hardening is to keep the core of the gear tooth at a level under 40 HRC to avoid tooth breakage while hardening the outer surface to increase pitting resistance.

Carburizing

Figure 3. Atmosphere carburizing of large gears | Image Credit: Photograph courtesy of Aichelin Group

Atmosphere carburizing is the most common of the case hardening methods in use today and can handle a diverse range of part sizes and load configurations (Figure 3). In general, a properly carburized gear will be able to handle somewhere between 30–50% more load than a through-hardened gear. Examples of commonly carburized gear steels include AISI/SAE grades 1018, 4320, 5120, 8620, and 9310, as well as international grades, such as 20MnCr5, 17CrNiMo6, 18CrNiMo7-6, and 20MoCr4.

Atmosphere carburizing is typically performed in the temperature range of 870°C–955°C (1600°F–1750°F) although temperatures up to 1010°C (1800°F) are used for deep case work. Carburizing case depths can vary over a broad range, typically 0.13–8.25 mm (0.005–0.325 inches).

Carbonitriding

Carbonitriding is a modification of the carburizing process, not a form of nitriding. This modification consists of introducing ammonia into the carburizing atmosphere to add nitrogen to the carburized case as it is being produced. Examples of gear steels that are commonly carbonitrided include AISI/SAE 1018, 1117, and 12L14.

Carbonitriding is done at a lower temperature than carburizing, typically between 790°C–900°C (1450°F–1650°F), and for a shorter time. Combine this with the fact that nitrogen inhibits the diffusion of carbon, and what generally results is a shallower case than is typical for carburized parts. A carbonitrided case is usually between 0.075–0.75 mm (0.003–0.030 inches) deep.

Nitriding

Nitriding is another surface treatment process that has as its objective increasing surface hardness. One of the appeals of this process is that rapid quenching is not required, hence dimensional changes are kept to a minimum. It is not suitable for all gear applications; one of its limitations is that the extremely high surface hardness case produced has a more brittle nature than say that produced by the carburizing process. Despite this fact, in a number of applications, nitriding has proved to be a viable alternative. Examples of commonly nitrided gear steels include AISI/SAE 4140, 4150, 4340, and Nitralloy® 135M.

Nitriding is typically done in the range of 495°C–565°C (925°F–1050°F). Case depth and case hardness properties vary not only with the duration and type of nitriding being performed but also with steel composition, prior structure, and core hardness. Typically, case depths are between 0.20–0.65 mm (0.008–0.025 inches) and take from 10 to 80 hours to produce.

Nitrocarburizing (Ferritic or Austenitic)

Nitrocarburizing is a modification of nitriding, not a form of carburizing. In the process, nitrogen and carbon are simultaneously introduced into the steel while it is in a ferritic or at times an austenitic condition. A very thin “white” or “compound” layer is formed during the process, as well as an underlying “diffusion” zone. Like nitriding, rapid quenching is not required. Examples of gear steels that are commonly nitrocarburized include AISI/SAE grades 4140, 5160, 8620, and certain tool steels, such as H11 and H13.

Nitrocarburizing is normally performed at 550°C–600°C (1025°F–1110°F) and can be used to produce a 58 HRC minimum hardness, with this value increasing dependent on the base material. White layer depths range from 0.0013–0.056 mm (0.00005–0.0022 inches) with diffusion zones from 0.03–0.80 mm (0.0013–0.032 inches) being typical.

In Summary

There are many ways to heat treat gears. While atmosphere heat treatment (discussed above) is perhaps the most widely used technology today, other types of heat treatments, namely vacuum and induction hardening, are becoming more and more common methods. These will be discussed in Part Two.

About the Author

Dan Herring
“The Heat Treat Doctor”
The HERRING GROUP, Inc.

Dan Herring has been in the industry for over 50 years and has gained vast experience in fields that include materials science, engineering, metallurgy, new product research, and many other areas. He is the author of six books and over 700 technical articles.

For more information: Contact Dan at dherring@heat-treat-doctor.com.

For more information about Dan’s books: see his page at the Heat Treat Store.

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Ask The Heat Treat Doctor®: Hot Topic for a Cold Day — Why Is Hot Gaseous Corrosion So Devastating?

/ ATMOSPHERE AIR FURNACES TECHNICAL CONTENT, CARBURIZING TECHNICAL CONTENT, MANUFACTURING HEAT TREAT TECH, OP-ED

Ask The Heat Treat Doctor® has returned to bring sage advice to Heat Treat Today readers, answer questions about heat treating, brazing, sintering, and other types of thermal treatments, as well as metallurgy, equipment, and process-related issues. In this installment, Dan Herring examines the devastating effects of hot gaseous corrosion on furnace alloys: exploring the mechanisms behind metal dusting, the gas-solid reactions that drive catastrophic carburization, and the mitigation strategies to extend the life of heat treaters’ most valuable furnace components.

This informative piece was first released in Heat Treat Today’s January 2026 Annual Technologies To Watch print edition.

Have questions or feedback? We’d love to hear from you — reach out to our editorial team at editor@heattreattoday.com.

Corrosion is a concern experienced by everyone involved in manufacturing industrial products. While there is a plethora of data and information on the effects of corrosion on engineered materials available (sources provided in the references section of this column), most corrosion engineers are focused on aqueous corrosion. By contrast, heat treaters must understand the effects of hot gaseous corrosion, especially on our furnace alloys. Let’s learn more.

Corrosion Basics

It is important to understand that all materials are chemically unstable in some environments and corrosive attack will always occur. In the scientific world, it can often be modeled and its effects predicted by studying thermodynamic data and knowing which of the many corrosion-related chemical states are active. In our world, however, it is equally important to understand the various forms of corrosion, namely:

  • Dezincification (aka selective leaching)
  • Electrolytic
  • Erosion
  • Galvanic (or two metal) action
  • General (aka uniform) attack
  • Intergranular attack
  • Pitting
  • Stress corrosion

The greater the metal’s solubility, the greater the degree and severity of the corrosive attack. There are many important variations of these forms of corrosion; two of the most important are 1) localized corrosive attack (e.g. pits, intergranular attack, crevices) and 2) interaction with mechanical influences (e.g., stress, fatigue, fretting). These actions are frequently rapid and have catastrophic effects.

The number of ways to combat corrosion have been well-documented, including alloying to produce better corrosion resistance materials; cathodic protection (via sacrificial anodes); coatings (metallic or inorganic); organic coatings (e.g. paints); metal purification; alteration of the environment; and nonmetallic or design (i.e., physical) changes.

Heat Resistant Alloys

Furnace interiors contain numerous examples of heat-resistant nickel-chromium-iron (Ni-Cr-Fe) alloys, including radiant tubes, fans, heating elements, roller rails and rollers, thermocouple protection tubes, chain guides, and atmosphere inlet tubes, to name a few. Baskets, grids, and fixtures are other examples. These alloys are normally selected based on their strength (at temperature) rather than resistance to corrosive attack.

Since these heat-resistant alloy parts are often the most expensive furnace components, heat treaters must understand how they can be attacked and what can be done to extend their life by minimizing or preventing corrosion.

Gas-Solid Reactions

A chemical reaction involving a (non-equilibrium) gas or gas mixture and a solid is classified as a gas-solid reaction. Examples of intermediate and high temperature reactions of this type include oxidation, sulfidation, carburization, and nitriding. Effects of gases containing vapors of chlorine, fluorine, and effluents from deposits of various alkaline chemicals (from cleaning compounds) and even phosphates are also problematic. The principles are the same for all types — only the details differ. As heat treaters, our interest is in controlling, retarding, or suppressing these reactions to prevent unwanted corrosion, gasification, or embrittlement of the furnace alloy or materials being processed.

Examples of Catastrophic Carburization (a.k.a. Metal Dusting)

Figure 1. Pusher furnace alloy fan and shaft assembly | Image Credit: The Heat Treat Doctor®

Metal dusting (Figure 1) is a hot gaseous corrosion phenomenon in which a metallic component disintegrates into a dust of fine metal and metal oxide particles mixed with carbon.

Generally, metal dusting occurs in a localized area, and how rapidly the disintegration progresses is a function of temperature, the composition of the atmosphere and its carbon potential, and the material. Other significant factors include the geometry of the system, reaction kinetics, diffusivities of alloy components, the specific-volume ratio of new and old phases, and the ultimate plastic strain.

Metal dusting usually manifests itself as pits or grooves on the surface, or as an overall surface attack in which the metal can literally be eaten away in a matter of days, weeks, or months. As an example, this writer has seen a 330-alloy plate mounted underneath a refractory-lined inner door of an integral quench furnace (where atmosphere passes underneath the door and into the quench vestibule) reduced in thickness from 12.5 mm (0.50 in) to less than 0.75 mm (0.03 in) in a little over two months.

Figure 2. 330 alloy radiant tube removed after six months of use (rotary retort furnace) | Image Credit: The Heat Treat Doctor®
Figure 3. Microstructural view: catastrophic carburization | Image Credit: The Heat Treat Doctor®

In another example, a metallographic investigation performed by this writer on a failed wrought 330 alloy radiant tube (Figure 2) was conducted. Optical microscopy of the inside (Figure 3) and outside diameter surfaces in the attacked area revealed evidence of massive carbides. These carbides are formed by the reaction of carbon with chromium, depleting the matrix of chromium in regions adjacent to the carbides. Grain detachment and subsequent failure by erosion then occurred.

How Does It Occur?

In general, catastrophic carburization of ferrous alloys proceeds via the formation and subsequent disintegration of metastable carbide. The first step in the process is absorption of the gaseous phase on the surface of the metal; the more reactive this phase, the easier it decomposes or is catalytically decomposed (in the case of iron) on the surface. This step is followed by diffusion of carbon atoms from the surface into the bulk metal.

As a result, there is a continuous buildup of carbon within the surface layer. As this layer becomes saturated with carbon, a stable carbide, metastable carbide, or an active carbide complex forms, which then grows until it reaches a state of thermodynamic instability, at which point it rapidly breaks down into the metal plus free carbon.

It’s at this stage that the metal disintegrates to a powder as the result of plastic deformation and subsequent fracture in the near-surface layer. The process is controlled by internal stresses due to phase transformation; in other words, competition between stress generation and relaxation exceeds the ultimate strength in this near-surface layer and causes fracture to occur.

In Ni-Cr-Fe alloys, the phenomenon occurs slower (but does not stop) since the disintegration leads to larger metal particles, which are less active catalysts for carbon deposition than the fine iron particles that form with ferrous metals. Therefore, the mass gain from carbon depositing onto high-nickel alloys is much lower. Also, the decomposition of high-nickel alloys occurs by graphitization and not via unstable carbides.

Pourbaix-Ellingham Diagrams

Thermodynamics can be applied to solid-gas reactions to obtain equilibrium dissociation pressures below which no reactions occur. Data and diagrams are available for the free energies of formation versus temperature for most metallic compounds. An interesting use of Pourbaix diagrams (generally reserved for mapping out possible stable equilibrium phases of an aqueous electrochemical system) as a predictor of stable alloy systems is found by superimposing the various elemental constituents. These diagrams are read much like a standard phase diagram (with a different set of axes).

In Summary

Hot gaseous corrosion should be an area of focus for every heat treater to extend the life of alloy components, reduce downtime, and save money. Mitigation in the form of alloy selection, equipment design, type of atmosphere, process/cycle selection, and idling temperatures will play a huge role in extending the life of our furnace alloys, baskets, and fixtures.

References

ASM International. 1971. Oxidation of Metals and Alloys.

ASM International. 2003. ASM Handbook. Vols. 13A–C.

Fontana, Mars G., and Norbert D. Greene. 2008. Corrosion Engineering. New York: McGraw-Hill.

Herring, D. H. 2003. “What to Do About Metal Dusting.” Heat Treating Progress, August.

Herring, Daniel H. 2015. Atmosphere Heat Treatment. Vol. 2. Troy, MI: BNP Media Group.

Javaheradashti, Raza. 2008. Microbiologically Induced Corrosion. Berlin: Springer-Verlag.

NACE International. www.nace.org.

Nateson, K. 1980. Corrosion–Erosion Behavior in Metals. Warrendale, PA: Metallurgical Society of AIME.

National Bureau of Standards. 1978. Gas Corrosion of Metals.

Pourbaix, Marcel. 1974. Atlas of Chemical and Electrochemical Equilibria in Aqueous Solutions. Houston, TX: NACE International.

Pourbaix, Marcel. 1998. Atlas of Chemical and Electrochemical Equilibria in the Presence of a Gaseous Phase. Houston, TX: NACE International.

Schweitzer, Philip A. 1996. Corrosion Engineering Handbook. New York: Marcel Dekker.

Staehle, R. W. 1995. “Engineering with Advanced and New Materials.” Materials Science and Engineering A 198 (1–2): 245–56.

Stempco, Michael J. 2011. “The Ellingham Diagram: How to Use It in Heat-Treat-Process Atmosphere Troubleshooting.” Industrial Heating, April.

Uhlig, Hubert H. 2008. Corrosion and Corrosion Control. Hoboken, NJ: Wiley-Interscience.

Fabian, R., ed. 1993. Vacuum Technology: Practical Heat Treating and Brazing. Materials Park, OH: ASM International.

The Boeing Company. n.d. “Practical Vacuum Systems Design Course.”

About the Author

Dan Herring
“The Heat Treat Doctor”
The HERRING GROUP, Inc.

Dan Herring has been in the industry for over 50 years and has gained vast experience in fields that include materials science, engineering, metallurgy, new product research, and many other areas. He is the author of six books and over 700 technical articles.

For more information: Contact Dan at dherring@heat-treat-doctor.com.

For more information about Dan’s books: see his page at the Heat Treat Store.

Ask The Heat Treat Doctor®: Hot Topic for a Cold Day — Why Is Hot Gaseous Corrosion So Devastating? Read More »

Ask The Heat Treat Doctor®: Why Use Partial Pressure in Vacuum Furnaces?

/ HARDENING TECHNICAL CONTENT, MEDICAL HEAT TREAT TECHNICAL, VACUUM FURNACES TECHNICAL CONTENT

Ask The Heat Treat Doctor® has returned to bring sage advice to Heat Treat Today readers and to answer your questions about heat treating, brazing, sintering, and other types of thermal treatments as well as questions on metallurgy, equipment, and process-related issues. In this installment, Dan Herring explains how partial pressure atmospheres prevent evaporation and achieve bright, oxide-free parts in vacuum furnaces.

This informative piece was first released in Heat Treat Today’s December 2025 Annual Medical & Energy Heat Treat print edition.

Have questions or feedback? We’d love to hear from you — reach out to our editorial team at editor@heattreattoday.com.

Operating in vacuum can often lead to problems related to evaporation, that is, literally “boiling away” elements present in the materials being heat treated. This affects surface integrity, functionality, performance, and in some rare cases altering the chemical composition of the base (or filler) metal.

One way to overcome this problem is to introduce a gas partial pressure higher than that of the material’s vapor pressure. Different gas choices, introduction methods, and controls are available to the heat treater. The natural question is, how and when should they be used? Let’s learn more.

What is Partial Pressure?

In simplest terms, the partial pressure of a gas introduced into a vacuum furnace is the force exerted by that gas (or gases) constrained in the vacuum vessel. If only a single gas is present, the partial pressure of the system is the same as the total pressure. For a multi-gas system, air is a good example to look at. At sea level with atmospheric pressure 760 torr (760 mm Hg) and at an altitude of 3,657 m (12,000 ft), the atmospheric pressure is only 483 Torr (Table A).

Table A. Partial Pressure of Individual Gases Present in Air | Source: Jones 1997

In vacuum systems, when the chamber atmosphere is evacuated to a high enough vacuum level — commonly between 10⁻³ Torr (0.1 micron) and 10⁻⁵ Torr (0.01 microns) — issues of evaporation are likely to occur during heat up and holding at temperature. As such, nitrogen or a truly inert gas is introduced below a predetermined temperature at a controlled rate to a fixed partial pressure range and then controlled within this range. One then isolates the high vacuum portion of the pumping system and employs bypass circuitry using the mechanical pump to introduce a continuous flow of gas equal to the pumping capacity (throughput) at the required operating pressure (Figure 1 below).

Figure 1. Typical partial pressure piping on a vacuum furnace
Key:
A: Incoming gas supply line
B: Backfill line
C: Quench solenoid
D: Partial pressure line
E: Partial pressure solenoid valve
F: Partial pressure (micrometer) needle value
G: Inlet into furnace
Source: Courtesy of Vac-Aero International

Why Do We Need to Use Partial Pressure in a Vacuum Furnace?

There is no hard and fast rule for partial pressure settings used for processing various materials in the heat treat industry. However, from a practical standpoint, there are two process considerations for determining partial pressure. The first is the metal-oxide reduction partial pressure. The partial pressure of oxygen at a given temperature determines the direction of the reaction and consequently whether the part is “bright” or “discolored” (oxidized). These values are typically in the range of 10⁻⁶ Torr to 10⁻² Torr. This is why materials like titanium alloys and superalloys must be processed at extremely low vacuum levels. The second consideration is the vaporization of metal at high temperature and hard vacuum. The metal solid-to-vapor partial pressures require higher pressures to avoid alloy depletion. These higher pressures often produce sufficient dilutions of contaminants to drive the reaction to be reducing.

What is often overlooked or misunderstood is that higher levels of partial pressure “dilute” any oxygen or water vapor partial pressure but still can produce oxide free “bright” parts at higher pressures. This dilution also occurs, for example when a retort is purged with nitrogen or argon to achieve clean parts. The oxygen partial pressure is reduced by dilution rather than by vacuum. In addition, it cannot be overemphasized that oxidation present on parts from exposure to the atmosphere and moisture absorbed by the furnace lining when the door is open are critical in running clean work. Oxidation occurs on heat up, but when the temperature is high enough and conditions are right, we can reverse the oxidation reaction so the parts will clean up. This is why it is harder to bright temper than to bright harden.

In batch vacuum furnaces, combination hardening and tempering cycles are used to take advantage of the furnace configuration in which parts stay in the furnace for the full process. Often, the same parts will discolor if tempered in the same furnace after they have been removed and the furnace exposed to air.

Also, a thorough understanding of the required component properties and material characteristics (e.g. alloy composition, grain size, hardenability response) is needed to design the final vacuum heat treat cycles and select the final partial pressure settings.

Figure 2. Chromium deposits / discoloration in the area of a graphite cooling nozzle | Source: The HERRING Group, Inc

For example, stainless steels, tool steels, and more exotic alloys run in a vacuum furnace will benefit substantially from the use of partial pressure atmospheres. In most heat treat shops, partial pressure cycles begin around 760°C (1400°F) at pressure from 1–1.5 Torr (1000–1500 microns). This is primarily because chromium present in many of these materials and in our baskets/fixtures evaporates noticeably at temperatures and pressures within normal heat treatment ranges. At around 990°C (1800°F), chromium will vaporize rapidly as a function of both vacuum level and time. In general, the practical operating vacuum level for most materials is significantly above their equilibrium vapor pressures. It is also helpful at times to know the temperature at which individual elements exceed a critical (10⁻⁶ g/cm²-s) vaporization rate (Herring 2015).

In practice, heat treaters often observe greenish discoloration (chromium oxide) on the interior of their vacuum furnaces (Figure 2), the result of chromium vapor reacting with air leaking into the hot zone. Otherwise, the evaporation deposit is bright and mirror-like. To avoid these types of deposits contaminating both the furnace and the parts run in it, an operating partial pressure between 1 Torr and 5 Torr (1,000 microns to 5,000 microns) is typical for parts that will boil away their elemental constituents.

Chromium Coloration

Heat treaters should be aware that although the most common color of chromium discoloration is green, the color is dependent on chromium’s oxidation state (Table B). For example, Cr (II) compounds typically appear blue, Cr (III) compounds appear green, and Cr (VI) compounds appear orange or red.

Notes: * Most commonly observed colors
Table B. Oxidation Colors of Chromium and Chromium Compounds

Table B provides a more detailed breakdown of chromium’s oxidation states and associated colors.

Which Partial Pressure Gas(es) Can We Use?

Argon, nitrogen, and hydrogen are the most common partial pressure gases. Often, argon is preferred as it is a truly inert gas and tends to “sweep” the hot zone; that is, being a heavier molecule, it tends to reduce evaporation compared with nitrogen or hydrogen. Specialized applications, such as those in the electronics industry, may use helium or even neon (if an ionizing gas is needed). Gases having a minimum purity of 99.99% and a dew point of -60°C (-76°F) or lower should be specified.

Certain cautions are in order. For example, nitrogen may react with certain stainless steels and titanium bearing alloys resulting in surface nitriding. In the case of hydrogen, the normally near neutral vacuum atmosphere can be sharply shifted to a reducing atmosphere to prevent oxidation of sensitive process work or for furnace/fixture bakeout/cleanup cycles. Embrittlement by hydrogen is a concern for certain materials (e.g., Ti, Ta).

Figure 3. 410 stainless steel housings, hydrogen partial pressure (1,000 microns) at 1010°C (1850°F) | Source: Courtesy of Vac-Aero International, Inc
Figure 4. Knee implants (cobalt-chromium-molybdenum alloy) vacuum heat treated under an argon partial pressure at 1 Torr (1,000 microns) to prevent elemental evaporation | Source: Courtesy of Vac-Aero International, Inc

In Summary

Partial pressure atmospheres are required in many heat treating and brazing operations to achieve desired results. Introduction of the partial pressure gas into the furnace hot zone at one or more locations and controlling the partial pressure injection gas stream as a continuous flow, rather than trying to operate at a specific pressure, are critical considerations. The choice of partial pressure gas is also important both from a cost and quality standpoint.

References

Herring, Daniel H. 2014. Vacuum Heat Treatment. Vol. 1. Troy, MI: BNP Media.

Herring, Daniel H. 2015. Vacuum Heat Treatment. Vol. 2. Troy, MI: BNP Media.

Houghton, R., Jr. n.d. Private correspondence, Spectrum Thermal Processing.

Jones, W. R. 1997. “Partial Pressure Vacuum Processing – Part I and II.” Industrial Heating, September/October.

Jones, William. n.d. Private correspondence, Solar Atmospheres Inc.

Fabian, R., ed. 1993. Vacuum Technology: Practical Heat Treating and Brazing. Materials Park, OH: ASM International.

The Boeing Company. n.d. “Practical Vacuum Systems Design Course.”

About the Author

Dan Herring
“The Heat Treat Doctor”
The HERRING GROUP, Inc.

Dan Herring has been in the industry for over 50 years and has gained vast experience in fields that include materials science, engineering, metallurgy, new product research, and many other areas. He is the author of six books and over 700 technical articles.

For more information: Contact Dan at dherring@heat-treat-doctor.com.

For more information about Dan’s books: see his page at the Heat Treat Store.

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