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Sustainability Insights: How Can We Work To Get The Carbon Out Of Heating? Part 2

The search for sustainable solutions in the heat treat industry is at the forefront of research for industry experts. Michael Stowe, PE, senior energy engineer at Advanced Energy, one such expert, offers some fuel for thought on the subject of how heat treaters should prioritize the reduction of their carbon emissions by following the principles of reuse, refuel, and redesign.

This Sustainability Insights article was first published in Heat Treat Today’s January/February 2024 Air & Atmosphere print edition.


Reduce

Michael Stowe
PE, Senior Energy Engineer
Advanced Energy

We explored why the question above has come to the forefront for industrial organizations in Part 1, released in Heat Treat Today’s December 2023 print edition. Now, let’s look at the four approaches to managing carbon in order of priority.

The best way to manage your carbon footprint is to manage your energy consumption. Therefore, the first and best step for reducing your carbon footprint is to reduce the amount of energy you are consuming. Energy management tools like energy treasure hunts, energy assessments, implementation of energy improvement projects, the DOE 50001 Ready energy management tool, or gaining third party certification in ISO 50001 can all lead to significant reduction in energy consumption year over year. Lower energy use means a smaller carbon footprint.

Additionally, ensuring proper maintenance of combustion systems will also contribute to improved operational efficiency and energy savings. Tuning burners, changing filters, monitoring stack exhaust, controlling excess oxygen in combustion air, lubricating fans and motors, and other maintenance items can help to ensure that you are operating your combustion-based heat treating processes as efficiently as possible.

Reuse

Much of the heat of the combustion processes for heat treating goes right up the stack and heats up the surrounding neighborhood. Take just a minute and take the temperature of your exhaust stack gases. Chances are this will be around 1200–1500°F. Based on this, is there any effective way to reuse this wasted heat for other processes in your facility? One of the best things to do with waste heat is to preheat the combustion air feeding the heat treating process. Depending on your site processes, there are many possibilities for reusing waste heat, including:

  • Space heating
  • Part preheating
  • Hot water heating
  • Boiler feed water preheating
  • Combustion air preheating

Refuel

Once you have squeezed all you can from reducing your process energy consumption and reusing waste heat, you may now want to consider the possibility of switching the fuel source for the heat treating process. If you currently have a combustion process for a heat treat oven or furnace, is it practical or even possible to convert to electricity as the heating energy source? Electricity is NOT carbon free because the local utility must generate the electricity, but it typically does have lower carbon emissions than your existing direct combustion processes on site. Switching heating energy sources is a complex process, and you must ensure that you maintain your process parameters and product quality. Typically, some testing will be required to ensure the new electrical process will maintain the metallurgical properties and the quality standards that your customer’s specific cations demand. Also, you will need a capital investment in new equipment to make this switch. Still, this method does have significant potential for reducing carbon emissions, and you should consider this where applicable and appropriate.

Redesign

Finally, when the time is right, you can consider starting with a blank sheet of paper and completely redesigning your heat treating system to be carbon neutral. This, of course, will mean a significant process change and capital investment. This would be applicable if you are adding a brand-new process line or setting up a new manufacturing plant at a greenfield site.

In summary, heat treating requires significant energy, much of which is fueled with carbon-based fossil fuels and associated-support electrical consumption. Both combustion and electricity consumption contribute to an organization’s carbon footprint. One of the best ways to help manage your carbon footprint is to consider and manage your energy consumption.

For more information:
Connect with IHEA Sustainability & Decarbonization Initiatives www.ihea.org/page/Sustainability
Article provided by IHEA Sustainability

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Exo Gas Composition Changes, Part 2: Cool Down and Use in Heat Treat Furnaces

In Part 1, the author underscored the importance of understanding the changes in gas composition through three steps of its production: first, the production in the combustion chamber; second, the cool down of gas to bring the Exothermic gas (Exo gas) to below the ambient temperature; and third, the introduction of the gas to the heat treat furnace. Read Part 1, published in Heat Treat Today’s August 2023 Automotive Heat Treat print edition, to understand what Exo gas is and to learn about the composition of gas in the first step.


Harb Nayar
Founder and President TAT Technologies LLC Source: TAT

As the author demonstrated in Part 1, Exo gas composition changes in its chemistry for heat treatment; this first step is how the gas composition changes when it is produced in the combustion chamber. The composition of reaction products, temperature, Exothermic energy released, various ratios, and final dew point are all factors that need to be considered to protect metal parts that will be heat treated in the resulting atmosphere.

Now, we’ll turn to Steps 2 and 3.

Step 2: Composition of Exo Gas after Exiting the Reaction Chamber Being Cooled Down

The two examples that follow demonstrate how lean and rich Exo under equilibrium conditions change as they are cooled from peak equilibrium temperature in the combustion chamber down to different lower temperatures (Table B). This cool down brings the Exo down to below ambient temperatures to avoid water condensation.

Example 1: Lean Exo Gas with a 9:1 Air to CH₄ Ratio

The first column highlighted in blue shows the composition of the lean Exo gas as generated in the reaction chamber with an air to natural gas ratio of 9:1. The peak temperature as generated in the combustion chamber is 3721°F. The next four columns show how the composition changes when the lean Exo gas is slowly cooled from 3721°F to 2000°F, 1500°F, 1000°F, and 500°F under equilibrium condition. The following key changes take place as the temperature of the lean Exo is lowered from the peak temperature to 500°F:

  1. Hydrogen volume almost triples from 0.67% to 1.97%.
  2. H₂O volume decreases slightly from 19.1% to 17.5%, but still is very high at all temperatures.
  3. Oxidation-reduction potential (ORP) changes as the H₂ to H₂O ratio increases from 0.035 to 0.111. At all temperatures, it is very low.
  4. CO and the CO to CO₂ ratio drop in a big way, making lean Exo from being decarburizing at higher temperatures to being highly decarburizing at lower temperatures.
  5. The percentage of N₂ remains at 70.34 at all temperatures.
  6. There is no C (carbon, i.e., soot) or residual CH₄ at all temperatures.
  7. For all practical purposes, at an air to natural gas ratio of 9:1, the Exo gas as generated is predominantly an N₂ and H₂ (steam) atmosphere with some CO₂ and small amounts of H₂ and CO.
Table B. Air to Natural Gas at 9:1 and 7:1, cooled to various temperatures

Example 2: Rich Exo Gas with a 7:1 Air to CH₄

The column under ratio of seven is highlighted as red to show the composition of the rich Exo gas as generated in the reaction chamber with an air to CH₄ ratio of seven. The peak temperature is 3182°F — significantly lower than that for lean Exo. The next four columns show how the composition changes when the rich Exo gas is slowly cooled from 3182°F to 2000°F, 1500°F, 1000°F, and 500°F. The following key changes take place as temperature of the rich Exo is lowered from the peak temperature to 500°F:

  1. Hydrogen volume almost doubles from 5.58% at peak temperature to 9.91% at 1000°F, and then it drops to 5.70% at 500°F. The overall volume of H₂ in rich Exo is significantly higher than in lean Exo.
  2. H₂O volume decreases slightly from 17.9% to 15.1%, but it is still very high at all temperatures.
  3. Oxidation-reduction potential (ORP) changes as the H₂ to H₂O ratio increases from 0.312 at peak temperature to 0.737 at 1000°F before decreasing to 0.377 at 500°F. Overall, ORP in rich Exo is significantly higher than that in lean Exo.
  4. CO and the CO to CO₂ ratio drop in a big way, making it mildly decarburizing to more decarburizing
  5. The percentage of N₂ remains at 65– 67%, which is lower than lean Exo.
  6. There is no C (carbon, i.e., soot) at any temperature. However, there is residual CH₄ at 1000°F and lower. This increases rapidly when cooled slowly below 1000°F.
  7. For all practical purposes, the rich Exo gas (at air to natural gas ratio of 7:1) generated is still predominantly a H₂
    and H₂O (steam) atmosphere, but with more H₂; hence, it has somewhat higher oxidation-reduction potential (ORP) than lean Exo and a bit higher CO to CO₂ ratio (less decarburizing than lean Exo).

In summary, rich Exo as generated in the combustion chamber differs from lean Exo as follows:

  1. It has a little less N₂ % as compared to lean Exo.
  2. It has significantly more H₂ , but a little less H₂O than lean Exo. As such, it has a significantly higher H₂ to H₂O ratio (ORP).
  3. It is decarburizing, but less than lean Exo.
  4. It has residual CH₄ at temperatures below 1000°F. Therefore, it must be cooled very quickly to suppress the reaction of developing too much residual CH₄.

Discussion

Let us take the example of rich Exo (an air to natural gas of 7:1) exiting from the reaction chamber in Table B (see column highlighted in red). The total volume is 853.3 SCFH and has H₂O at 152.4 SCFH (17.9% by volume). This is equivalent to dew point of 137°F. Its H₂ content is 47.6 SCFH (5.58% by volume). And the H₂ to H₂O ratio is 0.312.

If this were quenched to close to ambient temperature “instantly,” this composition would be “frozen,” except most of the H₂O vapor will become water. Let us assume the Exo gas was instantly quenched to 80°F (3.6% by volume after condensed water is removed). Rough calculation shows that the final total volume of H₂O vapor has to be reduced from 152.4 SCFH to about 26.0 SCFH in order to meet the 80°F dew point goal. This means 152.4 – 26.0 = 126.4 SCFH of H₂O vapor got condensed to water.

Now the total volume of Exo gas after cooling down to 80°F= 853.35 – 126.4 = 726.95 SCFH, or almost 15% reduction in volume of Exo gas as compared to what was generated in the reaction chamber.

Of course, the composition of Exo gas will not be the same as calculated above. The exact composition after being cooled down depends upon the following:

a. Cooling rate of the reaction products from the peak temperature in the reaction chamber to some intermediate temperature, typically around 1500°F.
b. Cooling rate of the gas from the intermediate temperature to the final (lowest) temperature via water heat exchangers — typically 10–20°F below ambient temperature unless a chiller or dryer is installed on the system.

Depending upon the overall design of the generator, especially how Exo gas coming out of the combustion chamber is cooled and maintained during the period of its use, the expected Exo gas composition should be in the range of the light red columns in Table B — where temperatures are between 1500°F to 1000°F — however:

  1. Total volume closer to 727 SCFH (since a major portion of H₂O was condensed out)
  2. N₂ between 74–77%
  3. Dew point between 80–90°F
  4. CH₄. between 0.1–0.5%
  5. H₂ percentage between 7–9%

Step 3: Composition of Exo Gas after Being Introduced into the Heat Treat Furnace

The cooled down Exo gas will once again change its composition depending upon the temperature inside the furnace where parts are being thermally processed.

As an illustration, let us assume the following composition of the rich Exo gas (with a 7:1 air to natural gas ratio) at ambient temperature just before it enters the furnace:

  • Total volume: 727 SCFH
  • H₂: 8% (58.16 SCFH)
  • Dew Point 86°F or 4.37% (31.77 SCFH)
  • CO: 6% (43.62 SCFH)
  • CO₂: 6% (43.62 SCFH)
  • CH₄ : 0.4% (2.91 SFH)
  • Balance N₂ (%)
  • 75.23% (546.92 SCFH)

Table C shows how the composition changes once it reaches the high heat section of the furnace where parts are being thermally treated. The column highlighted blue shows the composition of Exo gas as it is about to enter while it is still at the ambient temperature. The next three columns show the composition of the Exo gas in the high heat section of furnaces operating at three different temperatures depending upon the heat treat application — 1100°F like annealing of copper, 1500°F like annealing of steel tubes, and 2000°F like copper brazing of steel products. The H₂ to H₂O ratio decreases as temperature increases.

Other general comments on Exo generators:

  1. Generally, they are horizontal.
  2. Size ranges from 1,000 to 60,000 SCFH.
  3. Rich Exo generators use Ni as a catalyst in the reaction chamber. Lean Exo does not.
  4. Lean Exo generators typically operate at a 9:1 air to natural gas ratio. There is no carbon/soot buildup.
  5. Rich Exo generators typically operate at a 7:1 air to natural gas ratio. Below about 6.8 and lower ratios, soot/carbon deposits start appearing that require carbon burnout as part of the maintenance procedure.
Table C. Exo gas compositions in heat treat furnaces

Conclusions

A walkthrough of the entire cycle of gas production to cool down to use in the high heat section of the furnace clearly shows that as temperature changes, so does the Exo gas composition for any air to natural gas ratio.

Having a well-controlled composition of Exo gas requires the following:

  • Well-controlled composition of the natural gas used
  • Air supply with controlled dew point
  • Highly accurate air and natural gas mixing system
  • Highly controlled and maintained cooling system
  • A reliable ORP analyzer or the H₂ to H₂O ratio analyzer as part of the Exo gas delivery system.

Protecting metallic workpieces is paramount in heat treating, and in order to do this, the atmosphere created by Exothermic gas must be understood, both in the cool down phase and within the heat treat furnace. For further understanding of the good progress made in the improvement of Exo generators, see Dan Herring’s work in the reference section below.

References

Herring, Dan. “Exothermic Gas Generators: Forgotten Technology?” Industrial Heating, 2018, https:// digital.bnpmedia.com/publication/?m=11623&i=53 4828&p=121&ver=html5.

Morris, Art. “Exothermic Atmospheres.” Industrial Heating (June 10, 2023), https:// www.industrialheating.com/articles/91142-Exothermic-atmospherees.

About the Author

Harb Nayar is the founder and president of TAT Technologies LLC. Harb is both an inquisitive learner and dynamic entrepreneur who will share his current interests in the powder metal industry and what he anticipates for the future of the industry, especially where it bisects with heat treating.

For more information: Contact Harb at harb.nayar@tat-tech.com or visit www.tat-tech.com


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Sustainability Insights: How Can We Work to Get the Carbon Out of Heating? Part 1

The search for sustainable solutions in the heat treat industry is at the forefront of research for industry experts. Michael Stowe, PR, senior energy engineer at Advanced Energy, one such expert, offers some fuel for thought on the subject of how heat treaters can reduce their carbon emissions.

This Sustainability Insights article was first published in Heat Treat Today’s December 2023 Heat Treat Medical and Energy print magazine.


Michael Stowe
PE, Senior Energy Engineer
Advanced Energy
op-ed

The question in the article title is becoming increasingly popular with industrial organizations. Understanding the carbon content of products is becoming more of a “have to” item, especially for organizations that are in the supply chain for industrial assembly plants such as in the automotive industry. Many heat treaters are key steps in the supply chain process, and their carbon footprints will be of more interest to upstream users of heat treated parts in the future. I know I am overstating the obvious here, but I am going to do it anyway for emphasis:

  1. Heat treating requires HEAT.
  2. HEAT requires ENERGY consumption.
  3. ENERGY consumption creates a carbon footprint:
    a. Fossil fuels heating — direct carbon emissions (Scope 1)
    b. Electric heating — indirect carbon emissions (Scope 2)

Therefore, by definition and by process, if you are heat treating, then you are producing carbon emissions. Again, the question is, “How can we work to get the carbon out of heating?” Let us explore this.

Figure 1. Methane combustion (Source: Advanced Energy)

Once more, heat treating requires energy input. The energy sources for heat treating most frequently include the combustion of carbon-based fossil fuels such as natural gas (methane), propane, fuel oil, diesel, or coal. Also, most combustion processes have a component of electricity to operate combustion air supply blowers, exhaust blowers, circulation fans, conveyors, and other items.

Figure 1 shows the chemical process for the combustion of methane (i.e., natural gas). Figure 1 demonstrates that during combustion, methane (CH4) combines with oxygen (O₂) to form carbon dioxide (CO₂) and water (H₂O). This same process is true for any carbon-based fuel. If you try to imagine all the combustion in progress across the globe at any given time, and knowing that all this combustion is releasing CO₂, then it is easy to see the problem and the need for CO₂ emission reductions.

In the most basic terms, if you have a combustion-based heat treating process on your site, then you are emitting CO₂. The electricity consumed to support the combustion processes also has a carbon component, and the consumption of this electricity contributes to a site’s carbon footprint.

Figure 2. The 4 Rs of carbon footprint (Source: Advanced Energy)

So, combustion and electricity consumption on your site contributes to your carbon footprint. Knowing this, organizations may want to consider the level of their carbon footprint and explore ways to reduce it. There are many methods and resources available to help organizations understand and work to improve their carbon footprint. For this article, we will focus on the 4 Rs of carbon footprint
reduction (see Figure 2).

We will discuss each of these approaches individually in priority order in the next installment of the Sustainability Insights.

For more information:
Connect with IHEA Sustainability & Decarbonization Initiatives www.ihea.org/page/Sustainability
Article provided by IHEA Sustainability


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Heat Treat Radio #101: Heat Treat Tomorrow, Hydrogen Combustion 2023 – Fuel of the Future?

Doug Glenn, publisher of Heat Treat Today, moderates a panel of 4 industry experts who discuss how hydrogen combustion is being received in the market this past summer 2023, both in terms of availability to in-house heat treaters and the receptivity of using hydrogen for combustion by heat treaters. Experts include Mark Hannum, Fives North American Combustion, Inc; Brian Kelly, Honeywell Thermal Solutions; Robert Sanderson, Rockford Combustion; and Joe Wuenning, WS Thermal.

Get IMMEDIATE access to this highly-informative discussion.

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On-Site Hydrogen Generation Essential for Riverhawk Company’s Heat Treat Operations

OC

For heat treat operations, use of hydrogen comes with questions about price-point, safety, and storage or delivery. Read this case study to learn how a manufacturer with in-house heat treat, Riverhawk Company, contended with these questions and decided to meet stringent production requirements for pivot bearings by leveraging on-site hydrogen and a hydrogen furnace.

This original content article was written by Marie Pompili, a freelance writer, for Heat Treat Today's May 2023 Sustainable Heat Treat Technologies print edition.


For companies using hydrogen furnaces for heat treating operations, questions always surface surrounding the provision of the necessary hydrogen. Should we have it delivered in cylinders? Do we have the room outdoors for a large storage tank? Can we generate it ourselves? For Randy Gorman, maintenance supervisor at Riverhawk Company, the overriding question is always, “How do we handle hydrogen safely?” The ultimate solution the company chose was the installation of an on-site hydrogen generator. How and why the in-house heat treater came to that conclusion is an interesting story.

Making a History

Riverhawk staff (L to R): Spencer Roose, Flex Pivots Manager; Randy Gorman, Maintenance Supervisor; and Josh Suppa, Pivot Department Engineer
Source: Nel Hydrogen

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Located in New Hartford, NY, Riverhawk Company was established in 1993 as a value-added provider of hydraulic tooling. The company quickly grew from a “buy and assemble” operation to a manufacturer with 14 CNC machine tools, 21 conventional machines, and all the necessary peripheral devices, tools, and software. Through a period of smart acquisitions and the development of new product lines, Riverhawk became one of the leading manufacturers of tensioners, powertrain couplings, and accessories for the turbomachinery industry; the instrumentation product line of legacy torque and vibrations measuring instruments; and the Free- Flex® pivot bearings, which are very well known in high performance industry sectors.

Pivot Bearing Line Requires Improved Heat Treat Abilities

The Free-Flex® pivot bearing line is the focus in this heat treat/hydrogen story. Riverhawk purchased this line from Goodrich in 2004. It is the same product that was developed by Bendix more than 60 years ago. In fact, many of the original part numbers are the same, and the manufacturer strives to maintain the quality and performance characteristics that Bendix established more than six decades ago. Many of the manufacturer’s clients have been purchasing flex pivots for long-running applications, some of which are 25 to 50 years old.

Cantilevered-double ended thick spring. Riverhawk purchased the Free-Flex® pivot bearing line from Goodrich. Many of the company’s clients, in a wide range of critical industries, have been purchasing flex pivots for long-running applications.
Source: Nel Hydrogen

If a product line could talk, the flex pivots could share some tales and compelling accounts about all it has seen and done in the world’s most critical and sophisticated applications — many in the military, commercial aerospace, outer space, industrial robotics, medical, clean rooms, information technology, semiconductors, and many more. In all of these challenging sectors, clients are well-known and demand exacting results.

Shortly after integrating the pivot line into its existing production processes, it became clear that the company needed to improve its heat treat function. After researching several options, Riverhawk purchased a new Camco batch hydrogen furnace.

The pivot line consists of flat springs crossed at 90° and supporting cylindrical counter-rotating sleeves. Standard Free-Flex® pivots are made from 410 and 420 stainless steel; however, certain special material compositions include 455 stainless, Inconel 718, titanium, and maraging steel. During the manufacturing process for the flexure bearings, Riverhawk uses the batch atmosphere heat treat furnace to braze the springs to the body halves using a braze alloy, and to simultaneously heat treat certain components in the assembly. The atmosphere used for the heat treating and brazing is a 100% hydrogen atmosphere — chosen because it is universally applicable to all the different metallurgy used for the flex pivots.

The Tension: Delivered vs. On-site Hydrogen?

The use of a batch atmosphere heat treat furnace requires that the hydrogen atmosphere be flushed from the furnace with inert nitrogen when a finished batch is unloaded and a new load is added. Likewise, the furnace must return to inert atmosphere again with nitrogen after the new load is added, and before hydrogen is again injected; hence, hydrogen is used in a batch-wise fashion. The function of the hydrogen atmosphere is to prevent oxidation of the metal surfaces, and to promote fluxing of the braze alloy during the thermal cycle.

Until 2009, Riverhawk used hydrogen-filled cylinders to provide hydrogen to their batch heat treat furnace. Each run of the furnace would use several cylinders of hydrogen. Increases in production rates required careful management of hydrogen gas supply to the furnace. Running out of hydrogen mid-run could sacrifice a whole batch of nearly completed parts.

In 2009, the company elected to move away from hydrogen cylinders and transition to a hydrogen supply approach less disruptive to their production process. The choices were either bulk stored hydrogen or on-site hydrogen generation. After extensive consideration, they chose a model H2 hydrogen generator from Nel Hydrogen because the zero-inventory hydrogen generation saved the company money as compared to the cost of permitting, construction, and compliance for bulk stored hydrogen approaches.

The approach that was not chosen — delivered, stored bulk hydrogen — was unappealing for several reasons. Chief among these were the capital cost of the hydrogen storage infrastructure, the requirement for permitting for the necessary hydrogen storage, the accompanying project schedule risk for permitting, the continuous compliance issues with stored hydrogen, and the price volatility of delivered hydrogen that would have made cost accounting more difficult.

“The state and local regulations were likely necessary; however, there was a lot to wade through to become compliant,” said Gorman.

Finding the Best Way

Fast forward 14 years to today and Riverhawk is once again analyzing its approach to handling its hydrogen requirement.

“The H2 model generator that we have has served us well for 14 years, several years beyond the typical life of a cell stack,” said Gorman. “But we need more capacity and redundancy due to the increased demand for our Free-Flex® products and to cost-effectively mitigate the risk of a hydrogen generator issue, leaving us without the use of our furnace.”

The company decided to go with a model H4 hydrogen generator from Nel Hydrogen, which doubles their capacity with two cell stacks and the capacity for three if and when needed. The new system features the same footprint as the former H2 model, which is important to them, and they are even gaining floor space as they will eliminate the number of cylinders formerly stored nearby. The additional free space to move about also appeals to Gorman’s top mandate for safety.

Josh Suppa — engineer of the Pivot Department at Riverhawk — has had hands-on experience with this particular generator series (pictured above). “The maintenance of it is easy, and if there ever is a rare issue, Nel is quick to respond either in person or if it’s something that they can walk us through, they take all the time we need to resolve the matter and get us back online quickly. From a product line and customer satisfaction perspective, we cannot take the risk of our heat treat operation to go down for long. It’s that integral to our success. It’s essential, really, and one of our core competencies.”

Riverhawk will soon use a model H4 hydrogen generator from Nel Hydrogen, which doubles their capacity with two cell stacks and the capacity for three if and when needed. The new system features the same footprint as the former H2 (pictured here).
Source: Nel Hydrogen

Choosing On-Site Hydrogen Generation

Looking back on the initial decision to generate on site, one of the important issues that Riverhawk and Nel personnel had to determine was the most cost-effective configuration of the hydrogen generator and ancillaries to supply the hydrogen required for thermal processing. Had the manufacturer used a continuous furnace such as a belt furnace, then the calculations would have been easy, as the flow rate required would have been level and continuous. Instead, the batch furnace required more complex calculation because the hydrogen flow rate varies depending on the stage of the furnace cycle: fast hydrogen flow to fill the furnace, then slow to maintain the atmosphere, then no flow during parts removal and during loading. Additionally, there were many factors that affected the precise furnace cycles employed, including the size of the pivots in each batch, the number of parts loaded, and the specific metallurgy of the flex pivots in the batch. Overall, the cycle times can vary between 6 and 12 hours per batch.

It is important to seek out a knowledgeable hydrogen partner in this endeavor to specify exactly what’s needed, no more and no less. For heat treat applications, users generally would want compact equipment, extreme hydrogen purity, load following, near-instant on and instant off, and considerable hydrogen pressure that make it flexibly suited for a variety of thermal processes.

By combining on-site hydrogen generation with a small amount of in-process hydrogen surge storage if needed, on-site hydrogen generation can be used to meet the needs of batch processes, such as batch furnaces. By carefully choosing generation rate and pressure, and surge storage vessel volume, the process can provide maximum process flexibility while minimizing the amount of hydrogen actually stored.

In practice, client priorities such as minimum hydrogen storage, or lowest system capital cost, or highest degree of expandability, or least amount of space occupied can be met by choosing the specific hydrogen generator capacity and surge storage system employed for any particular production challenge.

In this case study, the optimum solution chosen was based on lowest capital cost and operating cost (including maintenance) while preserving the maximum possible expandability for production increases, and safety. These sound like common reasons and may be yours as well. Success continues at Riverhawk with the arrival of the new H4 generator in the coming weeks.

 

About the Author: Marie Pompili is a freelance writer and the owner of Gorman Pompili Communications, LLC.

For more information: 

Visit nelhydrogen.com and riverhawk.com.

 

 


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Heat Treat Radio #81 (Special Video Edition): Heat Treat Tomorrow – Hydrogen Combustion for Heat Treating: Reality or Smoke

Doug Glenn, publisher of Heat Treat Today, returns to the question on the future of hydrogen for heat treaters as he moderates a panel of five industry experts. What are the technological developments since last year and how do heat treaters need to prepare for these developments?

The experts who will give their take on the issue include Joe Wuenning, WS Thermal; Jeff Rafter, Selas Heat Technologies; Justin Dzik, Fives North American Combustion; John Clarke, Helios Electric Corporation; and Perry Stephens, EPRI.

Below, you can watch the video or listen to the podcast by clicking on the audio play button, or read an edited transcript. 




The following transcript has been edited for your reading enjoyment.

Doug Glenn (DG):  Well, we’d like to welcome everybody to a second round of Hydrogen Combustion. We’re going to have a discussion about hydrogen combustion here on Heat Treat Radio which is now really a Heat Treat Radio (and video). We’re welcoming back some of the same folks that talked with us from about one year ago.

Contact us with your Reader Feedback!

I want to do some introductions, reintroductions in most cases, and we’ve got one new participant on the panel this year. So, let’s start with the introductions and then we’re going to jump in. We’ve got about six questions to cover; hopefully we’ll be about 30–45 minutes of discussion on this.

Let’s first introduce John Clarke (if you want to raise your hand just to let everybody know who you are there). This is John Clarke. He is the technical director and owner of Helios Electric Corporation, a Fort Wayne, Indiana-based company that specializes in energy and combustion technologies. John is also a regular columnist for Heat Treat Today, which we appreciate, by the way, and has written 12 articles with our publication in a series called Combustion Corner. So, John, I want to thank you, and welcome.

Next is Justin. Justin is our “newbie” on this one, but not a newbie to the industry — of course! — but to this panel. Justin Dzik from Fives North American Combustion, Inc. is the manager of business development at Fives North America with a special focus in combustion engineering. Justin has written technical articles about Ultra Low NOx combustion technology for the steel industry and is closely involved with spearheading the advent of a thermal process combustion tuning solution that leverages industrial internet of things (IIOT) and Industry 4.0 technology. So, Justin, welcome, glad to have you with us this time.

Next is Jeff Rafter from Selas. Jeff is the VP of sales and marketing for Selas Heat Technology Co., the company being out of Streetsboro, Ohio; Jeff being out of somewhere in the lovely state of Wisconsin. Jeff has a rich history in the combustion industry including many years with Maxon Corporation, 29 years of industry experience in sales, research and development, and marketing, combustion application expertise in process heating, metals, refining and power generation. He also has 11 years of service on the NFPA 86 committee and holds patents for Ultra Low NOx burner design and is an IHEA member, as well.

Next is Perry Stephens. Perry is the principal technical leader for the Electric Power Research Institute (called EPRI) and, among other things, currently leads the End-Use Technical Subcommittee of the Low Carbon Resource Initiative, which is a collaborative effort with GTI Energy, formerly known as Gas Technology Institute and nearly 50 sponsor companies and organizations which is aiming and advancing low carbon fuel pathways on an economywide basis, hopefully towards the achievement of decarbonization. Perry is also an active member of the Industrial Heating Equipment Association (IHEA).

Jeff Rafter
Selas Heat Technology Company, LLC

We wanted to bring someone in, as we did last time — Joe Wuenning (Joachim Wuenning) — from Europe. Joe is the president and owner and CEO of WS Thermprocess Technic Gmbh [WS Wärmeprozesstechnik GmbH] in Germany and also WS Thermal Process Technology, Inc., in Elyria, Ohio, here in the States. Joe’s company has been on the cutting edge when it comes to hydrogen combustion, and Joe’s company is also an IHEA member company.

Gentlemen, welcome. Thanks a lot. Let’s just start off.

Jeff Rafter, I’m going to start with you, if you don’t mind. It’s been about a year since we spoke last, so the question is (and I’ll address this to all of you, but I’ll throw this one out to Jeff first): What has changed? In the last 12 months, have we seen any major changes in hydrogen combustion technology application?

Jeff Rafter (JR):  I think I would say, probably, that the dominant change over the last 12 months has just been general interest in momentum. We’re now seeing inquiries and interest from a variety of different industries. A lot of people are preparing for the future and starting to think about decarbonization in a bigger sense, and then watching that interest be amplified by geopolitical events, I think, is obviously a later discussion question that we’ll talk about, but we’re now getting to a place where parts of the world sincerely have more motivations. It’s now not just an environmental protection motivation, but we’re also seeing, really, a need to continue operations as fuel supplies, in some parts of the world, have now become called into question.

Dr.-Ing. Joachim G. Wünning
President
WS Wärmeprozesstechnik GmbH

DG:  Let’s go to Joe next and then after Joe we’ll jump over to Perry. Joe, what do you think? Any major changes in the last 12 months?

Joe Wuenning (JW):  Of course. Here, we are closer to Ukraine Russian war. Germany is directly, very much dependent on Russian gas and the real fear here for companies is that they have to shut down in the Fall because of gas shortages. So, that intensified, of course, the thinking about the future. One issue which became less important is the price. At the moment, the people think- do we even get gas and don’t think what it costs for it. Before, it was a big discussion if prices would go up by 5% or 10%; now, everybody is happy if they will get it and so, basically, we have no more jobs within Europe where that is not a point of discussion.

What can we do? Some people think about electrifying, of course, but we still produce electricity from gas, so that is not really the solution alone, and we don’t know what the electricity grid will do in the future, so flexibility has become a major player also besides. So, not only hydrogen but can we also go ammonia? Can we do other things? What are the options which keep us independent and doesn’t make us dependent so much on one source as it is now, at the moment?

Perry Stephens
Electric Power Research Institute (EPRI)

DG:  Let’s go to Perry and then over to Justin and then, John, we’ll finish up with you. Perry, what do you think — the last 12 months?

Perry Stephens (PS):  I would echo what Jeff said. I think we’re seeing not only sort of a general greater interest but the leadership of Fortune 500 companies which are global in nature and seeing all of these geopolitical situations occur, wanting to think through stabilizing their future energy supplies and understanding that the impacts of climate are beginning to really push down to their suppliers a desire to decarbonize all of their final energy pathways. So, they’re beginning to make inquiries in terms of how they can change over equipment and what needs to be done.

From a technology standpoint, we’re beginning to understand a bit more what elements of hydrogen combustion or blended hydrogen with natural gas, for example, have impacts on what parts of overall systems and what areas may have significant costs or performance impacts for which we may need to do a bit of additional research, so we’re beginning to understand where those impacts may be, as well. I think, finally, we’re beginning to see some results of research that sort of tells us, on an economy-wide basis, the drivers for demand for hydrogen and sort of under various scenarios how much hydrogen might be needed for various economic sectors including the industrial sector.

Justin Dzik
Manager of Business Development
Fives North American Combustion
Source: Fives North American Combustion

DG:  Justin, how about you? Now, you weren’t with us a year ago but if you can take your imagination back to about a year ago, what have you seen change on the hydrogen combustion side of things?

Justin Dzik (JD):  Honestly, what we’ve seen is just the growing acceptance across not only just industry but government and society that we need to transition from where we are with natural gas or conventional fuels to lower or zero carbon intensity. So, obviously, depending on where you are in the world, the exact timeline varies, but there is increasing focus on how we get from where we are to where we’ve got to go. Obviously, hydrogen is the purer, noncarbon footprint fuel so that’s obviously the ideal state. We’ve also received an increased amount of inquiries and interest in hydrogen, specifically on combustion equipment, and not only just from industry but from utility companies even here in the states talking about blending fuel and putting hydrogen in the natural gas lines and what effect that has on industry as well as some of the residential implications it might have, going forward, for their users.

DG:  John, how about you?

John B. Clarke
Technical Director
Helios Electric Corporation
Source: Helios Electrical Corporation

John Clarke (JC):  I believe we’re kind of living through that old Chinese curse — “May we live in interesting times!” — because we have seen disruptions, both on our energy supplies and our energy costs. In the U.S., we were tracking Henry Hub prices approaching $10 and now, all of a sudden then, we had a fire in pre-port and the price of natural gas fell 30%. But I think the long-term trend (and the trends are being recognized by everybody), is that we are in an international market, not only for oil, but for natural gas, as well. I think we’ve seen the effect really come home.

The other thing that’s going on, too, is the price of gasoline and transportation in the U.S. has skyrocketed and we’re now experiencing the kind of prices that Europe has lived with for years and years and years. I think all these factors, these externalities, are going to drive interest in any alternative. Hydrogen, for combustion, but hydrogen also for fuel cells and for automobiles. We’re kind of entering a period where I think our technological focus needs to be “all of the above” and I think there’s an acceptance throughout industry and industry leaders that that’s the path we have to be on to protect our businesses going forward.

DG:  So, it seems like the consensus, is, from a year ago, the interest — and to a certain extent some of the technologies is advancing, but at least the interest — is very much being advanced. So, it’s becoming more and more of an issue.

Let’s talk specifically and, Perry, I’m going to address this one to you first if you don’t mind: Have we seen in the last 12 months actually any new applications and/or industries that are aggressively adopting it? There is one that pops to my mind that’s been very obvious.

PS:  Probably the one you’re thinking about is the steel industry that has a specific nuance of steel production that huge amounts of fossil fuels, natural gas, cooking coal, are involved in the production of raw steel and so that reduction reaction, hydrogen can serve as a chemical-reducing agent. So, it not only introduces thermal inputs but also serves as a thermochemical-reducing agent to actually remove the oxides from the ore that allow you to liberate pure iron content that eventually becomes steel. Plus, a significant amount of process-related emissions that come from steel production make it a target industry, so they’ve been fairly aggressive, particularly in Europe, with a couple projects where hydrogen is involved. And the fact that, as we grow the use of steel, high-strength steel, and a lot of applications, globally, there will be a need to add new iron units into the system. A lot of steel is now recovered scrap steel that is melted through electric arc furnaces, but we need to add additional iron content. So, direct reduced iron processes are beginning to take a close look at hydrogen as a reducing agent and also for thermal inputs.

Quickly, beyond that, in most industrial settings, there is a lot of mobile equipment, and that mobile equipment uses a variety of diesel, compressed gas, propane and so forth, and those applications have a particularly easily converted to hydrogen type applications because they’re relatively small size and captive space; they compete with electric equipment in that space and so those two technologies will come forward.

"That is a little bit more challenging, but we see no real major problems towards that because, of course, we will not have hydrogen as a cheap fuel tomorrow, but we have to introduce it slowly if we have excess electricity converted to hydrogen and then get into the grid but therefore the burner systems have to be able to handle that — the change in compositions; not only switching but also the change in compositions." - Joe Wuenning, WS Thermal Process Technology

As far as other industries, the petrochemical industry uses a lot of hydrogen — they’re used to it. They’ll continue to look at both liberated hydrogen from process and other sources of hydrogen for their end-product production for process heating as well as inputs into the production of various synthetic fuels and other synthetic products that they make in the petrochemical industry.

So, those are the two — steel and petrochemical — in my view, probably most aggressively looking at hydrogen. Others may have other experience, as well.

DG:  Justin, let’s jump over to you next on that question; then, Joe, we’ll go to you after that. So, Justin, new applications? Is there anything of that sort you’ve seen?

JD:  Yes, absolutely. To echo what Perry said, obviously, the steel industry with their green steel initiative is really pushing forward. From our experience, a lot of interest is coming from the aluminum industry, as well. We play heavily in the aluminum industry, specifically on the melting side, and some major companies are interested in adopting hydrogen firing, especially the ones coming out of Europe and their interest really comes from what happens when you fire hydrogen fuel, and it interacts with the molten bath. There are a lot of material concerns with hydrogen, right? Not just in aluminum, but in titanium firing, as well. Those types of metals tend to have an affinity for hydrogen which could, obviously, have a detrimental effect on the final product. So, really there’s pilot scale tests, full scale tests, all kind of undertaking right now. Obviously, the focus is in Europe but a lot of European companies have plants in the U.S., so we’re seeing a lot of that kind of drift into our territory here and, obviously, being focused out of the European headquarters.

DG:  Joe, how about you?

JW:  We see a lot of projects right now are running now in the last 12 months. We have various customers which told us they want to try out, out of whatever their furnace with a hundred burners, so two of them run with hydrogen and see what happens — see what the emissions are, see what the burner life is, do they have varying parts? That is a part we do with many customers. It’s quite inexpensive to just try and see what happens. And then, we have two big research projects where we can do it in a more thorough manner, together with university, really also not only switch to hydrogen but also to see what happens if we switch back and forth. So, if we have hydrogen coming in, it goes to hydrogen, it should automatically adjust without human interference. That is a little bit more challenging, but we see no real major problems towards that because, of course, we will not have hydrogen as a cheap fuel tomorrow, but we have to introduce it slowly if we have excess electricity converted to hydrogen and then get into the grid but therefore the burner systems have to be able to handle that — the change in compositions; not only switching but also the change in compositions.

On the other hand, we are using hydrogen now in our lab for quite some time and the people in the lab, really, they get more and more used to it. I think they think it’s more and more rather the better fuel than natural gas, cleaner fuel the more they work with it, and I think not really too many people are concerned now that it could be a replacement if the hydrogen would be easily available.

"But what we’ve seen in the last 12 months is now a general interest shift and we’re starting to field inquiries and take on demonstration projects and things that we would traditionally consider low-temperature heating: baking applications, foods production, metal finishing. And it tells me that, again, momentum is building." - Jeff Rafter, Selas Heat Technologies

DG:  Yes, being easily available is an issue, I’m sure. We’ll talk about that a little bit more.

John, how about you? Any new applications, new industries that are adopting?

JC:  The thing I have seen is a little off the core of your question, but I’ve seen a couple of municipalities dealing with some of their distribution challenges, and that I’ve seen in the last year where they recognize that hydrogen is a potential opportunity to save on carbon emissions but what would it take and at what percentages can you introduce what kind of impact will it have on common appliances? That is a trend, too, and I think the middle between the production and the utilization is going to be a serious challenge for us in the U.S. and it’s an impediment if we’re trying to advance the front. You know, we have to advance on all three fronts simultaneously if we’re going to achieve an effective market. I’ve seen some very encouraging work now being considered at the local distribution level.

DG: Yes, I think we talked last time. Maybe it was Jeff Rafter, I can’t remember if you brought it up, about some of the distribution snags that we might see in New England with type of old pipe or something like that- wood pipes or something, I forget what it is.

It’s your shot, Jeff, so you go ahead. Any advances? And you can comment on that if you like.

JR:  I guess I would say what’s different is that the dominant pattern over the last couple of years that we’ve seen is primarily most of the interest came from industries that were highly energy intensive which usually travels with a high temperature process. So, it goes without saying that many of the early adopters were glass, steel, other metals. But what we’ve seen in the last 12 months is now a general interest shift and we’re starting to field inquiries and take on demonstration projects and things that we would traditionally consider low-temperature heating: baking applications, foods production, metal finishing. And it tells me that, again, momentum is building.

I think, in general, industries beginning to be comfortable with the concept of decarbonization and low carbon fuels, whether it’s ammonia, whether it's hydrogen, but, again, the recognition is that we’re only going to get so far until we see some more significant advancements in the generation of hydrogen and the distribution of hydrogen. Again, I think that remains probably the largest hill that we have to crest before we really get through some significant decarbonization impacts.

DG:  It seem that everybody really loves the concept; it’s just the matter of producing it and getting it where it needs to be.

"[Heat] treaters use a lot of hydrogen as an atmosphere, and they use it chemically rather than as an energy source. So, I think when the price comes down, they will jump very quickly on the use of hydrogen or hydrogen blends for furnace atmospheres to replace endo or nitromethanol atmospheres."

Just a quick question to follow-up on this one before we move on to the next question which, John, I’ll address to you first. But, just real quick, a lightening round here: Has anybody seen any significant application of hydrogen, specifically in heat treat, whether it be a commercial heat treat or a captive heat treat? Jeff, have you seen anything? I don’t know that I have the answer, so I’m just curious — have you seen anything, Jeff?

JR:  Nothing specific, and I think I’ll take an attempt at explaining why. I think it’s because so much of the heat treat application is really dominated by commercial heat treaters. I think they all do the bulk of most of the capacity. Where end-use companies do indeed have internal or vertically integrated heat treat, we have some interest but nothing yet in terms of meaningful commercial activity where we’ve seen commitment to projects. A couple of major industrial manufacturers have brought forward projects and studies, but nothing on-line that I’m aware of, at least in our space.

DG:  Joe, how about you? Anything in the heat treat specific, just briefly?

JW:  In the heat treat industry, like I said, single burners, of course. No complete heat treat shop will switch to hydrogen --- it’s simply too expensive. But we don’t need to switch/convert all operations; we can take one or two burners and see that it works.

DG:  Justin, how about you? Anything specifically in heat treat?

JD:  No, we haven’t had anything in heat treat, mainly for the reasons, I think, John has already highlighted.

DG:  John, how about you? Anything specific you’ve seen in heat treat?

JC:  No, but I would like to also point out that our heat treaters use a lot of hydrogen as an atmosphere, and they use it chemically rather than as an energy source. So, I think when the price comes down, they will jump very quickly on the use of hydrogen or hydrogen blends for furnace atmospheres to replace endo or nitromethanol atmospheres.

DG:  Joe, did you want to add something?

JW:  Just a comment:  That makes it of course easier since many of the heat treaters have the hydrogen tank available, making tests is not really getting the hydrogen. It’s more expensive for a little while, but they can run the tests for a week or so and that’s done then pretty easily.

DG:  Perry, anything specific in heat treat?

PS:  The short answer is no; we’ve not seen or heard of anyone, primarily because of that. There are a lot of inquiries around direct electrification as an alternative but that doesn’t work in every case. There are a number of scenarios where that’s not a viable decarbonization pathway and so we need to continue to pursue this as aggressively as we can, but at this point, that, the market price of hydrogen and, I’ll add, the sort of working out of a reliable supply chain of hydrogen because, right now, tube trucks is probably the only way you could really deliver hydrogen reliably to a remote heat treat shop so there is a supply issue there, as well.

DG:  And just to unduly poke fun at Perry, you’re the only guy on here that is allowed to mention electricity and get away with it, okay? The rest of us don’t even like that topic. ~chuckle~

John, I’m going to jump over to you on this question. It may or may not apply to you in this case, but your company: What have you specifically been doing developing, let’s say encouraging, over the last 12 months? This is kind of a time when you can tell people what your company is doing.

JC:  As far as technology, nothing like my colleagues on this roundtable. We have spent and spend a good deal of time running economic simulations for major users but we still act as consultants. I wouldn’t say we’re laying the groundwork, but when the economic data can be put in, we’ll be in a position to better and more rapidly provide people good, accurate feedback as to cost of switching and cost of implementation.

DG:  I think you and Perry kind of are maybe a little bit more on the consulting side, so it will be interesting to see what Perry has to say. But let’s go to Joe next. Joe, what has your company been doing? Then, Justin, we’ll jump over to you after Joe.

JW:  At the moment, we are doing two things:  one is installing a bigger ammonia tank because we want to get into using ammonia as a form of indirect hydrogen combustion. Do we need to crack it first? Can we use it directly? How far have to purify it? These are questions we want to resolve and do in-house. That is one thing. And then also to improve our hydrogen supply, we will install an electrolyzer. We have a lot of solar on our roofs. It’s not directly our business to produce hydrogen, but we want to have the knowledge to tell our solar customers- does it make sense to produce your own hydrogen on site or should it come from the pipeline? What are the options here? We want to be prepared for that.

DG:  Justin, over to you, and then Perry, then we’ll finish up with Jeff.

"[So] we’ll really be focusing on not only the burners ability to run hydrogen . . . but also we’re going to try to really look at the material impacts that hydrogen has on heating and as well as metallurgy to try to help some of these end-users because obviously this is a huge shift going from natural gas to hydrogen." - Justin Dzik, Fives North American Combustion

JD:  As of about two months ago, we just fired hydrogen on our regenerative burners. This was in an effort to supply data for our talk at AISTech in Pittsburgh, back in May, where we sat on a panel about decarb. From that, we are actually in the process of breaking ground on installing a permanent hydrogen facility to supply our lab with hydrogen fuel for all our test furnaces.

From what I’ve been told, we’re looking in aiming at about 10 million BTU an hour as the max capacity, so we’ll really be focusing on not only the burners ability to run hydrogen --- we’ll focus on the markets, obviously steel and aluminum first because those have shown the greatest interest, what burners actually go on those, testing the burners ability to run hydrogen; but also we’re going to try to really look at the material impacts that hydrogen has on heating and as well as metallurgy to try to help some of these end-users because obviously this is a huge shift going from natural gas to hydrogen. So, over the next year, we hope to make significant headway in, obviously, our hydrogen studies in our conventional burners here.

DG:  Perry, how about you? What are you seeing?

PS:  From a purely industrial perspective, we have a handful of projects that we’re working on now. They are essentially down-selecting the most viable pathways for industrial process heating through alternate energy carriers, whatever those might be. We have sister groups within our low carbon resources initiative that are looking at the production and transportation storage of hydrogen, whether that is the electrolysis of hydrogen from water, whether that happens to be the use of steam methane reformation with a carbon captured scenario associated with that, and we’re looking at the cost and performance of all of those particular pathways.

And looking at that for a couple of different sizes of steam boilers as well as direct combustion which is, I think, the primary focus here, and a variety of different types of furnaces, ovens, heaters and a variety of different types of burner configurations in order to assess cost and performance of those, and then begin to do the technoeconomic analysis to determine where these technologies might compete as we project the cost and delivering storage costs of hydrogen into these locations regionally where these industries may be located. So, we’re doing all of that work to basically circle wagons around the most important research that we need to do going forward.

We’re also involved in an oxy firing project with GTI Energy which is looking at, right now, natural gas but also evaluating oxy firing. Of course, if you electrolyze hydrogen, you liberate a lot of oxygen from water and that oxygen is valuable and can be a very important constituent in oxy firing combustion which has a variety of advantages, whether you do carbon capture at the source or just trying to improve the overall thermal efficiency of the process. Those are some areas that we’re working on right now.

DG:  Jeff, how about Selas? What’s been going on the last 12 months or so?

JR:  Well, I think the last year has really just been a continued pattern of counseling customers on applications and, in specific, what particular burner styles are appropriate for utilizing hydrogen in different processes. But I will say, the other topic that is starting to garner some of our attention and efforts is thinking forward about codes and standards as an enabler for more of industry to get interested in decarbonization and, realistically, while burning hydrogen is relatively easy, the handling and distribution of hydrogen has yet to really permeate the codes and standards that we use on a daily basis to govern design of products and processes. Again, it’s not unknown; it’s used in other industries for other purposes like heat treating, like refining, but we need to bring that knowledge into our codes and standards and really kind of be the highway for industries and customers to be able to convert without a significant amount of “white sheet of paper” engineering.

"I think the work that the steel industry is doing is interesting from a couple of perspectives. One is: How do you supply huge amounts of hydrogen, at scale, at a cost that is reasonably competitive? So, they’re really challenging that outer envelope in terms of how much hydrogen, and in what manner, it needs to be produced, whether blue hydrogen or green hydrogen, and really pushing forward to ultimately, hopefully, drive the price of hydrogen down, green hydrogen."

DG:  Are you still at all involved with the NFPA? Is that the type of standards you’re talking about, like the 86’s and things of that sort?

JR:  NFPA 86, obviously 85 you could drive into the boiler’s world, 87 if you go into process heaters.

DG:  Are you still involved with that? I know it says you have done that in the past.

JR:  No, I am not currently on the committee.

DG:  But you’d know enough about what’s going on in those, so that’s good.

A quick question. I don’t know that we need to spend a lot of time of this. Justin, I’m going to start with you on this one. We talked about it earlier, about the steel industry and the fact that they seem to be with steel and/or aluminum, but steel specifically, I guess; they seem to be one of the early adopters, or at least attempting to adopt it. The specific question here is: Do you see what they are doing in the steel industry as having any impact beneficial (and/or otherwise) on the heat treat industry, at all? Is there any obvious connection between what they’re doing and how it might apply to a captive heat treater or potentially a commercial heat treater?

JD:  Yes. Obviously you have to a crystal ball to know what the future is, but obviously, I think, as the demand for 100% green steel increases and the green steel producers can push their will down on scope 1, 2, 3 suppliers, you’re going to see all processing steps will need to be decarbonized. That’s the future goal, that’s the future state. So, obviously if you go down far enough in the scopes, obviously that includes processes for heat treatments of steel. Who knows how long that will take, but for sure, that is probably the future path in the next quarter century or so.

DG:  John, how about you? Do you see any benefit or any impact in what’s going on in the steel industry on the heat treat? After John, we’ll go to Jeff.

JC:  Specifically, in the short-term, no, but it’s like with any technological initiative, often there are unforeseen breakthroughs, unforeseen bits of technology that are developed that are very beneficial. Again, it’s the “known unknown” in technological development — we don’t know what it will be but, from experience, we know it’s there. So, I’m optimistic that something will benefit them, but I can’t tell you what it is.

DG:  Jeff, how about you?

JR:  Well, I’ll take a little bit of a projective throw at this one and that is I think that experiences in the steel industry will help some types of heat treating, in particular, direct-fired applications like annealing. When we move to atmosphere furnaces, I think you get to a position where the application becomes so unique that the experiences in steel probably don’t translate. So, I think there are a couple of different bodies of transferability, so to say; when we look at what happens in steel or other industries, I think it’s going to application specific.

DG:  Perry, what about you? Then we’ll finish up with Joe.

PS:  I think the work that the steel industry is doing is interesting from a couple of perspectives. One is: How do you supply huge amounts of hydrogen, at scale, at a cost that is reasonably competitive? So, they’re really challenging that outer envelope in terms of how much hydrogen, and in what manner, it needs to be produced, whether blue hydrogen or green hydrogen, and really pushing forward to ultimately, hopefully, drive the price of hydrogen down, green hydrogen.

They are also, I think, helping us to evaluate what we need to understand about valve trains, other supply components and materials, whether that’s seals, and at pressure, obviously, hydrogen has a little quirk of wanting to embrittle carbon steels that may be used for storage or transport. So, work around how to really pardon the systems such that those risks can be mitigated and understanding what it’s going to cost to convert when we go to higher and higher concentrations of hydrogen, up to 100% hydrogen, as a fuel or reducing agent. So, they’re pushing the envelope; the rest of us will be able to take advantage of what they learn.

DG:  So, Joe, I think in Europe, the steel industry is probably a little bit more aggressive than the rest of the world. What are you thinking about what they’re doing there and how it might benefit heat treaters specifically?

JW:  I’m very happy about that — that they are moving forward and being proactive. I think it used to be a dirty, complaining, dying industry (the steel industry), and now suddenly they are on the forefront of really changing themselves and really wanting to do that. I think we will, absolutely, also profit from that. We see students coming to apply for work from us because they think that’s the future: to work in that business and, I think, that’s true, but that was different twenty years ago when everybody thought maybe we will have no steel industry in twenty years. It might sound stupid that we will have steel industry, but the steel industry presented themselves as being “go to Gary, Indiana or whatever,” if you don’t think that’s a future industry, but that is changing at the moment, and I am very happy about that.

DG:  I would like to start with Joe, actually, we’ll just start with you; let’s reverse the course on this one. Let’s talk about obstacles. Whether it be production of hydrogen, distribution of hydrogen, or other technologies, what do you see being the main obstacles for adoption? And again, if you can tailor comments specifically into heat treat, fine, but I think, to a certain extent, where we see it being done in steel and aluminum then, probably, the obstacles will be very similar for the heat treat market.

Joe, what do you think?

JW:  I think, at the moment, of course, it’s uncertainty. The people are a little bit sometimes wait-and-see because nobody knows. Will it be electricity? Will it be widely available for affordable prices? Will it be energy carriers? So, I think,  and in general, at the moment, of course, there is a lot of uncertainty. What will happen with China? What will happen here? So, it’s very different. Some people just now are sitting there like a little rabbit and doing nothing; other companies are still active and say and see what their options are. I think we will see a lot of changes into the next decade compared to the past and it will be interesting times.

JW:  I think the uncertainty, that is, of course, there is no clear pathway to go; everybody has to make their own decisions.

DG:  Perry, how about you? Main obstacles for the adoption of hydrogen?

PS:  It’s the big elephant in the room: the price. It has to come down in price at the burner tip to be competitive or else, globally, there has to be some agreement which is very difficult to obtain in terms of, sort of, regional competitiveness and globally economic competitiveness of industries. And so, something has to be done.

We have to continue to pursue how we’re going to produce hydrogen, transport and store it and have it become cost effective at the end-use. There are a  number of strategies around how to do that but, obviously, if you’re going to electrolyze it, there’s a lot of work looking at how that could be improved in terms of its overall, final efficiency. That’s the biggest challenge. I think, the other transport and storage attributes can be overcome technically; I think we kind of know how to do that.

There is a big decision, I think, with regard to whether we produce hydrogen centrally and then move it around the world in various modes of transport including pipelines, which is generally the most cost-effective way, or in some cases, do you produce that in situ and then the question of whether or not you use steam methane reformation of a fossil fuel and carbon capture — that’s a policy matter.

I will say this: our first round of studies and sort of bookend scenarios that we’ve looked at for hydrogen production and use economywide suggests that policy matters a lot and whether or now we allow carbon capture and sequestration will make a huge difference in the degree to which hydrogen penetrates economically, markets beyond the very big ones that we’ve talked about. So, if we get into heat treat shops, other end-use applications, economically and transport and buildings, a lot depends on where we end up with carbon policy.

DG:  Jeff, how about you? Obstacles?

JR:  Well, very similar comments to what Perry had said — it has a lot to do with economics, distribution, and availability. Obviously, the last 12 months has not been a typical economic environment for what we’ve enjoyed for fuel security in the last 40 or 50 years, and I think, at this point, nobody has a crystal ball to determine what the relative price of fuel alternatives is going to look like going forward. Obviously, the hydrogen play is still reasonably new from the perspective that we need better ways to generate hydrogen, ones that could put the fuel on par or near natural gas, and as a real-world example of that is we’ve actually seen a resurgence in interest for firing liquid fuels as an alternative to a nonsecure natural gas supply and why? For the simple reason that they’re transportable without a pipeline. So, it will be interesting, but I think it’s that juncture of economics, supply and distribution that’s really going to be the determinate on where we land 10 or 15 years from now.

DG:  John, how about you? Obstacles?

JC:  For the heat treat area, I think the transportation. Heat treats, unlike steel mills, unlike petrochemical facilities, tend not to be collocated. The commercial heat treat and the captive heat treat tend to be distributed and they’re used to being able to obtain natural gas from a pipe on the road. So, until we have a means to run more pipe, which is a challenge, it’s a very real challenge, especially if you’re trying to obtain a new right-of-way in the U.S., that’s an extremely lengthy period of time. So, assuming, and I’ll assume for one minute that the cost of production, that issue can be dealt with. I think distribution, very likely, will be a longer-term impediment for heat treat in the U.S., maybe not so much for steel or other applications.

DG:  Justin, how about you? Last one here on the obstacles.

JD:  Yes, obviously, to just echo everyone else — it’s cost and availability, right? So, cost is like ten times what natural gas is right now so, in availability, like John said, do we have a pipeline that goes around the United States with it, that’s quite difficult, or do we produce at site? And then we have to consider the manufacturing capacity of the electrolyzers and the device if we’re going to do it on site; can that keep up with the demand?

Operationally, the cost. You know, thermal efficiency and process integration — really those things will help bring down the cost of hydrogen. The other industries like steel and aluminum are advocates of heat recovery right now — they employ it with recuperative technology or regenerative. Heat treaters don’t really do that and, I think, that is kind of a need when you’re switching to hydrogen to try to bring the cost close. It’s never going to be equal, but to bring it closer to natural gas, heat recovery is almost a must.

DG:  Production and distribution, yes, as somebody said, “it’s cost at the nozzle,” how much is it costing?

If anybody wants to comment on this, fine, otherwise we’ll gloss over it and move on to the last question, but somebody commented and said, “I don’t know if you’ve noticed or not, but three-quarters of the earth is made up of water with two hydrogen and one oxygen, right? I don’t know if you noticed, but the bond between those two things is very, very strong.” It’s very difficult to break the hydrogen away from the oxygen. So, almost anything we do to produce it from that, the most abundant source, it seems like, would be water, would be very, very expensive. Does anybody want to comment on that?

JR:  Just one additional thought is that in addition to water being widely available, the other challenge you have to have is you’re typically looking for a relatively clean source of water to run through an electrolyzer, and if you think about just what you see on the news every night, we already have a challenge where many parts of the world are having difficulty coming up with adequate supplies of clean, fresh water. So, desalinization definitely has a play in there, but the abundance of water, or hydrogen being the most abundant element in the universe, really doesn’t solve our problems. There are still a lot of developmental challenges around the generation of hydrogen.

DG:  Anyone else care to comment on that before we move on? Joe, go ahead.

JW:  Regarding the price, of course, that’s a little relative. We fear the moment the natural gas prices triple and quadrupling, it’s also the hydrogen price has to come down. But if the net/gas price goes up steeply, that will then make them also equal, just at another level, not that it’s what the people want but that could well make it much more attractive sooner natural price gas go up.

DG:  It’s all the relative price, you’re correct. Any other comments? I think it’s a good segue into our last question and that is: the disruptions that we’ve seen, geopolitical situations and what impact that’s having on the advancement of hydrogen.

Justin, why don’t we start with you on this one. Any comment on the geopolitical situation, how that’s helping or hurting the current move to hydrogen?

JD:  Yes, obviously every day it’s changing, so every day it’s making a different effect. But with the increased upward pressure on fossil fuels due to the geopolitical environment, there are potential cost penalties for changing from fossil fuel to carbon-neutral fuels like hydrogen that may be decreased, obviously. So, the desire to maintain the production capability in the face of fossil fuel shortage may further drive switching to hydrogen — hopefully, it will — or other carbon neutral fuels and obviously or ways to achieve the thermal input needed for the processing steps for all these customers.

DG:  Perry, how about you? Any comment on the geopolitical situation?

PS:  It’s unpredictable. I think the volatility of fossil fuels is an issue. The attraction that we have, at the moment, for hydrogen is that, ultimately, if we look at the production of green hydrogen, it would come from some renewable source.

Now, that could be biofuels that are hydrocarbon-based that are produced in natural avenues that are carbon-fixing so they’re renewable, but when you look at the green pathway for hydrogen through electrolysis, you’ve got to use electricity and so the attractiveness to that right now is that there are periods of time where we have a lot of excess power and we need to store that; batteries are not a good option for the volumes and timeframes that we want to store that power and so production and storage of hydrogen so that we then can reuse it either directly as combustible fuel somewhere or otherwise. That helps the whole energy system work a little better in terms of periods of higher and lower demand and so, I think, to me, that’s going to be sort of near-term more likely to drive things.

I think the geopolitical situations create a lot of interest and realization that we’ve got to do something, but the changes that are going to have to happen, I don’t think they’re going to happen fast enough to respond to those kinds of shock scenarios. So, this is going to take some time for us to deliver an integrated energy system takes advantages of low-cost power to produce hydrogen pulls together production distribution systems that end up working on a fairly seamless and effective final energy distribution system. So, this is not a quick fix.

DG:  John, how about you? Geopolitical situation.

JC: Speaking as an American, our geopolitical concerns differ greatly with our European friends. We produce and export 10% of the natural gas — or attempt to export 10% of the natural gas we produce, so we are actually awash with natural gas while our European friends are not. Even if the instability in Ukraine is settled tomorrow, the question comes up: Can Europe trust Russia, long-term, to be a critical supplier and, arguably, I think you can’t. So, I think there’s going to be a divergence.

But even in the U.S., we have a significant political risk that we have to recognize and that is forming a consensus to put in place the necessary rules and put in place the necessary legislation to enable this transformation because we have yet to form a solid consensus in the U.S. that decarbonization is necessary. There are a lot of, again, I’ll use the term “externalities” at play and in the U.S. we, ourselves, even with all our resources are not yet in a position to form any sort of coherent plan to tackle this initiative. So, I caution people from the political side to keep working on the technology and keep writing your congressman.

DG:  Two fronts there. So, Joe, give us the unique perspective from Europe on this. Geopolitically, you’re going to have a little different perspective here.

JW:  John already mentioned, of course, we are in a different position because we don’t have our own energy sources and now, I think, we are hurt pretty badly by relying on cheap, Russian natural gas supply. We thought that we would get that forever and very reliably and that’s not the case. So, I think we have to diversify, we have to get more of our own resources, we have to conserve energy, use less, because otherwise we are just dependent — we are not free in our political possibilities if we have to rely on that cheap energy. Of course, to a degree, maybe, that is a little different in the U.S. but being dependent if everybody goes out on the street if the electricity shuts off and the air conditioning cuts down is also a kind of dependency on certain things so no telling for the future. So, I think that dependency on cheap energy is dangerous everywhere. And we should work on that to be here more conservative in using it — using less, using on-site; you can have local tank and there have your own air condition on every roof and not depend on the grid and everything. I think that would be good. We learn the hard way right now, but I think sort of which it wouldn’t hurt for the U.S. to do certain things the same way.

DG:  Learn by watching rather than learn by doing, you know?

Jeff, how about you?

JR:  Well, I think the current geopolitical situation is a reminder that although we’ve enjoyed five decades of really stable, inexpensive energy supply, it’s never guaranteed. It’s been quite a while since we had this type of market disruption around fuel supplies, but it’s a reminder that fuel supplies and energy really are a worldwide market that are deeply interlinked region to region. So, as we look at potential changes and what’s coming forward, I think we have to give a significant amount of focus to where we can make the most impact and decarbonization, and manufacturing really represents, at least in the United States, about a third of all the natural gas consumption. That means that two-thirds of it is power generation residential building and heat and from that perspective it kind of echoes Joe’s comments that it’s multiple technological advancements and market changes at the same time that are going to drive the initiative forward; it can’t just be heat treating or manufacturing, it has to be a union of multiple technological changes and adoptions at the same time for heat, power, electricity and industrial heating.

DG:  That wraps up the initial questions that you all knew about ahead of time, so I’m just going to throw out one more: If there was something we were talking about here and you said, “You know, this is really something important that ought to be said.” Did anything like that jump to your mind? Is there anything that you would say kind of as a concluding or also a “Hey, let’s not forget about this?” Anything come to mind?

PS:  I’ll jump in, Doug, just tagging on to what Jeff just said. Just a reminder that our energy systems, our supply of binary energy where the energy comes from and the final end-use systems are interconnected by very complex markets and delivery and storage systems, whether you’re talking about power, natural gas, fossil fuels, other liquid fuels and so forth. Those sources, whether you’re looking at bio sources, have limitations in terms of land use or whether you’re looking at hydrolysis of water, whether that be the cost or the impact on water resources and availability or whether you’re looking at wind and solar- all of them have their positives and their negatives. In the end, the marketplace, with all of these various end uses, there are a lot of societal decisions we’re going to have to make around who gets access to which sources. As an example, aviation fuel is a very difficult one to replace in terms of the liquid fuel because of energy density needed and the need to carry it along with you. How do we ensure that aviation gets the  type of fuel at a cost that we can all withstand?

So, whether a lot of competition — not just within our industry that we’re talking about here, but amongst all aspects of the economywide uses of these various fuels, including hydrogen — there will be competitive forces that ultimately will create challenges for where and how we use hydrogen and how we produce it and where the best end-uses of hydrogen, specifically, would be, or other fuels like Joe mentioned- ammonia has its interesting potential areas where it could be applied as a combustible fuel and so forth. We just need to understand that there are complex economics involved in determining to what degree hydrogen may end up being a fuel for industrial furnaces.

DG:  Anyone else? Something that needs to be mentioned you might’ve forgot?

JR:  I would throw in one other comment. Knowing that the audience, for most of this presentation, is going to be in heat treating, I think perhaps one word of advice would be: hedge your bets. Design in and plan for flexibility. Being linked to one energy source is probably not economically advisable for any manufacturing business at least until markets and geopolitical events settle down.

DG:  That’s a good point.

Gentlemen, thanks a lot, I appreciate the update in 12 months. Justin, thank you for joining us this time, I appreciate that.

 

For more information, go to:

Jeff Rafter: www.selas.com

Justin Dzik: www.fivesgroup.com

Joe Wuenning: www.flox.com

Perry Stephens: www.epri.com

John Clarke: www.helios-corp.com

 

Doug Glenn <br> Publisher <br> Heat Treat Today

Doug Glenn
Publisher
Heat Treat Today


To find other Heat Treat Radio episodes, go to www.heattreattoday.com/radio .


.

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Heat Treat Radio #81 (Special Video Edition): Heat Treat Tomorrow – Hydrogen Combustion for Heat Treating: Reality or Smoke Read More »

Natural Gas Revisited

OCNatural gas is the dominant energy source used by heat treaters and its price and availability is critical to all U.S. industry, so let’s look at the data and nail down some simple quantitative facts and maybe answer this pressing question: How will the war in Ukraine impact natural gas production and consumption?

This column is a Combustion Corner feature written by John Clarke, technical director at Helios Electric Corporation, and appeared in Heat Treat Today’s May 2022 Induction Heating print edition.

If you have suggestions for savings opportunities you’d like John to explore for future columns, please email Karen@heattreattoday.com.


John B. Clarke
Technical Director
Helios Electric Corporation
Source: Helios Electrical Corporation

As political pundits seek to explain the cause and impact of the war in Ukraine, I am struck by the lack of quantitative information they use to support their opinions and analyses. Given the complexity of the U.S. energy market, with a myriad of imports and exports between countries (especially Canada and Mexico), it is no wonder that people can support any preconception they have by simply omitting this import or that export. As always, we will focus exclusively on natural gas.

Let’s start with some basic facts. FACT: 40% of our electricity in the U.S. in 2021 was generated using natural gas1 and 20% of electricity generated in Europe is from natural gas2 — so even a vacuum furnace runs on a substantial quantity of this fuel.

One of the challenges when discussing energy markets is the many different units of measure people use to describe production, consumption, and costs. Our preferred unit of measure for natural gas production and consumption will be trillion cubic feet or 1 quadrillion British Thermal Units (BTU)* per year (one cubic foot of natural gas contains 1000 BTU (HHV)). To put this in perspective, if we pay $4.70 per mmBTU** — one trillion cubic feet is valued at 4.7 billion dollars. In 2021, the United States produced 34.1 trillion cubic feet or roughly 161 billion dollars of dry natural gas.

 

FACT: U.S. production of natural gas was at an all-time high in 2021 and is rising.3, 4 The U.S. is the largest producer of natural gas in the world by a significant margin. U.S. consumption has fallen over the last two years because of our COVID recession — but it is projected to rise in 2022.

 

Liquified Natural Gas (LNG) Exports

Natural gas can be exported via ship in its liquified state. The following graph shows the U.S. exports of LNG in recent years.5 Our ability to export LNG is limited by facilities that compress and cool the gas to its liquid state and the availability of tankers to move the gas across the ocean. Both ports and ships require significant capital investments and take time to construct — so there is a limit to the rate we can expand exports. Even as we export LNG, we continue to import some natural gas from Canada — but we are obviously a net exporter of natural gas by a considerable margin.

FACT: In 2021, the U.S. exported roughly 10% of the natural gas it produced as LNG. The U.S. is currently the largest exporter of LNG6 while Russia is the largest exporter of gaseous natural gas. Australia and Qatar are also major players in the LNG export market, and we may see these three countries vying for the top spot in the coming decade. The big advantage enjoyed by LNG is once liquified, it is a fungible source of energy — it can be exported to anywhere with a suitable port. Gaseous natural gas must travel through a pipe.

In 2021, the European countries in the Organization for Economic Co-operation and Development (OECD) together imported about 80% of the natural gas they use. Of this number, roughly 6.6 trillion cubic feet per year is imported from Russia, the largest importers of Russian gas include Germany — 1.70, Turkey — 0.95, Italy — 0.92, and France — 0.62 trillion cubic feet per year.

The U.S. has significantly expanded its LNG supplies to Europe in 2019—20217 to an annual rate of 1.86 trillion cubic feet in January of 2022,8 but LNG import capacity is still limited — with additional import facilities coming online in the next few years. Prior to 2019, Europe had little volume of LNG imports, so all the movement of natural gas was by pipeline.

While our price for natural gas in the U.S. has gone up considerably in the last year (approaching a mean of about $5.00 per mmBTU on the spot market), the price in Europe is running about six times as much — $30.00, with recent spikes as high as $60.00 per mmBTU. So, we load a typical LNG tanker with $15 million in natural gas in the U.S., and in 20 days, we lose 4% of the load to vapor, which we burn to power the ship, and offload $86 million at a port in Germany. Of course — this is an oversimplification, but the point is obvious. This price differential will continue to drive the market to invest in new production, LNG ports and ships — and apply upward pressure to our domestic price.

With or without the instability caused by the Russian invasion of Ukraine, we can expect a reliable supply of natural gas to fuel our furnaces and generate our electricity in the United States, but we can also expect higher prices to remain with us for the foreseeable future. Can the U.S. supplant Russia’s natural gas imports? The data indicates the answer is yes — but it will take time and investment. No matter what the outcome of the current war, the West will question the reliability of Russia as an energy supplier and explore all options to lessen their dependency on Russia’s oil and natural gas exports.

 

*1 BTU is the energy required to heat 1 pound of water, 1 degree Fahrenheit.

**Rough Henry Hub Price per mmBTU of natural gas at time of publication

References

[1] “Electricity explained: Electricity in the United States,” EIA.gov, March 18, 2021, https://www.eia.gov/energyexplained/electricity/electricity-in-the-us.php#:~:text=Natural%20gas%20was%20the%20largest,power%20plants%20use%20steam%20turbines.

[2] Statistical Review of World Energy — 2021. PDF File, 2021, https://www.bp.com/content/dam/bp/business-sites/en/global/corporate/pdfs/energy-economics/statistical-review/bp-stats-review-2021-eu-insights.pdf.

[3] Kirby Lawrence and Troy Cook, “EIA forecasts U.S. natural gas production will establish a new monthly record high in 2022,” EIA.gov, December 16, 2021, https://www.eia.gov/todayinenergy/detail.php?id=50678.

[4] “Natural Gas Summary,” EIA.gov, February 28, 2022, https://www.eia.gov/dnav/ng/ng_sum_lsum_a_EPG0_FPD_mmcf_a.htm.

[5] “Liquefied U.S. Natural Gas Exports,” EIA.gov, February 28, 2022, https://www.eia.gov/dnav/ng/hist/n9133us2A.htm.

[6] Mundahl, Erin. “We’re #1! U.S. Ends 2021 as World’s Largest LNG Exporter,” energyindepth.org, January 5, 2022, https://www.energyindepth.org/were-1-u-s-ends-2021-as-worlds-largest-lng-exporter/.

[7] Victoria Zaretskaya and Warren Wilczewski, “Europe relies primarily on imports to meet its natural gas needs,” EIA.gov, February 11, 2022. https://www.eia.gov/todayinenergy/detail.php?id=51258.

[8] EU-US LNG Trade: US liquefied natural gas (LNG) has the potential to help match EU gas needs, PDF File, March 2022, https://energy.ec.europa.eu/system/fi les/2022-02/EU-US_LNG_2022_2.pdf.

About the Author:

John Clarke, with over 30 years in the heat processing area, is currently the technical director of Helios Corporation. John’s work includes system efficiency analysis, burner design as well as burner management systems. John was a former president of the Industrial Heating Equipment Association and vice president at Maxon Corporation.


Find heat treating products and services when you search on Heat Treat Buyers Guide.com


 

Natural Gas Revisited Read More »

The “Known – Unknown”: Preparing Your Facility for Unpredictable World Events

op-edThe “Known – Unknown,” the “Undiscovered Country,” the “Movement from cocksure ignorance to thoughtful uncertainty.” It doesn’t matter if you get your catch phrase from Donald Rumsfeld, Star-Trek, or that plaque your mother kept above the kitchen sink, the implication is the same: we really don’t know what the future holds. But, the Unknown of which I speak in this article is natural gas prices.

This column is a Combustion Corner feature written by John Clarke, technical director at Helios Electric Corporation, and appeared in Heat Treat Today’s March 2022 Aerospace print edition.

If you have suggestions for savings opportunities you’d like John to explore for future columns, please email Karen@heattreattoday.com.


John B. Clarke
Technical Director
Helios Electric Corporation
Source: Helios Electrical Corporation

Does “What happens in Eastern Europe stays in Eastern Europe” hold true? Unfortunately — no.

We have learned from recent and ongoing supply chain issues just how interconnected our economy and manufacturing sector is with the rest of the world. The standoff in Ukraine has the potential to impact the world energy markets for years to come, and I suspect this impact will be felt no matter what transpires. I am certainly no expert, but I have a sinking suspicion that our country offered some American methane molecules to Germany to stiffen their resolve to cancel the Nord Stream 2 pipeline. If the EU works to reduce their dependency on Russian natural gas, a significant portion of worldwide exports are removed from the supply side of the equation. From a practical standpoint, these shifts in supply will take some years to achieve, but we have seen a new realization on the part of business and governmental leaders about the importance of robust and reliable supplies of commodities, and manufactured goods and manufacturing capacity. So, less natural gas supply with rising demand equates to higher prices. And as we have discussed previously, liquefied natural gas transportation from the U.S. to the rest of the world is connecting our natural gas market with the world market — and our natural gas price will be affected by consumption and production factors worldwide, just as the price we pay for petroleum oil today is determined in New York, London, and Riyadh — following the consumption patterns in Beijing, Sydney, and Tokyo.

Ok — let’s get back to what we can do in our own facilities to insulate ourselves, to some degree, from unpredictable world events.

Recuperation, or preheating combustion air using the waste heat exiting the furnace or oven is a time proven method to reduce fuel gas consumption. Before we quantify the effect of preheating air, we need to briefly discuss what affects this heated air has on the combustion process. Higher combustion air temperatures are associated with the following:

  1. Peak flame temperatures are increased. As less energy is used to heat the incoming air, the energy in the natural gas can raise the products of combustion (CO2, H2O and N2) to a higher temperature than would be achieved without combustion air preheating. This can be either beneficial or problematic for a specific application. If the work being heated can accept increased radiation from these higher temperatures — heating rates are improved and throughput increased, but these higher temperatures may reduce the life of furnace components, or, in extreme cases, lead to a catastrophic failure.
  2. Flame speeds are increased, so the combustion process concludes in less space. Again, this is a double-edged sword, benefiting some and leading to a loss on temperature uniformity in others.
  3. Total products of combustion required for any quantity of heat input is reduced. Mass flow is especially important in systems where the operating temperature is below approximately 1200°F. If the energy saved leads to a loss in temperature uniformity, it may be a Pyrrhic victory.
  4. NOx formation is increased. Burner technology has come a long way in recent years to allow for systems to use these higher temperatures without greatly increasing NOx emissions, but the rule of thumb is that by increasing the combustion air temperature from 70°F to 800°F, we basically double NOx formation.

Each of these drawbacks, other than NOx formation, may be a plus rather than a minus for any application. Float glass furnaces (plate glass used in windows) and ingot reheat furnaces are examples of applications where recuperation was applied a century or so ago, at a time where fuel costs where not much of a factor. In both cases, the increased flame temperatures accelerated the heat transfer to either the glass or the steel, increasing production. These applications required furnace temperatures where combustion without preheating would have been impractical — as most of the energy would have been lost in the flues, and very little heat would be available to do any useful work.

What questions should I ask? How much can I save? What is my project’s estimated payback? All are critical questions. To start with, can your existing furnace accept these higher flame temperatures, and can you capture the heat and apply a cost-effective heat exchanger? An example would be a radiant tube furnace. Applying recuperation may require an upgrade in the alloy used in the burner and radiant tube. In direct fired applications, will my uniformity suffer? In general, this is a greater concern at temperatures below 1600°F. As the operating temperatures increase, we can generally expect better uniformity. (I can hear the furnace and burner experts reading this cry “foul,” and they are right, it is not wise to rely on my generalizations — always consult an expert about your specific application.)

How much will it cost? With recuperation, it is best to take advantage of an experienced person’s mistakes, rather than making them on your own. Consult a qualified contractor, OEM, or consultant to help with the application and costs.

How much can be saved? To answer that question, I provide the above graph. It is not the end all be all but will provide a rough estimate of potential savings. It is for an application with an exhaust temperature of 1600°F operating with 15% excess air.

As we can see, in this application, if we apply recuperation to preheat the air to 800°F, we will save 28% of the natural gas we would otherwise consume.

Before investing your money, an individual analysis of each application is required. This article’s purpose is simply to motivate the reader to invest the time necessary to properly determine, as I mentioned last month, if they have “uncashed checks” lying around their shop.

As always, please let me know if you have any questions.

About the Author:

John Clarke, with over 30 years in the heat processing area, is currently the technical director of Helios Corporation. John’s work includes system efficiency analysis, burner design as well as burner management systems. John was a former president of the Industrial Heating Equipment Association and vice president at Maxon Corporation.


Find heat treating products and services when you search on Heat Treat Buyers Guide.com


 

The “Known – Unknown”: Preparing Your Facility for Unpredictable World Events Read More »

Heat Treat Tomorrow – Hydrogen Combustion: Our Future or Hot Air?

OCDoug Glenn, publisher of Heat Treat Today, moderates a panel of 5 experts who address questions about the growing popularity of hydrogen combustion and what heat treaters need to do to prepare. Below is an excerpt of this lively and compelling discussion. 

To view the 1-minute trailer or register to watch this FREE video, go to www.heattreattoday.com/2021-09-H2-Vid

Today’s Technical Tuesday was originally published in Heat Treat Today's December 2021 Medical & Energy print edition.


Introduction

Doug Glenn (DG): Welcome to this special edition of Heat Treat Radio, a product of Heat Treat Today. We’re calling this special episode “Heat Treat Tomorrow: hydrogen combustion. Is it our future or is it just a bunch of hot air?” This discussion is sponsored by Nel Hydrogen, manufacturers of on-site hydrogen generation systems. I’m your host, Doug Glenn, the publisher of Heat Treat Today and the host of Heat Treat Radio. I have the great privilege of moderating this free-for-all discussion today with five industry experts who I’d like to introduce to you now.

Perry Stephens
Electric Power Research Institute (EPRI)

Dr.-Ing. Joachim G. Wünning
President
WS Wärmeprozesstechnik GmbH

First, Perry Stephens. He is the principle technical leader of the Electric Power Research Institute (EPRI) and currently leads the end-use technical subcommittee of the low carbon resource  initiative (LCRI) which is a collaborative eff ort with the Gas Technology Institute (GTI), and nearly 50 sponsor companies and organizations. They aimed at advancing the low carbon fuel pathways on an economy-wide basis for the achievement of decarbonization. EPRI is a member of the Industrial Heating Equipment Association (IHEA).

Joachim Wuenning (Joe Wuenning) is the owner and CEO of WS Thermprocess Technic Gmbh [WS Wärmeprozesstechnik GmbH] in Germany and WS Thermal Process Technology, Inc. in Elyria, Ohio. Joe’s company has been on the cutting edge when it comes to hydrogen combustion. In fact, the last time I heard you, Joe, was at the Thermprocess show in Düsseldorf, where you gave the keynote address regarding the advent and development of hydrogen combustion. Joe’s company has been a leader in hydrogen combustion. Joe’s company is an IHEA member as well. Joe is our European representative, and may provide us with a different perspective.

John Clarke is the technical director of Helios Electric Corporation (Fort Wayne, Indiana), a company that specializes in energy and combustion technologies. John is also a regular columnist for Heat Treat Today and a past president of IHEA.

Jeff Rafter is vice president of sales and marketing for Selas Technologies out of Streetsboro, Ohio and has a rich history in the combustion industry as well, including many years with Maxon Corporation. He’s got 28 years of industrial experience in sales, research and development, and marketing. He’s a combustion applications expert in process heating, metals refining, and power generation and has also served 10 years on the NFPA 86 committee and holds a patent for ultra-low NOx burner designs. He is also an IHEA member.

Finally, we have Brian Kelly with an equally rich history in combustion, spending most of his years at Hauck Manufacturing in Lebanon, PA, where he did a lot in sales and engineering before they were purchased by Honeywell. Brian currently works for Honeywell Thermal Solutions and is also an IHEA member.

Gentlemen, thank you for joining us. Let’s just jump right in. Brian, since I picked on you last, let’s go to you first on the questions.

Is Hydrogen Combustion the Future?

DG: Is this hydrogen combustion thing coming? And, if so, how soon and what’s driving it?

Brian Kelly (BK): It is coming and there is going to be a lot of back and forth in that it doesn’t make sense and all that. It is here. We’re seeing inquiries from customers that ask, “Hey, do we have burners that do this, control systems and stuff that do that?” The news that I get emails on, for example, is that with one of the steel companies in Europe, they already said their plan is totally going to be hydrogen. We’re delivering billets right now of hydrogen.

So, yes, it’s coming. Is it coming soon? It’s here today. Widespread? That’s going to be a longer road. I think you’re going to hear from people that know more about it than I do, but, certainly from industry buzz, we’re testing burners, we’re making sure our burners run on partial hydrogen, full hydrogen, safety valves, control valves, and all that is definitely within a lot of the testing that we’re doing right now beyond the usual R&D on lower emissions burners and things of that nature.

Jeff Rafter (JR): I have a slightly different answer, but I agree with Brian. I think hydrogen combustion has been here for over a century. The difference has been, it’s been largely restrained to a few industries that have a regular hydrogen supply. A great example would be refining and petrochemical industries. We have had, for literally decades, burners designed to burn pure hydrogen, for example, in applications like ethylene crackers.

The fundamentals of hydrogen combustion are very well known. The next evolution that we’re currently in the process of seeing is taking more industries into an availability of hydrogen as a fuel and modifying designs and process heating equipment to accept it. There are fundamentally a lot of changes that occur when you switch the fuel, and we can get into more of those later with more relevant questions, but it doesn’t come without challenges. There is quite a bit to be done, but I think the fundamental science is already well-known. There is a lot of design work to be done and there is a lot of economic and supply development yet to be had.

John Clarke (JC): Yes, I certainly think it is coming, but the timing is uncertain. And, when I say “coming,” I mean deployed in a certain or large volume. When we simply talk about hydrogen, I do think the order of deployment is somewhat predictable and when it comes to pure hydrogen, I think it will likely be deployed first for transportation, and only after that need is met, as a process heating fuel, widely. Now, if there is a breakthrough in battery technology, this order of deployment may change. But, right now, it looks like hydrogen represents an opportunity for higher energy density for long haul transportation. And, if we’re pushing hard to reduce CO2 or carbon emitted, I think policy will be implemented in a means to maximize a reduction of carbon. That’s where I think they’ll be pushing harder.

Now, that said, partial hydrogen, blending hydrogen into natural gas, is likely to occur perhaps sooner than that.

Joachim Wuenning (JW): Not really. I think a lot of things were said correctly and I strongly believe it has to come. If you believe in climate change, it must happen because we cannot use fossil fuels forever. I also don’t believe that we will have an all-electric world. I don’t believe in nuclear power, so we cannot get all our energy from that, therefore, chemical energy carriers will be necessary for storage and long-haul transportation. Is it coming soon? Of course, it is hard to predict how fast it will be. Now, fossil fuel is cheap so it will be hard to compete with as hydrogen is likely to be more expensive.

But certainly, what we see is the requirement from our customers to have hydrogen ready burners. Because, if they invest in equipment at that point, why would they buy a natural gas only burner. They should, of course, look for burners which are able to do the transition without buying all new equipment again. So, we have a lot of projects momentarily to demonstrate the ability of the equipment to run with hydrogen or natural gas and, preferably, not even readjusting the burners if you switch from one to another gas.

Perry Stephens (PS): I’ll try to add something a little different. At EPRI, we’re charged with providing the analysis and data from which other folks, like these gentlemen, are going to try to base important business decisions. Our work hasn’t focused specifically on hydrogen, but, more generally, the class of alternate energy carriers — molecules, gas, or liquid — that can be produced in low carbon first energy ways through renewable energy sources. A lot of our work is focused on understanding the pathways from the initial energy which as a biomass source, solar, wind, could be nuclear, could be hydro. These sources of electric power that ultimately have to be used to produce this low carbon hydrogen. One other pathway is hydrogen or hydrogen-based fuels produce the steam methane reformation process which uses a lot of hydrocarbons but would then require carbon capture and sequestration. The CO2 from these processes could be employed in a circular economy fashion. So, we look at all of these.

The real challenge is the challenge of cost. How do you produce this hydrogen or alternate fuel? And there are many other potential fuel molecular constructs that could be deployed. Ammonia is one being discussed in some sectors. And then how do you transport them, store them, and what is their fuel efficiency and the cost of either new equipment or conversion of existing equipment to deploy those. We’re not specifically focused on hydrogen. It is a very important energy carrier. It can be blended with fossil fuels in the near-term and then maybe expanded in the long term to higher percentages up to pure hydrogen depending on the application, depending on where you produce it. These costs must be evaluated and that is a big job that we’re doing at EPRI with our LCRI initiative right now. We are trying to understand that techno economic analysis, that is, what makes the most sense for each sector of the economy.

Why Not Electricity?

DG: Thanks, guys. Joe had mentioned global warming, a driving force here. Why not electricity? Why don’t we just convert everything over to electricity? Perry, you’re with EPRI, let’s start with you on that. Instead of going just straight-out hydrogen, why not just go to electricity?

PS: I think the question again rephrased might be, “when electricity and when hydrogen” because I think that’s really what we’re trying to decide. There are interesting areas of research involving catalysis techniques that dramatically improve the net energy efficiency of chemical processes, for example, that might make direct electrification of certain processes more competitive. There are electric technologies for the low- to midrange temperatures that are attractive and use pieces of the electromagnet spectrum to produce transformation of products, heating and/or other transformations, that are very cost effective today. So, we judge that a portion, maybe something approaching 30% of the remaining fossil fuel, could be electrified. A certain chunk, a quarter, maybe reduced consumption through energy efficiency, 30% or more through electrification. It’s that difficult-to-electrify piece. Steam-based processes and other direct combustion processes where electric technologies — for one reason or another, don’t look like they offer a strong solution, at least today — that we’re really concerned with. And, both in steam production and direct combustion of fossil fuels today, many cases we’re looking at having to have some sort of alternate combustible fuel.

JC: I’m not sure I completely agree with your question. In some ways, clean hydrogen, or environmentally or low carbon hydrogen, is electricity. It is simply a different means of storing electric power because the source of that is going to be some sort of renewable power, more likely than not, photovoltaics, wind, hydroelectric; those are going to be the electricity we use to break down the water to generate the hydrogen that we then go ahead and store. So, the alternative is whether we use batteries or hydrogen to store this electricity and make it available either in a mobile setting, in a car or a truck, or off-peak times, at times when we are not able to generate electricity from renewables.

I think the question really is more along the line of end use. When are we going to be using electricity for the final end use? We’re kind of process heating guys around this table. I think it’s going to come down to economics, for the most part. And I don’t think we’re quite there yet.

JW: Electricity is fine for some applications. I’ve driven an electric car for the last 10 years, but in long range, I drive the fuel cell hydrogen car from my father, so different technologies for different purposes. There might be batch processes where I can have a break of a week if there is no sunshine and do the batch processing when electricity is available. But if I have a continuous furnace with 100 megawatts which should run 365 days a year, it will be tough to produce the electricity constantly from a renewable basis to fulfill all these requirements. I think it’s just more economic and makes more sense to use the right technology for the right processes. It’s not an either/or. Use the right technology for the right application.

BK: I would just back what Joe says. It can be selective to industry, the furnace type, or the type of material being processed. I know I’ve dealt in my career with a lot of the higher temperature type applications — ceramics and heat treating and things of that nature. If you start getting above 2000 degrees Fahrenheit and up, and especially dealing with airspace, uniformity has a lot to do with it.

Electricity can be hard to get that uniformity without moving fans and having fans that operate at higher temperatures is another challenge. It’s extremely challenging and a big cost factor. What most people have said here is that it is probably not either/or. We see a lot of electricity being used but we’re fossil fuel burner guys, so we’re going to push that efficiency and that kind of cost.

You’re not going to want to miss the rest of this thought-provoking discussion. To watch, listen, or read in its entirety, go to heattreattoday.com/2021-09-H2-Reg.

Heat Treat Tomorrow – Hydrogen Combustion: Our Future or Hot Air? Read More »

Stop the Burn: 3 Tips to Cut Natural Gas Costs

op-edFor the next series of articles on heat treaters and combustion, the focus will be on the cost of natural gas and how we can reduce its consumption. Given significant movements in natural gas prices, it is essential we shift our focus to this important pocketbook issue.

This Technical Tuesday column appeared in Heat Treat Today’s November 2021 Vacuum Furnace print editionJohn Clarke is the technical director at  Helios Electric Corporation and is writing about combustion related topics throughout 2021 for Heat Treat Today.


John B. Clarke
Technical Director
Helios Electrical Corporation
Source: Helios Electrical Corporation

What Is the Cost To Operate My Burner System?

We will begin this and future articles by looking at natural gas prices and price forecast(s) that are published by the Department of Energy’s Energy Information Agency (EIA). Unlike the price for gasoline, we don’t drive past large, illuminated billboards displaying the current price of natural gas on our way to work, even though it is a significant operating cost for all heat treaters. Even if you operate primarily electrically heated equipment, natural gas is likely used to generate your electrical power. Obviously, neither Heat Treat Today or this author make any claims as to the accuracy of these projections. In other words, please don’t shoot the messenger. The American taxpayer funds this agency and it is only reasonable that we see what they have to say.

Let’s start with a quick definition. Henry Hub is a gas pipeline located in Erath, Louisiana that serves as the official delivery location for futures contracts on the New York Mercantile Exchange. This hub connects to four intrastate and nine interstate pipelines. It is unlikely any industrial consumer pays the Henry Hub price alone for the natural gas they consume. There are a great many other factors that determine the price that appears on your monthly bill; but the Henry Hub price is indicative of pricing trends and represents a consistent way to discuss the cost.

A good website to bookmark in your browser is www.eia.gov/naturalgas/weekly/. It is a quick read and will be the primary reference for my monthly sidebar. Let’s first look at the spot price trend. The spot price is the current price at which a natural gas can be bought or sold for immediate delivery at the Henry Hub. There is volatility in the price of natural gas because of supply, demand, and trading activities (speculation), but when we expand the time horizon, it provides a representative look at the pricing trend. This trend will be reflected in the price we will pay in the future. The prices quoted are in terms of U.S. Dollars per 1,000,000 BTU — roughly 1,000 SCF of natural gas.

The EIA also provides forward-looking projections — but we will leave it to the reader to explore this information on the EIA website. The intent of this series of articles is not to provide the basis of trading futures, but rather to provide some ideas on how to save money.

We can see a definite upward trend. When we combine this data with our understanding that natural gas is increasingly being used to displace coal to generate electricity and North America’s increasing capacity to export liquified natural gas (LNG), there is reason to believe this is a durable trend. We can expect to pay more next year than the recent past to heat our equipment. And in time, this higher fuel cost will lead to higher electrical rates.

How Can I Save Natural Gas?

To save natural gas, we can optimize our processes, reduce unnecessary air, and contain heat within the furnace and/or capture the energy that leaves our system to preheat work or combustion air. Ideally, we should take advantage of all these opportunities — provided the effort pays for itself. In general, operators of heat processing equipment are aware of these opportunities but are not always confident when determining the payback for their investments in time and capital. We will endeavor to bring clarity to these decisions by not only discussing opportunities, but also discussing how to quantify the value of the opportunities. The following are the questions that will be answered in future articles:

Optimizing the Process:

  1. How do I know when the material I am heating is at the desired temperature?
  2. Do I have excessive factors of safety built into my process to compensate for not knowing the temperature at the core of the part being heated?
  3. How much fuel can I save with a shorter cycle?

Reducing Air or Containing Heat:

  1. Is my furnace or oven at the correct internal pressure?
  2. Is it time to rebuild door jams?
  3. How much fuel is wasted because I am not containing heat within the furnace or letting excessive air reduce my combustion efficiency?

Reducing the Heat Exiting the System:

  1. Can I justify installing recuperators to preheat combustion air?
  2. Can the heat from my system be used to preheat work? If so, will I shorten my cycle time and save fuel?

No one likes rising energy prices, but if the trend is up, it is better to recognize reality and invest accordingly. It is our wish that future columns will provide ideas and tools to help you get the most from the energy you consume. If you have specific requests or questions that might guide our discussions, please let us know.

About the Author:

John Clarke, with over 30 years in the heat processing area, is currently the technical director of Helios Corporation. John’s work includes system efficiency analysis, burner design as well as burner management systems. John was a former president of the Industrial Heating Equipment Association and vice president at Maxon Corporation.

Stop the Burn: 3 Tips to Cut Natural Gas Costs Read More »