OP-ED

Ask The Heat Treat Doctor®: Why and How Do We Heat Treat Gears? Part Two

Ask The Heat Treat Doctor® has returned to bring sage advice to Heat Treat Today readers and to answer your questions about heat treating, brazing, sintering, and other types of thermal treatments as well as questions on metallurgy, equipment, and process-related issues. In this installment, Dan Herring continues his discussion on gear heat treatment, exploring vacuum and induction hardening methods for gears — from low-pressure carburizing for advanced materials to single shot and tooth-by-tooth induction techniques — and how each can be matched to the specific demands of any gear application.

This informative piece was first released in Heat Treat Today’s March 2026 Annual Aerospace Heat Treating print edition.


In Part One of this discussion (Air & Atmospheres Heat Treating, February 2026), we discussed various gear types, materials, and how they can be atmosphere heat treated. This month, we are focusing on vacuum and induction heat treating methods. Let’s learn more.

Vacuum Heat Treatment Processing Methods

Table A. Advanced Materials Processed by LPC

Vacuum processing can be used for most of the atmosphere treatments mentioned in Part One including carburizing (Figure 1). Low pressure carburizing (LPC) is a proven technology and the choice for many advanced applications in aerospace, automotive, off-highway, and motorsports markets, as well as the development of carburizing cycles for high-performance materials (Table A).

Figure 1. Typical commercial heat treat load of gears for vacuum carburizing (Otto and Herring 2007) | Image Credit: Photo courtesy of Midwest Thermal-Vac
Figure 2. Pyrowear 675 – LPC – anneal – double normalize – harden – anneal – deep freeze – double temper | Image Credit: The HERRING GROUP, Inc.

The range of effective case depths for most of these grades can range up to 2.0–3.0 mm (0.080–0.120 inches) without significant sacrifice of microstructure (Figure 2). Furnace variables, such as temperature uniformity (± 3°C or ± 5°F), control of cycle parameters (boost/diffuse times, gas flow rate, pressure, hydrocarbon type) and surface carbon optimize the microstructure, producing case uniformities of ± 0.05 mm (± 0.002 inches). Where permitted, the range of carburizing temperatures now includes the use of high temperature (> 980°C, or 1800°F) techniques.

All these advanced materials required extensive development testing to produce custom designed recipes to optimize cycle parameters. Also, quenching methods (Otto and Herring 2002) have improved, allowing us to achieve desired core properties with quenching parameter selection (high-pressure gas or oil) for distortion-sensitive and distortion-prone part geometries (Otto and Herring 2005, 2008).

Induction Hardening Methods

Various methods of hardening via applied energy are used in manufacturing gears, including flame hardening, laser surface hardening, and induction hardening.

Of the various types of applied energy processing, induction hardening is the most common. Induction heating is a process that uses alternating electrical current that induces a magnetic field, causing the surface of the gear teeth to heat. The area is then quenched resulting in an increase in hardness within the heated area. This process is typically accomplished in a relatively short time. The final desired gear performance characteristics are determined not only by the hardness profile and stresses but also by the steel composition and prior microstructure. External spur and helical gears, bevel and worm gears, racks, and sprockets are commonly induction hardened. Typical gear steels include AISI/SAE grades 1050, 1060, 1144, 4140, 4150, 4350, 5150, and 8650.

Figure 3. Patterns produced by induction hardening (Rudnev 2000)

The hardness pattern produced by induction heating (Figure 3) is a function of the type and shape of inductor used, as well as the heating method. Quenching or rapidly cooling the workpiece can be accomplished by spray or submerged quench. The media typically used for the quench is a water-based polymer. The severity of this quenchant can be controlled by the polymer’s concentration. Cooling rates are usually somewhere in between what would be obtained from pure water and oil. In some unusual situations compressed air or nitrogen is used to quench the part.

The most common methods for hardening gears and sprockets are by single shot (Figure 4) or the tooth-by-tooth method (Figure 5). Single shot often requires large kW power supplies but results in short heat/quench times and higher production rates. This technique uses a circumferential copper inductor, which will harden the teeth from the tips downward.

Figure 4. Typical single shot induction hardening operation | Image Credit: Photo courtesy of Ajax-Tocco-Magnethermic
Figure 5. Tooth-by-tooth induction hardening of a helical gear | Image Credit: Photo courtesy of Ajax-Tocco-Magnethermic

The larger and heavier loaded gears (where pitting, spalling, tooth fatigue, and endurance are issues) need a hardness pattern that is more profiled like those produced by carburizing, which can be obtained by tooth-by-tooth hardening. This method is limited to gear tooth sizes with modulus 4.23–5.08 (6 or 5 DP) using frequencies from 2 to 10 kHz and about 2.54 (10 DP) using a range of 25 to 50 kHz.

The lower the frequency, the deeper the case depth. Tooth-by-tooth hardening is a slow process and usually reserved for gears and sprockets that are too large to single shot due to power constraints. The process involves heating the root area and side flanks simultaneously, while cooling each side of the adjacent tooth to prevent temper-back on the backside of each tooth. The induction system moves the coil at a pre-programmed rate along the length of the gear. The coil progressively heats the entire length of the gear segment while a quench follower immediately cools the previously heated area. The distance from the coil to the tooth is known as coupling or air gap. Any changes in this distance can yield variation in case depth, hardness, and tooth distortion. The gear is indexed after each tooth has been hardened, often skipping a tooth. This requires at least two full revolutions in the process to complete the hardening of all teeth. Straight, spur, and helical gears up to 5.5 m (210 inches) weighing 6,800 kg (15,000 lb) have been processed with this method. The entire process yields a repeatable soft tip of the tooth with hard root and flank. In other applications, the tip and both flanks can be hardened simultaneously and yield a soft root.

In Summary

Today’s design engineer has the good fortune of being able to choose from a number of heat treatment technologies for any given type of gear material and design. When selecting a gear hardening method, it is essential to specify not only the desired mechanical and metallurgical properties, but the critical dimensions that must be held and even the desired stress state of the gears themselves. The secret to success is understanding the advantages and limitations of each technology and taking these into consideration when determining the overall cost of gear manufacturing.

References

Herring, Daniel H. 2004a. “Gear Heat Treatment: The Influence of Materials and Geometry.” Gear Technology, March/April.

Herring, Daniel H. 2004b. “Reducing Distortion in Heat-Treated Gears.” Gear Solutions, June.

Herring, Daniel H. 2007a. “Oil Quenching Technologies for Gears.” With Steven D. Balme. Gear Solutions, July.

Herring, Daniel H. 2007b. “Heat Treating Heavy Duty Gears.” With Gerald D. Lindell. Gear Solutions, October.

Herring, Daniel H. 2012–2016. Vacuum Heat Treatment. Vols. 1–2. BNP Media Group.

Herring, Daniel H. 2014–2015. Atmosphere Heat Treatment. Vols. 1–2. BNP Media Group.

Herring, Daniel H., Gerald D. Lindell, D. J. Breuer, and B. Matlock. 2001. “Atmosphere vs. Vacuum Carburizing.” Heat Treating Progress, November.

Herring, Daniel H., Gerald D. Lindell, D. J. Breuer, and B. Matlock. 2002. “An Evaluation of Atmosphere and Vacuum Carburizing Methods for the Heat Treatment of Gears.” In Off-Highway Conference Proceedings. SAE International.

Otto, Frederick J., and Daniel H. Herring. 2002a. “Gear Heat Treatment: Today and Tomorrow, Part 1.” Heat Treating Progress, June.

Otto, Frederick J., and Daniel H. Herring. 2002b. “Gear Heat Treatment: Today and Tomorrow, Part 2.” Heat Treating Progress, July/August.

Otto, Frederick J., and Daniel H. Herring. 2005. “Vacuum Carburizing of Aerospace and Automotive Materials.” Heat Treating Progress, January/February.

Otto, Frederick J., and Daniel H. Herring. 2007. “Advancements in Precision Carburizing of Aerospace and Motorsports Materials.” Heat Treating Progress, May/June.

Otto, Frederick J., and Daniel H. Herring. 2008. “Improvements in Dimensional Control of Heat Treated Gears.” Gear Solutions, June.

Rudnev, V. 2000. “Gear Heat Treating by Induction.” Gear Technology, March/April.

About the Author

Dan Herring
“The Heat Treat Doctor”
The HERRING GROUP, Inc.

Dan Herring has been in the industry for over 50 years and has gained vast experience in fields that include materials science, engineering, metallurgy, new product research, and many other areas. He is the author of six books and over 700 technical articles.

For more information: Contact Dan at dherring@heat-treat-doctor.com.

For more information about Dan’s books: see his page at the Heat Treat Store.


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“Just Balance the Pressure,” They Said

Jim Roberts of U.S. Ignition engages readers in a Combustion Corner editorial about the hidden complexity of balancing furnace pressures — explaining how thermal expansion, gas velocity, and pressure fluctuation interact in modern burner systems, and how flue gas recirculation can push firing efficiency from 30% to 75% while cutting NOx emissions by more than half.

This editorial was first released in Heat Treat Today’s March 2026 Annual Aerospace Heat Treating print edition.


When I made the comment about the negative attitude in Part 1 of this series (Air & Atmosphere Heat Treating, February 2026), I was referring to the fact that most of these burner designs require a suction component (in this case, the eductor) to help pull the exhaust gases out over the heat exchanger portion of the burner. Also, if we just tried to pressurize the burners and force the exhaust gases out through the exchanger section, there would be a pressure buildup in the furnace. With that comes the destruction of door seals. Burner plates begin to leak, and when the doors open, the operators and furnace guys get greeted with a blast of 2000°F flue gas. I can honestly say, I have not, in all my years in this industry, met a furnace guy who likes a thermal haircut.

So, by balancing the pressures, we can save gas, reduce emissions, and probably even heat treat some products along the way.

A comment like, “just balancing the pressures,” seems like such an easy thing to accomplish. And, for all the experienced furnace guys out there, that is probably regarded as pretty simple stuff. But we have to give proper respect to the myriad of moving parts in today’s modern burners and heating systems. When I say moving parts, perhaps the better description is designing around the fluctuations in pressures, temperatures, and flows that these modern systems all perform to operate at these efficiencies.

When Combustion Corner covered pressures and velocities in August and September 2025, you will recall that under these temperatures, everything starts moving around under the temperature growth and pressure increases. Velocity increases like crazy, and at heat treating temperatures, the very components expand significantly enough to affect the pressure and delivery of flue gases.

High temperatures cause flue gases to expand significantly because increased thermal energy boosts gas molecules’ kinetic energy, making them move faster and spread out. This principle, described by gas laws like Charles’s Law, leads to volume increases that necessitate expansion joints in equipment to prevent system damage and maintain integrity. This expansion can create immense stress on combustion systems, requiring specialized components like expansion joints to absorb thermal growth and maintain seals, while the high heat can also induce chemical changes and dissociation, influencing performance in other ways.

For example, can you begin to envision how furnace designers and burner design engineers have to pay attention to component growth while maintaining the critical pressures of the furnace and the burners and heat exchangers? It’s a dance, let me tell you! I believe I pointed out a while back that a 6-inch diameter radiant tube or burner combustor will grow almost an inch in length when running at 1400°F and above. If it’s growing in length, it is also trying to grow in diameter. It’s like trying to produce a constant flow of water at a constant spray rate on your garden hose, all the while the hose is changing dimensions. Not so easy is it?

To sum up, with heat recovery, and then with the addition of flue gas recirculation and high velocity burners, it is really quite remarkable how well many of these systems perform. The firing efficiency of a flue gas recirculation system over a conventional cold air burner can be the difference of 30% fuel efficiency and 75% fuel efficiency! We are talking about some serious fuel dollar savings when that all happens. And now, with recirculation, you are also cutting NOx by better than half as well.

Next time we will talk about how these systems do all of this.

About The Author:

Jim Roberts
President
US Ignition

Jim Roberts president at U.S. Ignition, began his 45-year career in the burner and heat recovery industry focused on heat treating specifically in 1979. He worked for and helped start up WB Combustion in Hales Corners, Wisconsin. In 1985 he joined Eclipse Engineering in Rockford, IL, specializing in heat treating-related combustion equipment/burners. Inducted into the American Gas Association’s Hall of Flame for service in training gas company field managers, Jim is a former president of MTI and has contributed to countless seminars on fuel reduction and combustion-related practices.

For more information: Contact Jim Roberts at jim@usignition.com.

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Answers in the Atmosphere: Argon Part 1 — An Inert Alternative

In this installment of Answers in the Atmosphere, David (Dave) Wolff, an independent expert focusing on industrial atmospheres for heat treat applications, explores the practical role of argon as a truly inert alternative to nitrogen in thermal processing.

This informative piece on argon’s unique properties, production challenges, and applications — from vacuum heat treating of titanium to powder metallurgy and additive manufacturing — was first released in Heat Treat Today’s February 2026 Annual Air & Atmosphere Heat Treating print edition.


Akin Malas
Business Development Manager / Metallurgist
Linde

In this column, I’ve invited Akin Malas, business development manager and metallurgist at Linde, to bring his deep expertise in the subject of argon gas. What follows is the fruit of our discussion and continued conversations about this specialized yet indispensable industrial gas in thermal processing applications.

Compared to nitrogen (the industrial gas this column last covered), argon exhibits actual inertness, enabling its use in high-temperature environments and for processing metals that cannot tolerate nitrogen atmospheres, such as titanium and certain high-performance stainless steels. While argon is significantly higher cost than nitrogen, it remains far more economical than helium, another highly inert alternative.

Argon plays a vital role across multiple stages of metal processing, including:

  • Primary metallurgy: ladle stirring
  • Powder metallurgy: atomization of metal powders
  • Additive manufacturing: laser and electron-beam processes requiring inert chamber atmospheres
  • Vacuum heat treating: backfill gas for titanium and specialty alloys

Argon is used differently than nitrogen in most cases. Inexpensive nitrogen is often used as a utility pressurization gas, for scavenging, and blended with other gases (such as hydrogen); however, argon is most often used in pure form. Nitrogen is considered inert for heat treatment applications except in extraordinarily high temperatures or heat treatment of reactive metals, such as titanium and stainless steels. In this case, using an actual inert gas like argon or helium is necessary. Also, while nitrogen is virtually the same density as air and thus will diffuse throughout a vessel, argon is much denser than air and can be used to form a stratified inert layer.

Linde gas storage tanks | Image Credit: Linde

Both argon and nitrogen are separated from air in a cryogenic air separation unit (ASU), but there are three main factors that make argon much harder to make than nitrogen and thus much more expensive:

  • Argon is only 1% of air while nitrogen is 78% of air. Argon boils at nearly the same temperature as oxygen, making a separate purification process necessary. Those two factors mean that only the largest ASUs make enough argon to make it worth purifying.
  • Argon cannot economically be separated from air non-cryogenically (primarily because the percentage in air is so low), so there is no low-cost competition to cryogenic argon. Also, because argon is prized for its inertness, there is much less interest in argon that might be lower purity.
  • Because argon is made in only the largest ASUs (typically those serving very large steel mills) and because those plants tend to be geographically grouped, shipping distances for argon tend to be much farther than for nitrogen and oxygen, further driving up the costs.

Processors of titanium parts and parts made of some stainless steels, such as the 300 series stainless alloys (SS), cannot be processed in nitrogen-containing atmospheres, because the metals will nitride at heat treating temperatures. Hence these metals may be processed in a pure argon (for Ti) or hydrogen (for SS) atmosphere blends.

We’ll pick up this discussion next month to see what market options are available, particularly in the U.S.

About The Author:

David (Dave) Wolff
Industrial Gas Professional
Wolff Engineering

Dave Wolff has over 40 years of project engineering, industrial gas generation and application engineering, marketing, and sales experience. Dave holds a degree in engineering science from Dartmouth College. Currently, he consults in the areas of industrial gas and chemical new product development and commercial introduction, as well as market development and selling practices.

For more information: Contact Dave Wolff at Wolff-eng@icloud.com.

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Ask The Heat Treat Doctor®: Why and How Do We Heat Treat Gears? Part One

Ask The Heat Treat Doctor® has returned to bring sage advice to Heat Treat Today readers, answer questions about heat treating, brazing, sintering, and other types of thermal treatments, as well as metallurgy, equipment, and process-related issues. In this installment, Dan Herring examines the essential role of heat treatment in gear performance: exploring the key material and design considerations for power transmission gears, the difference between through hardening and case hardening, and the atmosphere heat treatment processes — from carburizing and carbonitriding to nitriding and nitrocarburizing — that determine how well a gear handles load, wear, and fatigue in heavy-duty applications.

This informative piece was first released in Heat Treat Today’s February 2026 Annual Air & Atmosphere Heat Treating print edition.

Have questions or feedback? We’d love to hear from you — reach out to our editorial team at editor@heattreattoday.com.


Gears play an essential role in the performance of many products that we rely on in our everyday lives. When we think about gears, we generally separate them into two categories: motion-carrying and power transmission. Motion-carrying gears are generally nonferrous alloys or plastics, while load bearing power transmission gears (Figure 1) are usually manufactured from ferrous alloys and are intended for heavy-duty service applications.

Figure 1. Typical off-highway truck power transmission gears | Image Credit: The Heat Treat Doctor®

Gear Materials & Engineering

Power transmission gears involve a wide variety of steels and cast irons. In all gears, the choice of material must be made only after careful consideration of the performance demanded by the application end-use and total manufactured cost, taking into consideration such issues as pre- and post-machining economics.

Key design considerations require an analysis of the type of applied load, whether gradual or instantaneous, and the desired mechanical properties, such as bending fatigue strength or wear resistance — all of which will define core strength and heat treating requirements.

Figure 2. Stress profile in a heavy-duty transmission gear | Image Credit: The Heat Treat Doctor®

It is important for the designer to understand that each area in the gear tooth profile sees different service demands (Figure 2). Consideration must be given to the forces that will act on the gear teeth with tooth bending and contact stress, resistance to scoring and wear, and fatigue issues being paramount. For example, in the root area, good surface hardness and high residual compressive stress are desired to improve endurance or bending fatigue life. At the pitch diameter, a combination of high hardness and adequate subsurface strength are necessary to handle contract stress and wear and to prevent spalling.

Some of the factors that influence fatigue strength are:

  • Hardness distribution, a function of:
    • Case hardness
    • Case depth
    • Core hardness
  • Microstructure, a function of:
    • Retained austenite percentage
    • Grain size
    • Carbide size, type, and distribution
    • Non-martensitic phases
  • Defect control, a function of:
    • Residual compressive stress
    • Surface finish and geometry
    • Intergranular toughness

In the total manufacturing scheme, a synergistic relationship must exist between the material selection process, engineering design, and manufacturing (including heat treatment). A balance of the priorities in each discipline must be reached to achieve the optimization necessary for the ultimate performance of the gear design. This is often not an easy task.

Various atmosphere heat treatment methods are used for most types of gears including pre-hardening steps (e.g., annealing, normalizing, stress relief) and hardening processes (e.g., neutral hardening and case hardening).

Hardening

Neutral (aka through hardening) refers to heat treatment methods that do not produce a case. Examples of commonly through-hardened gear steels are AISI/SAE grades 1045, 4130, 4140, 4145, 4340, and 8640. It is important to note that hardness uniformity should not be assumed throughout the gear tooth. Since the outside of a gear is cooled faster than the inside, there will be a hardness gradient developed. The final hardness is dependent on the amount of carbon in the steel. The depth of hardness depends on the hardenability of the steel.

Through hardening can be performed either before or after the gear teeth are cut. When gear teeth will be cut after the part has been hardened, machinability becomes an important factor based on final hardness. The hardness is achieved by heating the material into the austenitic range, typically 815°C–875°C (1500°F–1600°F), followed by quenching and tempering.

Case Hardening

By contrast, case hardening is used to produce a hard, wear resistant case (surface layer) on top of a ductile, shock resistant interior (core). The idea behind case hardening is to keep the core of the gear tooth at a level under 40 HRC to avoid tooth breakage while hardening the outer surface to increase pitting resistance.

Carburizing

Figure 3. Atmosphere carburizing of large gears | Image Credit: Photograph courtesy of Aichelin Group

Atmosphere carburizing is the most common of the case hardening methods in use today and can handle a diverse range of part sizes and load configurations (Figure 3). In general, a properly carburized gear will be able to handle somewhere between 30–50% more load than a through-hardened gear. Examples of commonly carburized gear steels include AISI/SAE grades 1018, 4320, 5120, 8620, and 9310, as well as international grades, such as 20MnCr5, 17CrNiMo6, 18CrNiMo7-6, and 20MoCr4.

Atmosphere carburizing is typically performed in the temperature range of 870°C–955°C (1600°F–1750°F) although temperatures up to 1010°C (1800°F) are used for deep case work. Carburizing case depths can vary over a broad range, typically 0.13–8.25 mm (0.005–0.325 inches).

Carbonitriding

Carbonitriding is a modification of the carburizing process, not a form of nitriding. This modification consists of introducing ammonia into the carburizing atmosphere to add nitrogen to the carburized case as it is being produced. Examples of gear steels that are commonly carbonitrided include AISI/SAE 1018, 1117, and 12L14.

Carbonitriding is done at a lower temperature than carburizing, typically between 790°C–900°C (1450°F–1650°F), and for a shorter time. Combine this with the fact that nitrogen inhibits the diffusion of carbon, and what generally results is a shallower case than is typical for carburized parts. A carbonitrided case is usually between 0.075–0.75 mm (0.003–0.030 inches) deep.

Nitriding

Nitriding is another surface treatment process that has as its objective increasing surface hardness. One of the appeals of this process is that rapid quenching is not required, hence dimensional changes are kept to a minimum. It is not suitable for all gear applications; one of its limitations is that the extremely high surface hardness case produced has a more brittle nature than say that produced by the carburizing process. Despite this fact, in a number of applications, nitriding has proved to be a viable alternative. Examples of commonly nitrided gear steels include AISI/SAE 4140, 4150, 4340, and Nitralloy® 135M.

Nitriding is typically done in the range of 495°C–565°C (925°F–1050°F). Case depth and case hardness properties vary not only with the duration and type of nitriding being performed but also with steel composition, prior structure, and core hardness. Typically, case depths are between 0.20–0.65 mm (0.008–0.025 inches) and take from 10 to 80 hours to produce.

Nitrocarburizing (Ferritic or Austenitic)

Nitrocarburizing is a modification of nitriding, not a form of carburizing. In the process, nitrogen and carbon are simultaneously introduced into the steel while it is in a ferritic or at times an austenitic condition. A very thin “white” or “compound” layer is formed during the process, as well as an underlying “diffusion” zone. Like nitriding, rapid quenching is not required. Examples of gear steels that are commonly nitrocarburized include AISI/SAE grades 4140, 5160, 8620, and certain tool steels, such as H11 and H13.

Nitrocarburizing is normally performed at 550°C–600°C (1025°F–1110°F) and can be used to produce a 58 HRC minimum hardness, with this value increasing dependent on the base material. White layer depths range from 0.0013–0.056 mm (0.00005–0.0022 inches) with diffusion zones from 0.03–0.80 mm (0.0013–0.032 inches) being typical.

In Summary

There are many ways to heat treat gears. While atmosphere heat treatment (discussed above) is perhaps the most widely used technology today, other types of heat treatments, namely vacuum and induction hardening, are becoming more and more common methods. These will be discussed in Part Two.

About the Author

Dan Herring
“The Heat Treat Doctor”
The HERRING GROUP, Inc.

Dan Herring has been in the industry for over 50 years and has gained vast experience in fields that include materials science, engineering, metallurgy, new product research, and many other areas. He is the author of six books and over 700 technical articles.

For more information: Contact Dan at dherring@heat-treat-doctor.com.

For more information about Dan’s books: see his page at the Heat Treat Store.


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Answers in the Atmosphere: The Tremendous Value of Industrial Gas Smartphone Apps

In this installment of Answers in the Atmosphere, David (Dave) Wolff, an independent expert focusing on industrial atmospheres for heat treat applications, highlights the practical value of smartphone apps designed for industrial gas calculations and conversions.

This informative piece on mobile tools that simplify gas property calculations, unit conversions, and storage or flow-rate estimations — drawing attention to apps developed by major gas suppliers and equipment providers that help heat treaters access critical data in the field — was first released in Heat Treat Today’s January 2026 Annual Technologies to Watch print edition.


The field of industrial gases is complicated by the fact that the physical characteristics of gases depend on the temperature and pressure at the time of measurement. Industrial gases may be delivered and stored as cryogenic liquids and highly pressurized gases, though they are generally used in relatively low-pressure gaseous form. Additionally, gases may be used for different purposes; for example, hydrogen may be used as a metallurgical atmosphere or as a burner fuel. As such, users need a ready source of data on various industrial gases to make necessary calculations.

Image Credit: Open Library/Internet Archive

Years ago, industrial gas users had to rely on data tables in publications like the CRC Handbook of Chemistry and Physics — the nearly 8 lb, $195 hardbound handbook that has been published continuously since 1914 and is currently on its 106th edition.

Today, there are many more mobile solutions in the form of smartphone applications. Several of the major gas providers have developed handy apps available for both Apple and Android operating systems to simplify gas conversions and calculations. Equipment providers have also developed apps to help understand the specifics of their equipment. All of these can be helpful to metals thermal processors, including heat treaters at in-house processing operations.

Some examples follow:

  • Air Products and Linde both provide powerful conversion engines that enable users to convert from imperial to metric units, from mass to volume measurements, and from liquid to gaseous volumes for common industrial gases. For example, users can calculate how many hours of atmosphere coverage 6,000 gallons of liquid hydrogen stored in a tank will provide.
  • Cyl-Tec, Inc. has developed an app that focuses on calculations primarily specific to cryogenic and pressurized gas storage. In addition to unit of measure conversions for each common industrial gas, the app provides detailed information on each of the storage vessels that the company makes.
  • WITT-Gasetechnik of Germany has developed an app to support their gas safety and controls business. Their products include gas mixers, gas analyzers, regulators, and other controls. The app provides a variety of gas blending and measurement information, including welding gas blend suggestions, unit conversion, and flow rate calculators.
  • Gasmet of Finland has developed an app that simplifies calculation of dewpoint and combustion products depending on the fuel being combusted.

While these suppliers hope that you will buy their products, be assured that the measurements and conversions performed with their tools, and the recommendations generated, will be equally applicable to products and systems supplied by others.

I suggest you create a folder called “calculations and conversions” on your smartphone and load it up with several of these apps while you are connected to your home or office internet, so that you will have the apps handy when you are away from your standard technical resources.

About The Author:

David (Dave) Wolff
Industrial Gas Professional
Wolff Engineering

Dave Wolff has over 40 years of project engineering, industrial gas generation and application engineering, marketing, and sales experience. Dave holds a degree in engineering science from Dartmouth College. Currently, he consults in the areas of industrial gas and chemical new product development and commercial introduction, as well as market development and selling practices.

For more information: Contact Dave Wolff at Wolff-eng@icloud.com.

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When the Pressure Gets Too Much — And It Helps

Jim Roberts of U.S. Ignition engages readers in a Combustion Corner editorial about the double-edged sword of heat recovery technology — explaining how efforts to reduce fuel consumption inadvertently drove up NOx emissions, and how flue gas recirculation (FGR) emerged as the design solution capable of cutting both fuel use and emissions by up to 50%.

This editorial was first released inHeat Treat Today’s February 2026 Annual Air & Atmosphere Heat Treating print edition.


A furnace guy walks into the heat treating plant and says to the operators standing nearby, “This exhaust system and these burners all have a negative attitude.” The other furnace guys say, “They better be negative, or they would not work well!” As if we don’t have enough negativity swirling around in our world as it is, now we are happy about it?

In the Annual People of Heat Treat (September 2025) we talked about the types of burners that were developed as heat treating and furnace sciences and combustion designs evolved. We also chatted about how the advent of new fuels and government regulations was going to take a chunk of our attention in the coming years — for example, pollution laws coming to the forefront of our industry in the late ‘70s and onwards. Interesting new burner designs sprung up, primarily, as you recall, to address the usage of gas. In other words, how can we reduce fuel usage?

But First, NOx

The cost of gas skyrocketed for a stretch and it led us first to energy reduction plans. But with heat recovery sciences came the phenomenon of higher flame temperatures. When you get higher flame temperatures, you can sometimes (okay… all the time) generate NOx. One of the primary constituents of atmospheric pollution is NOx, and it became a prime target for reduction by the EPA and other governing air quality folks. As it should be.

Just a quick step back to the “remind me again, Jim” world. What do we breathe? Air, right? We have to have oxygen. But what we tend to forget is that air is roughly 79% nitrogen. So, what we breathe is actually nitrogen spiked with oxygen, and the fuel that we generally burn, natural gas, has some nitrogen in it too.

Natural gas can have as much as 5% nitrogen in it, although membrane filtering usually controls pipeline gas content at around 1%. The point is that nitrogen is the dominant gas in our combustible portfolio, and when we make it really hot, it makes NOx. And that is considered bad for all of us. So, NOx from fuel-borne nitrogen can be released at temperatures as low as 1400°F. Sometimes that is referred to as “sudden NOx” because it releases quickly. All of us Furnace Guys know that 1400°F ain’t nothing in our world.

The second form of NOx is referred to as “thermal NOx” and that is the major source of NOx in our world. That is when we heat the air we are combusting in a burner, burning off most of the 21% oxygen. Then, flame temperature climbs, and continues to now superheat and try to burn that remaining 79% of nitrogen. As temperatures approach 2300°F, the magic happens.

Thermal NOx forms significantly at high combustion temperatures, typically starting above 1300°C (2372°F), with formation increasing exponentially as temperatures rise, especially above 2800°F (1538°C), due to atmospheric nitrogen and oxygen reacting at peak flame temperatures. Does anybody remember what happens to flame temperatures when we preheat the combustion air (recuperation, recirculation, etc.)? Flame temp and heat transfer increase and we go up to theoretical flame temperatures of 3200°F without even working at it.

Solving Energy Efficiency Through Design

So, let’s return to the original question: What happened when we tried to only save gas with heat recovery? Answer: We installed energy efficient burners but increased the emissions footprint in doing so. We cut down on energy expenditure but made exhaust an issue with the higher temps.

For most industrial and commercial applications, the optimal range for flue gas recirculation (FGR) is between 10% and 25% as this range offers significant NOx reduction without compromising combustion stability or efficiency. By adjusting the pressures coming into the burner and then balancing the exhaust outlet pressures over the heat exchanger body, normally with an extraction device called an “eductor,” we can dial in the percentage of recirculation the burners are operating under.

Figure 1. Flow diagrams depicting the basic design for both direct fired and radiant tube style burners | Image Credit: Honeywell

With this design, I have seen fuel and emission reductions of 50% when compared to the existing conventional combustion systems. It really is a testament to what design and research can produce for us (Figure 1).

We’ll look more closely at these designs next time.

About The Author:

Jim Roberts
President
US Ignition

Jim Roberts president at U.S. Ignition, began his 45-year career in the burner and heat recovery industry focused on heat treating specifically in 1979. He worked for and helped start up WB Combustion in Hales Corners, Wisconsin. In 1985 he joined Eclipse Engineering in Rockford, IL, specializing in heat treating-related combustion equipment/burners. Inducted into the American Gas Association’s Hall of Flame for service in training gas company field managers, Jim is a former president of MTI and has contributed to countless seminars on fuel reduction and combustion-related practices.

For more information: Contact Jim Roberts at jim@usignition.com.

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Ask The Heat Treat Doctor®: Hot Topic for a Cold Day — Why Is Hot Gaseous Corrosion So Devastating?

Ask The Heat Treat Doctor® has returned to bring sage advice to Heat Treat Today readers, answer questions about heat treating, brazing, sintering, and other types of thermal treatments, as well as metallurgy, equipment, and process-related issues. In this installment, Dan Herring examines the devastating effects of hot gaseous corrosion on furnace alloys: exploring the mechanisms behind metal dusting, the gas-solid reactions that drive catastrophic carburization, and the mitigation strategies to extend the life of heat treaters’ most valuable furnace components.

This informative piece was first released in Heat Treat Today’s January 2026 Annual Technologies To Watch print edition.

Have questions or feedback? We’d love to hear from you — reach out to our editorial team at editor@heattreattoday.com.


Corrosion is a concern experienced by everyone involved in manufacturing industrial products. While there is a plethora of data and information on the effects of corrosion on engineered materials available (sources provided in the references section of this column), most corrosion engineers are focused on aqueous corrosion. By contrast, heat treaters must understand the effects of hot gaseous corrosion, especially on our furnace alloys. Let’s learn more.

Corrosion Basics

It is important to understand that all materials are chemically unstable in some environments and corrosive attack will always occur. In the scientific world, it can often be modeled and its effects predicted by studying thermodynamic data and knowing which of the many corrosion-related chemical states are active. In our world, however, it is equally important to understand the various forms of corrosion, namely:

  • Dezincification (aka selective leaching)
  • Electrolytic
  • Erosion
  • Galvanic (or two metal) action
  • General (aka uniform) attack
  • Intergranular attack
  • Pitting
  • Stress corrosion

The greater the metal’s solubility, the greater the degree and severity of the corrosive attack. There are many important variations of these forms of corrosion; two of the most important are 1) localized corrosive attack (e.g. pits, intergranular attack, crevices) and 2) interaction with mechanical influences (e.g., stress, fatigue, fretting). These actions are frequently rapid and have catastrophic effects.

The number of ways to combat corrosion have been well-documented, including alloying to produce better corrosion resistance materials; cathodic protection (via sacrificial anodes); coatings (metallic or inorganic); organic coatings (e.g. paints); metal purification; alteration of the environment; and nonmetallic or design (i.e., physical) changes.

Heat Resistant Alloys

Furnace interiors contain numerous examples of heat-resistant nickel-chromium-iron (Ni-Cr-Fe) alloys, including radiant tubes, fans, heating elements, roller rails and rollers, thermocouple protection tubes, chain guides, and atmosphere inlet tubes, to name a few. Baskets, grids, and fixtures are other examples. These alloys are normally selected based on their strength (at temperature) rather than resistance to corrosive attack.

Since these heat-resistant alloy parts are often the most expensive furnace components, heat treaters must understand how they can be attacked and what can be done to extend their life by minimizing or preventing corrosion.

Gas-Solid Reactions

A chemical reaction involving a (non-equilibrium) gas or gas mixture and a solid is classified as a gas-solid reaction. Examples of intermediate and high temperature reactions of this type include oxidation, sulfidation, carburization, and nitriding. Effects of gases containing vapors of chlorine, fluorine, and effluents from deposits of various alkaline chemicals (from cleaning compounds) and even phosphates are also problematic. The principles are the same for all types — only the details differ. As heat treaters, our interest is in controlling, retarding, or suppressing these reactions to prevent unwanted corrosion, gasification, or embrittlement of the furnace alloy or materials being processed.

Examples of Catastrophic Carburization (a.k.a. Metal Dusting)

Figure 1. Pusher furnace alloy fan and shaft assembly | Image Credit: The Heat Treat Doctor®

Metal dusting (Figure 1) is a hot gaseous corrosion phenomenon in which a metallic component disintegrates into a dust of fine metal and metal oxide particles mixed with carbon.

Generally, metal dusting occurs in a localized area, and how rapidly the disintegration progresses is a function of temperature, the composition of the atmosphere and its carbon potential, and the material. Other significant factors include the geometry of the system, reaction kinetics, diffusivities of alloy components, the specific-volume ratio of new and old phases, and the ultimate plastic strain.

Metal dusting usually manifests itself as pits or grooves on the surface, or as an overall surface attack in which the metal can literally be eaten away in a matter of days, weeks, or months. As an example, this writer has seen a 330-alloy plate mounted underneath a refractory-lined inner door of an integral quench furnace (where atmosphere passes underneath the door and into the quench vestibule) reduced in thickness from 12.5 mm (0.50 in) to less than 0.75 mm (0.03 in) in a little over two months.

Figure 2. 330 alloy radiant tube removed after six months of use (rotary retort furnace) | Image Credit: The Heat Treat Doctor®
Figure 3. Microstructural view: catastrophic carburization | Image Credit: The Heat Treat Doctor®

In another example, a metallographic investigation performed by this writer on a failed wrought 330 alloy radiant tube (Figure 2) was conducted. Optical microscopy of the inside (Figure 3) and outside diameter surfaces in the attacked area revealed evidence of massive carbides. These carbides are formed by the reaction of carbon with chromium, depleting the matrix of chromium in regions adjacent to the carbides. Grain detachment and subsequent failure by erosion then occurred.

How Does It Occur?

In general, catastrophic carburization of ferrous alloys proceeds via the formation and subsequent disintegration of metastable carbide. The first step in the process is absorption of the gaseous phase on the surface of the metal; the more reactive this phase, the easier it decomposes or is catalytically decomposed (in the case of iron) on the surface. This step is followed by diffusion of carbon atoms from the surface into the bulk metal.

As a result, there is a continuous buildup of carbon within the surface layer. As this layer becomes saturated with carbon, a stable carbide, metastable carbide, or an active carbide complex forms, which then grows until it reaches a state of thermodynamic instability, at which point it rapidly breaks down into the metal plus free carbon.

It’s at this stage that the metal disintegrates to a powder as the result of plastic deformation and subsequent fracture in the near-surface layer. The process is controlled by internal stresses due to phase transformation; in other words, competition between stress generation and relaxation exceeds the ultimate strength in this near-surface layer and causes fracture to occur.

In Ni-Cr-Fe alloys, the phenomenon occurs slower (but does not stop) since the disintegration leads to larger metal particles, which are less active catalysts for carbon deposition than the fine iron particles that form with ferrous metals. Therefore, the mass gain from carbon depositing onto high-nickel alloys is much lower. Also, the decomposition of high-nickel alloys occurs by graphitization and not via unstable carbides.

Pourbaix-Ellingham Diagrams

Thermodynamics can be applied to solid-gas reactions to obtain equilibrium dissociation pressures below which no reactions occur. Data and diagrams are available for the free energies of formation versus temperature for most metallic compounds. An interesting use of Pourbaix diagrams (generally reserved for mapping out possible stable equilibrium phases of an aqueous electrochemical system) as a predictor of stable alloy systems is found by superimposing the various elemental constituents. These diagrams are read much like a standard phase diagram (with a different set of axes).

In Summary

Hot gaseous corrosion should be an area of focus for every heat treater to extend the life of alloy components, reduce downtime, and save money. Mitigation in the form of alloy selection, equipment design, type of atmosphere, process/cycle selection, and idling temperatures will play a huge role in extending the life of our furnace alloys, baskets, and fixtures.

References

ASM International. 1971. Oxidation of Metals and Alloys.

ASM International. 2003. ASM Handbook. Vols. 13A–C.

Fontana, Mars G., and Norbert D. Greene. 2008. Corrosion Engineering. New York: McGraw-Hill.

Herring, D. H. 2003. “What to Do About Metal Dusting.” Heat Treating Progress, August.

Herring, Daniel H. 2015. Atmosphere Heat Treatment. Vol. 2. Troy, MI: BNP Media Group.

Javaheradashti, Raza. 2008. Microbiologically Induced Corrosion. Berlin: Springer-Verlag.

NACE International. www.nace.org.

Nateson, K. 1980. Corrosion–Erosion Behavior in Metals. Warrendale, PA: Metallurgical Society of AIME.

National Bureau of Standards. 1978. Gas Corrosion of Metals.

Pourbaix, Marcel. 1974. Atlas of Chemical and Electrochemical Equilibria in Aqueous Solutions. Houston, TX: NACE International.

Pourbaix, Marcel. 1998. Atlas of Chemical and Electrochemical Equilibria in the Presence of a Gaseous Phase. Houston, TX: NACE International.

Schweitzer, Philip A. 1996. Corrosion Engineering Handbook. New York: Marcel Dekker.

Staehle, R. W. 1995. “Engineering with Advanced and New Materials.” Materials Science and Engineering A 198 (1–2): 245–56.

Stempco, Michael J. 2011. “The Ellingham Diagram: How to Use It in Heat-Treat-Process Atmosphere Troubleshooting.” Industrial Heating, April.

Uhlig, Hubert H. 2008. Corrosion and Corrosion Control. Hoboken, NJ: Wiley-Interscience.

Fabian, R., ed. 1993. Vacuum Technology: Practical Heat Treating and Brazing. Materials Park, OH: ASM International.

The Boeing Company. n.d. “Practical Vacuum Systems Design Course.”

About the Author

Dan Herring
“The Heat Treat Doctor”
The HERRING GROUP, Inc.

Dan Herring has been in the industry for over 50 years and has gained vast experience in fields that include materials science, engineering, metallurgy, new product research, and many other areas. He is the author of six books and over 700 technical articles.

For more information: Contact Dan at dherring@heat-treat-doctor.com.

For more information about Dan’s books: see his page at the Heat Treat Store.


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Answers in the Atmosphere: Nitrogen — Flow Rate, Sourcing, & Costs

In this installment of Answers in the Atmosphere, David (Dave) Wolff, an independent expert focusing on industrial atmospheres for heat treat applications, explores the versatile role of nitrogen gas in thermal processing.

This informative piece on nitrogen’s flow rate considerations, sourcing strategies, and cost factors — drawing on insights from Air Products engineers to help heat treaters make informed, cost-effective supply decisions — was first released in Heat Treat Today’s December 2025 Annual Medical & Energy Heat Treat print edition.


We’re picking up the topic of nitrogen this month with a continued discussion of several key aspects of flow rate, expert assistance, and atmosphere costs that I had the pleasure of hearing about from several key industry experts. My thanks to these Air Products individuals: John Dwyer, principal engineer; Bryan Hernandez, commercial technology sales engineer; and Emily Phipps, strategic marketing manager.

First, the experts shared that in a typical thermal processing operation, the required instantaneous nitrogen flow rate may vary significantly depending on several factors including number of furnaces in operation, flowrate required per furnace, and materials being processed. The nitrogen supply system must be capable of meeting these varying flowrate requirements, from minimum to maximum, on demand.

Although non-cryogenically generated nitrogen may be acceptable for some processes and materials, they emphasized that varying flowrate demands may make sizing a nitrogen operation system challenging.

Additionally, because nitrogen purity from non-cryogenic generation may vary depending on required flowrate (with purity decreasing as flowrate demand increases), it is important to prevent changes in nitrogen purity, which can cause quality issues with the material being heat treated.

Dwyer and his colleagues advise securing expert assistance when evaluating nitrogen needs prior to choosing a new or modified supply approach. This might involve going to your industrial gas provider or to an independent consultant. If you are working with an industrial gas provider, make sure that you are getting the technical assistance needed to determine the most cost-effective nitrogen supply system to meet your requirements.

There are upfront costs involved with both delivered and generated nitrogen supplies. According to the Air Products team, users may prefer a lower initial cost approach of dealing with a full-service industrial gas provider to provide a nitrogen system with higher operating costs (for delivered gas), versus a more complex generated nitrogen gas system with higher upfront costs that may offer significant long term savings through lower nitrogen costs. An industrial gas provider may also offer you a lease option for an on-site generation system that could offer you reliability at lower cost.

Besides the costs and investment timing, there are other considerations the experts shared:

  • NFPA 86 (and your insurance provider) may require sufficient nitrogen to be available for purging and inerting regardless of whether your electricity is operating.
  • Because delivered nitrogen production and delivery costs are a significant fraction of the nitrogen price, depending on where the nitrogen producing plant is, some suppliers may offer better prices than others.
  • Electricity costs are a significant fraction of the cost of both delivered and on-site generated nitrogen. If your local electric costs are high but the nitrogen comes from an area with lower electric costs, that may affect potential nitrogen costs and supply decisions.
  • Nitrogen tanks may require meaningful site investments in foundations and piping. If you are leasing your building, consider if a delivered or generated nitrogen supply solution minimizes your site investment.
  • An onsite nitrogen generation system requires large volumes of clean, dry air. In addition to buying a nitrogen generator, you may need to invest in additional air compression capacity. You also need to maintain your compressed air system, because oily air will destroy the expensive air separation media in a PSA nitrogen generation system. Consider your staff’s capabilities carefully.

It is important to take the time to think about a reliable supply that will avoid sending workers home due to lack of available nitrogen. Onsite nitrogen generation allows nitrogen users to make their own nitrogen, without the need for a tank and deliveries. At the same time, nitrogen generation requires large amounts of clean, dry compressed air. For companies that can commit to maintaining their air compression and nitrogen generation equipment, nitrogen generation can be a powerful approach to cost savings. But be realistic. If you can’t commit to 100% uptime for your air supply system, you need to plan for nitrogen downtime and production interruptions.

As a final note, the ideal nitrogen supply approach for your operations may be different from others in your industry. Dwyer, Hernandez, and Phipps say it is important to consider your process needs, ability to invest, interest in ownership vs. delivered utility, staff’s ability to manage a generation system, and the specific costs. Take the time to evaluate and understand that you can choose a different solution at a later time if your needs change.

About The Author:

David (Dave) Wolff
Industrial Gas Professional
Wolff Engineering

Dave Wolff has over 40 years of project engineering, industrial gas generation and application engineering, marketing, and sales experience. Dave holds a degree in engineering science from Dartmouth College. Currently, he consults in the areas of industrial gas and chemical new product development and commercial introduction, as well as market development and selling practices.

For more information: Contact Dave Wolff at Wolff-eng@icloud.com.

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Cost of Fuel Drives Change

Jim Roberts of U.S. Ignition engages readers in a Combustion Corner editorial about how rising fuel costs have driven dramatic improvements in furnace efficiency and combustion technology over the past 60 years, transforming heat treat processes from 20% to 70% fuel efficiency.

This editorial was first released in Heat Treat Today’s January 2026 Annual Technologies to Watch print edition.


A furnace guy walks into the shop and sees the cost of gasoline. “This keeps going up, what gives?”

My first car got about 10 MPG — we will not even go near to discussing when that was. Gasoline costs have since driven cars to become more efficient with 30+ MPG vehicles.

Last month’s article highlighted how there are five qualities in our heat treat processes: Quality and Accuracy, the necessary attributes; Efficiency and Performance, the variables; and Profit, which comes whenever we improve the two variables. We have discussed government regulation on emissions and technological breakthroughs that improved combustion technology in earlier articles, but now we turn to the connection of combustion and cost: how gasoline costs drove improvement of the two variable qualities of heat treat processing for combustion, Efficiency and Performance.

Gasoline Costs: A Timeline

Up until about 1960, the world of heat processing was pretty much a level playing field with Efficiency and Performance. We had tons of fuel at our disposal. Pollution was known but not yet a criterion to manage processes. So, burner efficiency and design were very low end. Nobody cared. Fuel was almost free. In doing research for this story, I found records of natural gas being less than $0.50 per million BTUs. Electricity was on par with delivered BTU costs. But then the cost of fuel started to fluctuate. The furnace guys started to notice; if nothing else changed, our friend Profit would weaken.

From 1930 to 1980, electricity pricing went up 500%. Natural gas started to bounce around in price. It was less than a $1.00/thm in the ’60s and ’70s, peaking during times of fuel shortage at $16.00/thm. Ten years later, in 2016, it hit $2.30/thm again. Some pretty wild fluctuations. In fact, it should be noted that the industry overseas had already begun to shift technologies — several years ahead of the U.S. — because they had been suffering with high fuel costs in Great Britain, Germany, Western Europe, and in Asian markets.

Furnace guy and the suppliers had to improve the efficiency and performance.

Troubleshooting and Combustion Design Changes

At first, you look at easy fixes to improve Efficiency and Performance. An example would be that insulation and refractory science really improved. If you can keep the heat in the furnace, you need less fuel to hold it at these high temperatures, right? So, improve the insulation.

Next, let’s get the burners from just being the opening in the furnace that you pour gas into, and make the burner more like a carburetor on an engine. Let’s get control of the air and gas ratios.

Next, let’s recover some of the flue gases and pre-heat the air coming into the burner. When you do that, the flame temp goes up, sometimes by as much as 400-500°F. That means higher heat transfer rates to the parts inside a now well-insulated furnace. Huge efficiency gains started happening.

Efficiency and Performance got a huge boost when the burners started to have high velocity discharge rates. In other words, we now had flames that were hotter and going into the furnace at several hundred miles an hour more than before. With that comes circulation improvement inside the furnace. And much like pudding in a blender, the faster the beaters, the smoother the mix. To give you an idea of the scope of these improvements, form 1960 to 1990, a matter of only 30 years, furnace and burner technology improvements went from 20% fuel utilization to estimated 60-70% fuel efficiencies, even higher in some instances. And there it was, super efficiency driven to occur by fuel cost and flucturation of supply.

To really hit home what that meant, let’s look at a 1,000-lb load of steel. Our process temp is 1750°F. Our furnace and combustion efficiency used to be 20%. That would require 1,370,000 BTU to heat up in an hour. Now, with 75% furnace and burner efficiency, that’s 352,000 BTU. You just saved approximately 1,000 ft3 of gas per hour! If we use the average industrial gas price today at $3.80/1,000 ft3, the difference of all this is $24,000/year, and that’s just a 1,000-lb load. Real world, the numbers are significantly higher, as all you furnace guys know. Imagine the dollar savings when fuel was at $16.00/thm?

And so, there it is. The well-known realization that in most markets, the dollar cost of the energy triggers improvement of technology.

Until next time…

About The Author:

Jim Roberts
President
US Ignition

Jim Roberts president at U.S. Ignition, began his 45-year career in the burner and heat recovery industry focused on heat treating specifically in 1979. He worked for and helped start up WB Combustion in Hales Corners, Wisconsin. In 1985 he joined Eclipse Engineering in Rockford, IL, specializing in heat treating-related combustion equipment/burners. Inducted into the American Gas Association’s Hall of Flame for service in training gas company field managers, Jim is a former president of MTI and has contributed to countless seminars on fuel reduction and combustion-related practices.

For more information: Contact Jim Roberts at jim@usignition.com.

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Answers in the Atmosphere: Nitrogen — The Swiss Army Knife for Thermal Processors

In this installment of Answers in the Atmosphere, David (Dave) Wolff, an independent expert focusing on industrial atmospheres for heat treat applications, explores the versatile role of nitrogen gas in thermal processing.

This informative piece on nitrogen’s critical functions in safety, as a diluent, and as an atmosphere component — including production methods and purity requirements — was first released in Heat Treat Today’s November 2025 Annual Vacuum Heat Treating print edition.


As discussed in the introduction for this series of gas-focused columns, nitrogen gas is ubiquitous in thermal processing — by far the most-used delivered or generated gas in secondary metallurgy. This column covers many important considerations for the use and availability of nitrogen gas, featuring the insights from my recent interview with Air Products experts: John Dwyer, principal engineer; Bryan Hernandez, commercial technology sales engineer; and Emily Phipps, strategic marketing manager. Because of its key role in thermal processing, we expect to have additional columns on nitrogen gas in this series.

Nitrogen serves three important purposes in secondary metallurgy:

  1. Safety
  2. Diluent
  3. Atmosphere

Regarding safety, the Air Products experts shared important attributes of nitrogen and several applications it is most often used in. According to them, nitrogen:

  • will not react with most metals used in fabrication applications until reaching extremely high temperatures
  • will not support combustion or oxidation
  • has about the same density as air (which is 78% nitrogen)
  • is the least expensive industrial gas on a volumetric basis.

For those reasons, nitrogen is used as a purging and inerting gas in metallurgical applications, such as inerting the furnace in preparation for a flammable atmosphere to be introduced, as well as expelling flammable atmosphere at the end of a furnace cycle. They further noted that the National Fire Protection Association (NFPA) Standard 86 for Ovens and Furnaces mandates that nitrogen be always available for furnace inerting except for very specific exceptions where alternative approaches are used (burn in and burn out). Beyond the strict safety considerations, nitrogen protects furnace linings and components from high temperature oxidation.

Dwyer, Hernandez, and Phipps emphasized that when used as a diluent, nitrogen makes it possible to use relatively small volumes of a more expensive reactive gas or gas blend and ensure that the diluted active gas can provide benefits for an entire furnace load of parts. Examples include nitrogen/hydrogen atmospheres where nitrogen gas can enable a relatively small volume of very powerful reducing gas hydrogen to be mixed with a higher volume of nitrogen to fill the furnace interior. I would add that a blended atmosphere of nitrogen/hydrogen will have a higher density than hydrogen alone, and hence may distribute more widely in the furnace rather than just pooling at the ceiling level.

They further discussed how nitrogen can be used as a sole constituent in a furnace atmosphere in many cases, especially at lower temperature ranges, such as tempering and stress relief. In situations where surface finish is a secondary consideration, or where additional operations are going to be performed, they note that the part lower finish quality provided under inert nitrogen alone might be acceptable.

The team then reported that nitrogen forms the bulk of the atmosphere and cryogenic air separation is now available virtually worldwide; because of this, liquified or gaseous compressed nitrogen can also be delivered to clients virtually worldwide. Cryogenically separated nitrogen is, by the nature of the process, extremely pure, and can be assumed to be 99.999% or purer as delivered into the client’s storage vessel. Nitrogen can also be made at the client’s site, using non-cryogenic or cryogenic air separation techniques. For secondary metallurgy, non-cryogenic techniques are the most common because the volumes of nitrogen required are too low for a dedicated cryogenic air separation unit.

Continuing along this line, they explained that while both pressure swing adsorption (PSA) and hollow fiber membrane techniques can be employed to generate nitrogen for a single customer site, the PSA technology is the one primarily used to supply generated nitrogen for thermal processes. This is because the membrane technique for non-cryogenic nitrogen generation makes relatively impure nitrogen, with too much oxygen to achieve the desired surface properties sought by heat treaters. As such, membrane generated nitrogen is primarily used for chemical blanketing and similar low temperature air displacement applications.

The final discussion point I will share from the interview today is about the variability in accepted purity based on the planned usage of nitrogen. The three Air Products experts pointed out that NFPA86 mandates that the atmosphere in a furnace must be below 1.0% oxygen before any flammable gas species can be introduced. So, they continued, nitrogen used solely for safety purging can be relatively impure and still achieve the 1.0% maximum oxygen allowed. When used as the sole atmosphere component (i.e., 100% N₂), or as a carrier gas blended with an active gas like hydrogen, they explained that nitrogen purity must be much higher in order to achieve acceptable surface quality. In general, for atmosphere uses, it should be assumed as a general rule that the purer the nitrogen is, the easier it is to achieve satisfactory heat treat results. The three concluded this thought noting that in blended atmospheres it may be possible to use slightly higher levels of active gases (like hydrogen) to react with excess oxygen in the nitrogen supply, but that approach is unlikely to make sense economically since nitrogen is typically far less expensive than an active gas.

In the December 2025 installment of Answers in the Atmosphere, I’ll share further insights that my interview uncovered. Until then, consider your unique nitrogen needs and therefore whether having direct access to this gas for the benefit of your heat treat operations is essential.

About The Author:

David (Dave) Wolff
Independent expert focusing on industrial atmospheres for heat treat applications

Dave Wolff has over 40 years of project engineering, industrial gas generation and application engineering, marketing, and sales experience. Dave holds a degree in engineering science from Dartmouth College. Currently, he consults in the areas of industrial gas and chemical new product development and commercial introduction, as well as market development and selling practices.

For more information: Contact Dave Wolff at Wolff-eng@icloud.com.

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