Don’t Vacuum-Braze Metals Containing Zinc

Source: Kay & Associates Brazing Consultants 

Are you sure you should vacuum braze that? As the title of this best of the web article suggests, vacuum brazing materials containing zinc is not a good idea. Volatized zinc can contaminate, and maybe even ruin, your vacuum furnace. But what about cadmium, lead, chromium, and magnesium? Is vacuum brazing safe for those materials?

In this article by Dan Kay, examine the vapor pressure curves of common metallic elements to be sure you know exactly when you need to worry about vaporization. And remember, operating your furnace at partial pressure does not offset the effects of vaporization.

An excerpt: 

Many people braze stainless steels (which contains chromium) at vacuum levels approaching 10-5 Torr [. . . ] You can readily see that at 10-5 Torr the temperature at which Cr volatilizes has dropped down to only about 1800F (950°C). Since nickel-brazing of stainless typically takes place at about 2000-2100°F (1095-1150°C), please understand that you will indeed be volatilizing chromium during this brazing operation, which will condense on the furnace walls, giving them a greenish/bluish coloration.

Read more: Don't Vacuum-Braze Metals Containing Zinc