Pelican Wire

Heat Treat Radio Series for Spring

OC

The days are getting a little longer, you've saved up some vacation hours, it's time for a break this spring!

Make use of some down time to listen in on a couple of Heat Treat Radio series. Putting in some driving miles, relaxing in the sand, or enjoying a staycation all mean some time to peacefully enjoy some heat treat topics. We've put together an original content piece that lets you listen in on a 3-part series on thermocouples, and a back-to-basics series on heat treat hardening. It's nice to know that there is plenty to listen to; you can just click to play each episode!


Thermocouples 101 with Ed Valykeo and John Niggle

This series gives the opportunity to learn from an expert all about thermocouples. The first episode digs into thermocouple history, types, vocabulary, and other basics. Hear from Ed Valykeo, as he gives some of his own history and then dives into all things thermocouple.

1. Heat Treat Radio #61

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The second episode covers thermocouple accuracy and classification. Ed Valykeo continues to review and explain necessary information on how thermocouples are calibrated and used.

2. Heat Treat Radio #62

The final episode in this series gets into discussion with John Niggle about thermocouple insulation types. His review towards the beginning of the episode is helpful, and his discussion of insulation reminds readers that job specifications and requirements are crucial.

3. Heat Treat Radio #64

Metal Hardening 101 

Mark Hemsath sits down with Heat Treat Radio to provide an overview of metal hardening basics. In the first part of the series he provides explanation of what it is, what materials can be hardened, why it has to be done, and more.

1. Heat Treat Radio #49

For the second episode, Mark Hemsath explains five hardening processes: carburizing, nitriding, carbonitriding, ferritic nitrocarburizing, and low pressure carburizing.

2. Heat Treat Radio #54

In this final episode for the metal hardening series, a discussion is presented on newer advances in metal hardening. A call is even put out for new ideas and engineers willing to experiment with some of these advance.

3. Heat Treat Radio #56

As you can see above, this resource provides two series -- each with three parts -- that give a comprehensive look at two fundamental components in the heat treat industry. Both the discussion of thermocouples and the investigation of metal hardening provide educational listening with something for everyone in the form of review as well as maybe some basics that have been neglected or forgotten.


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19 Quick Heat Treat News Chatter Items To Keep You Current

Heat Treat Today offers News Chatter, a feature highlighting representative moves, transactions, and kudos from around the industry. Enjoy these 19 news bites that will help you stay up to date on all things heat treat.

Equipment Chatter

  1. Global commodities group, Anglo American, and thyssenkrupp Steel have signed a memorandum of understanding to collaborate on developing new pathways for the decarbonization of steelmaking. The collaboration will focus on joint research to accelerate the development of high-quality input stock for lower carbon steel production, using both conventional blast furnace and direct reduction iron.
  2. SECO/WARWICK delivered additional CAB lines to SUZHOU RETEK in China.
  3. Tenova was contracted by Sinova Global to supply the basic engineering of a new silicon metal plant in Tennessee. The site will be North America’s most modern and efficient silicon metal plant, a greenfield development for Sinova Global.


Company and Personnel Chatter

  1. Brighton Science and Hubbard-Hall partner to provide the Infinity Surface Cleaning Intelligence Program, which is designed to aid manufacturers to prepare surfaces and prevent problems.
  2. Thermal-Vac Technology, Inc. announced the completion of a new microgrid from Verdant Microgrid, LLC. Collaboration with the following companies ensured the completion: Eos Energy Enterprises of Edison, NJ; Stronghold Engineering, Inc. of Perris, CA; and GridSwitch Asset Management Services of Moon, PA.
  3. Bryan Stern has joined Gasbarre as the product development manager for Gasbarre Thermal Processing Systems. Bryan’s experience, knowledge, and forward-thinking will allow him to support existing clients and advance the company’s growing footprint in the vacuum furnace market.
  4. Ipsen recently launched a new website with the goal of providing a better user experience for customers worldwide. IpsenGlobal.com now incorporates all Ipsen locations, products, and services under one domain.
  5. Furnaces North America 2022, the premier trade show and technical conference in the North American heat treating industry, attracted over 1,200 attendees from around the world. The show produced by the Metal Treating Institute in partnership with its media partner, Heat Treat Today.


Kudos Chatter

  1. Doug Peters, CEO of Peters’ Heat Treating, received the Winslow Award, an honor that is given to an individual or business that has made valuable economic improvements.
  2. A two chamber vacuum oil quench furnace has received Nadcap accreditation. Solar Manufacturing designed the furnace for Solar Atmospheres of Western PA.
  3. Ayla Busch was honored with the German Leadership Award 2022. This award was presented at the annual alumni convention of the Collège des Ingénieurs and is an award for innovative corporate leadership in the German economy.
  4. Texas Heat Treating, Inc. announces that both Round Rock and Texas Heat Treating Worth just completed ISO 17025 lab audits. The audits came back with no findings.
  5. Representatives from TAV VACUUM gave a speech during the first day of the 27th IFHTSE Congress & European Conference on Heat Treatment 2022. The talk was about the heat treatment of titanium alloys, specifically, “Vacuum heat treatment of Ti6Al4V alloy produced via SLM additive manufacturing.”
  6. RETECH, a SECO/WARWICK Group company, was acknowledged as “The Most Innovative Metallurgical Equipment Specialist in 2022 for the USA” by Acquisition International Magazine. Additionally, Earl Good, its managing director, has been honored by The Corporate Magazine in the “Top 20 Most Dynamic Business Leaders of 2022.″
  7. Nitrex Metal, Inc. announced that it was selected for the “American Dream” series airing on Bloomberg and Amazon Prime. The series explores the entrepreneurial stories of men and women who founded and built incredible companies from the ground up.
  8. Jim Oakes, president of Super Systems, has been awarded the first ever Furnaces North America (FNA) Industry Award at the trade show’s opening night kickoff reception.
  9. At the recent 2022 MTI fall meeting held in Indianapolis, IN, the Metal Treating Institute recognized Roy Adkins, director of Corporate Quality, with the MTI Award of Industry Merit. This award is given in recognition of current and ongoing commitment to the betterment of the commercial heat treating industry with one or more significant accomplishments.
  10. Hubbard-Hall has been awarded the Top Workplaces 2022 honor by Hearst Media Services in Connecticut. The award is based solely on employee feedback gathered through a third-party survey that is administered by employee engagement technology partner Energage LLC.
  11. Pelican Wire Calibration Laboratory received “ISO/IEC 17025:2017” accreditation from ANSI National Accreditation Board.

 


Heat Treat Today is pleased to join in the announcements of growth and achievement throughout the industry by highlighting them here on our News Chatter page. Please send any information you feel may be of interest to manufacturers with in-house heat treat departments especially in the aerospace, automotive, medical, and energy sectors to sarah@heattreattoday.com.


 

Find heat treating products and services when you search on Heat Treat Buyers Guide.com


 

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Don’t Be Unique! 10 Temperature Uniformity Tips

OCWe’ve assembled some of the top 101 Heat Treat Tips that heat treating professionals submitted over the last three years into todays original content. If you want more, search for “101 heat treat tips” on the website! Today’s tips are all things temperature: thermocouples, how to keep temperatures in check, TUS, and more.

By the way, Heat Treat Today introduced Heat Treat Resources this year; this is a feature you can use when you’re at the plant or on the road. Check out the digital edition of the September Tradeshow magazine to check it out yourself!


Temperature Monitoring When the Pressure is On!

Increasing in popularity in the carburizing market is the use of batch or semi-continuous batch low pressure carburizing furnaces. Following the diffusion, the product is transferred to a high-pressure gas quench chamber where the product is rapidly gas cooled using typically N2 or Helium at up to 20 bar pressure.

In such processes, the technical challenge for thru-process temperature monitoring is twofold. The thermal barrier must be capable of protecting against not only heat during the carburizing, but also very rapid pressure and temperature changes inflicted by the gas quench. From a data collection perspective, to efficiently perform temperature uniformity surveys at different temperature levels in the furnace it is important that temperature readings can be reviewed live from the process but without need for trailing thermocouples.

During the gas quench, the barrier needs to be protected from Nitrogen N2(g) or Helium He(g) gas pressures up to 20 bar. Such pressures on the flat top of the barrier would create excessive stress to the metal work and internal insulation / logger. To protect the barrier therefore a separate gas quench deflector is used. The tapered top plate deflects the gas away from the barrier. The unique Phoenix design means the plate is supported on either four or six support legs. As it is not in contact with the barrier no force is applied directly to the barrier and the force is shared between the support legs. The quench shield in addition to protecting against pressure, also acts as an additional reflective IR shield reducing the rate if IR absorption by the barrier in the vacuum heating chamber.

(PhoenixTM)


3 Tips to Meet Temperature Uniformity Surveys

  1. Adjust the burners with some excess air to improve convection.
  2. Make sure that the low fire adjustment is as small as possible. Since low fire will provide very little energy, it will make the furnace pulse more frequently and this will improve heat transfer by convection and radiation.
  3. Increase internal pressure. This will “push” heat to dead zones allowing you to increase your coldest thermocouples (typically near the floor and in the corners of the furnace).

(Nutec Bickley)


Ways to Increase Temperature Uniformity in Heat Treat Furnaces

  1. A (sometimes) simple way to increase uniformity in a furnace is to add a circulation fan. Circulation fans can be a quick way to add an additional 5°F tighter uniformity on a batch furnace application.
  2. Be sure that the furnace is tuned optimally to reduce/eliminate any overshoot and oscillation around setpoint.
  3. Eliminate any thermal lag by making sure that the control thermocouple and TUS thermocouples have similar sensitivity. If not, the control thermocouples can fall behind and cause the TUS thermocouples to overshoot and fail.

(L & L Special Furnace Co., Inc.)


Pack Your Thermocouples

When a thermocouple is used with an open-ended protection tube, pack rope or fiber between the thermocouple and the protection tube to prevent cold air infiltration from influencing the reading.

(Super Systems, Inc.)


A Good Fit

If a thermocouple fits loosely in a protection tube, avoid errors by ensuring that the tip maintains good contact with the tube.

(Super Systems, Inc.)


Introducing Your Common Thermocouple Types

What are the common thermocouple types?

Thermocouple material is available in types K, J, E, N, T, R, S, and B. These thermocouple types can be separated into two categories: Base and Noble Metals.

Types K, J, E, N, and T are Base Metals. They are made from common materials such as Nickel, Copper, Iron, Chromium, and Aluminum. Each base metal thermocouple has preferred usage conditions.

Types S, R, and B thermocouples are Noble Metals because they are made of one or more of the noble metals, such as Ruthenium, Rhodium, Palladium, Silver, Osmium, Iridium, Platinum, and Gold. Noble metals resist oxidation and corrosion in moist air. Noble metals are not easily attacked by acids. Some Noble metal thermocouples can be used as high as 3100°F.

(Pelican Wire)


Culprits of a Stable Thermocouple

Factors affecting the stability of a thermocouple:

The EMF output of any thermocouple will change slightly with time in service and at elevated temperatures. The rate and change are influenced by metallurgical and environmental factors. The four factors that can induce EMF drift are: Evaporation, Diffusion, Oxidation, and Contamination.

(Pelican Wire)


Does Length Matter?

Does the length of a thermocouple wire matter?

In a word, “Yes.” There are several factors when considering the maximum length of a thermocouple assembly. Total loop resistance and electrical noise. Total loop resistance should be kept under 100 ohms for any given thermocouple assembly. Remember, the total loop resistance would include any extension wire used to complete the circuit. Motors and power wires can create noise that could affect the EMF output.

(Pelican Wire)


Type N Thermocouple (Nicrosil/Nisil)

Type N Thermocouple (Nicrosil/Nisil): The Type N shares the same accuracy and temperature limits as the Type K. Type N is slightly more expensive and has better repeatability between 572°F to 932°F (300°C to 500°C) compared to type K.

(Pelican Wire)


Know Your Thermocouple Wire Insulations

Know your thermocouple wire insulations. When is Teflon® not Teflon®? Teflon® is a brand name for PTFE or Polytetrafluoroethylene owned by Chemours, a spin-off from Dupont. FEP is Fluorinated Ethylene Propylene. PFA is Perfluoroalkoxy Polymer. All three are part of the Fluoropolymer family but have different properties. Of the three compounds, PTFE has the highest heat resistance, PFA second highest and FEP third. The higher the heat resistance the more expensive the insulation. Keep that in mind when specifying the insulation and only pay for what you need.

(Pelican Wire)


Check out these magazines to see where these tips were first featured:

 

 

 

 

 

 

 

 

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Heat Treat Radio #64: Thermocouple 101 with John Niggle, Pelican Wire (Part 3 of 3)

Heat Treat Today publisher Doug Glenn wraps up this three-part series with Pelican Wire experts by talking with John Niggle from Pelican Wire about thermocouple insulation types and considerations.

The first two episodes cover the history, types, vocabulary, standards, and other basics of understanding how thermocouples work. Listen to the previous episodes of the series here.

Below, you can either listen to the podcast by clicking on the audio play button, or you can read an edited transcript.



The following transcript has been edited for your reading enjoyment.

Doug Glenn (DG):  Welcome to Heat Treat Radio!

John Niggle (JN):  Yes, it's good to see you again, Doug.  I know we've run into each other a couple of times out there in the field.  I'm looking forward to having the opportunity to do all of this stuff in person again.

DG:  It will be nice.  Before we hit the record button, we were talking about shows this fall and hoping that they happen because you, like I, are ready to get out and go.

You are the business development manager for Pelican Wire.  If you don't mind, give us just a little bit of background about you and about your experience in the whole thermocouple world.

Pelican Wire headquarters

JN:  Sure, absolutely.  As you said, I am the business development manager at Pelican Wire.  I've been at Pelican since 2013 so we're working out my eighth year here.  I'm a career industrial sales representative.  I do have previous experience also, actually, in the process instrumentation industry.  Way back when, before I even knew how to spell thermocouples, I was selling that stuff when I first got out of college.  My career has, sort of, gone full circle, let's say.

DG:  Very nice.  Well, you've got plenty of years of experience, which is great.  We've had two previous episodes with your colleague, Ed Valykeo, and we covered a good bit of stuff.  We covered a lot of basics in the first episode.  We covered standardization, and things of that sort, in the second episode.  I want to encourage any listeners who haven't listened to those episodes, feel free to go back, Google “Heat Treat Radio and search for “Pelican Wire” and listen to episodes 1 and 2.

John, you and I want to move forward.  I'm always kind of curious about this question:  From your perspective, with your experience, why do we use thermocouples?  Let's talk about what they are and why we use them.

JN:  First of all, we have to assume that somebody is trying to measure the temperature of some sort of a process- a process or an event of some kind.  That's basically what they're trying to do.  Compared to other devices like RTDs, bimetal thermometers, liquid expansion state change devices and so forth, thermocouples are robust, they're inexpensive; they're repeatability, they're ease of use and size  -- all of those factors lead them to be more widely used than another sort of thermal measurement device of any kind.  It is the preferred method.

On top of that, I mentioned the expense part.  Because they're relatively inexpensive, there are certain industries, the heat treat industry and smelting industry, for example, consider these as, actually, consumable or disposable.  So, the cost factors in significantly in the industry that we're talking about here.

DG:  I live in western Pennsylvania and the town where my wife grew up, there was an old Leeds and Northrup manufacturing plant.  I believe they made the consumable thermocouples for melt shops.  You would, basically, throw the thermocouple in and it would melt quickly but it would give you a response during that time.

CLICK to Listen!

JN:  Right.  And, as I mentioned earlier, the response factor is important, or that's one of the factors considered, when people are looking at thermocouple wire.  And, you're correct, Ed Valykeo, as you mentioned, has 40 years of experience in the industry and has seen exactly the same sort of thing that you're talking about where people will just tack weld it onto something that gets thrown into a furnace or it gets thrown into a melting pot or something like that, and they're looking for that instantaneous temperature.

If you don't mind, I'll tell you that we've done some work, actually, in the aerospace industry and we had a customer that we sold significant, literally miles, of thermocouple wire to (when I say aerospace, it was specifically for space exploration) and this was because of whatever we had done with the insulation.  I can't tell you, because it was before my time, but this is what was relayed to me- they were able to get another 3 - 4 seconds of temperature measurement out of that wire.  That critical, extra data for them made all the difference in the world.

DG:  We're going to get to the insulation part which should be interesting.  You won't have to tell us any trade secrets, but we are headed in that direction anyhow.

So, different types of thermocouples.  Again, just a review question for us.  Why use them?  Why the different types and why are we using different types?

JN:  Forgive me, Doug, and the rest of the audience, for that matter, if I end of repeating some of the things that came out in the previous episode.  Basically, when you're talking about thermocouples, there are the two chemistries; for lack of a better term, you have “base” and “noble” metals.  The base metals are really the metals that we focus on at Pelican.  The noble metals are the more expensive ones- rare earth metals, tungsten, titanium, platinum and all those sorts of things that people spend exorbitant amounts of money on.  There are purposes for those, but, typically, what you're going to see in the heat treat industry, in particular, you're going to see a lot of the base metals.

I like to say that, truly, the 20 gauge K, in particular, is the 800 pound gorilla in the room.  It's almost considered, and I think it would be by people in the industry, a commodity.  There are untold miles of that wire that are used in the heat treating and smelting industry.  K is used, really, because of the temperature range.  It fits in well with what people do in the heat treating industry.  It is good for temperatures from zero up to around 1260 C.  It's inexpensive, it covers the ranges that those people are looking for, and, again, it's the 800 pound gorilla in the room when it comes to temperature measurement in the heat treating industry.

Click to read the Heat Treat Today Original Content article on thermocouples.

The other types such as J comes up periodically, particularly if you're looking at lower temperature ranges.  You won't see it quite as often in the heat treating industry.  You will see it somewhat, but not to the degree that you would K.  The J thermocouple wire has an iron leg so it does oxidize and you need to be careful about that sort of thing.  Type T thermocouple wire has a narrower range.  It has very good response times in cryogenic and cold temperature applications.  The higher, upper end of type T thermocouple wire, typically, wouldn't be of terrible interest to the audience that we're involved with here, for the most part, because the upper ends around 370 to 400 C degrees, in lab environments; that's where it's going to be the most popular.

There is also type E.  It's a higher temperature, as well.  Response time.  Broader range is a little bit better than K at lower temperature ranges.  An interesting one is type N that you will see fairly often in the heat treating industry.  For those people not familiar with type N, it is different alloys than type K.  It covers virtually the same temperature range that type K does and will, actually, have less drift than type K.  It is more expensive because of the alloys that it is made of, but, again, if you're interested in less drift, then type N is worth looking at.  It hasn't quite caught on in the US the way it has in, say, Europe, in particular, and that really has to do with the infrastructure of the instrumentation.  People have instrumentation that is either calibrated for K or J or something like that.  Now, there is instrumentation out there, now, that would use K and N both, so we may see more, particularly, in the aerospace industry I would think it would become more and more popular.

DG:  That's helpful.  It's always good to hear those things over again.

How about the parameters and/or the factors that need to be considered when you're constructing the wire to start with?  What do we need to be worried about in that area?

JN:  I don't know if I like the word “worried” exactly, Doug.  It's more, what do we need to think about?  What do we need to be concerned about?  Besides the metallurgy that we just talked about, we need to think in terms of what the sensor is actually going to look like.  Is it just the wire?  Thermocouple wire, by itself, can be a thermocouple; that's it, without any protection or anything like that.

As I mentioned earlier, you can tack weld it to an ingot, or something like that, and there you go.  You don't have any probe, there is no thermal well to protect it or anything like that.  But, what we do need to think about, then, is the process that it's going to be involved in.  Where is it going to be used?  Is it going to see an environment where there is a flow.  Is it going to see an environment where somehow the thermocouple wire can become damaged?  In that case, then, we're headed in the direction of talking about what our customers are interested in.  And for a customer for Pelican Wire, we're mainly talking about people who actually assemble thermocouples – they make the connections, they have the molds and all that sort of thing.

To be clear, Pelican Wire just makes wire.  And, again, the thermocouple wire can be used as a thermocouple, but a tremendous amount of wire is actually connected to some sort of a sensor or a probe, as I said, and is protected in a thermal well or something along those lines.

"But, what we do need to think about, then, is the process that it's going to be involved in.  Where is it going to be used?  Is it going to see an environment where there is a flow.  Is it going to see an environment where somehow the thermocouple wire can become damaged?  In that case, then, we're headed in the direction of talking about what our customers are interested in."

John Niggle

DG:  Do we also have to be concerned with oxidizing, carburizing atmospheres, corrosive atmospheres?  Is that, also, something that we need to be aware of?

JN:  Absolutely.  And that is one of the reasons you will see a probe thermocouple is because the wire is protected from that atmosphere.  Nearly all of the wires that we talked about would be affected, particularly, in say, like a sulfurous environment; it would be subject to corrosion, oxidation and something along those lines.

Other factors, of course, are the accuracy and how much space we have.  Believe it or not, if it's going to go into a small orifice, then we need to think about what the age size is going to look like.  And then the environment:  Is it going to be abrasive?  Is there movement?  Is there some sort of braiding motion that could wear a hole in the wire in the insulation and so forth?  There are a lot of things to think about.

DG:  And, it would probably be a good idea, especially if our heat treat people are running anything outside of the norm, regardless of what it is, whether it be atmosphere, configuration, fixturing, if there is anything outside the norm, they would probably be wise to mention it to the thermocouple wire and/or thermocouple probe manufacturer and make sure that they know so that you guys can get help get the right thing on there in their furnace.

JN:  Yes, absolutely.  At the end of the day, we work with this every day.  We have design engineers on staff who can assist with technical questions and so forth and, of course, our customers, and the actual thermal wire assembly people, this is what they do every day of the week.

“I'll tell you that we've done some work, actually, in the aerospace industry and we had a customer that we sold significant, literally miles, of thermocouple wire to (when I say aerospace, it was specifically for space exploration) and this was because of whatever we had done with the insulation.”

DG:  Let's talk about something a little bit new, I guess, to our conversation here in this 3-part series, and that is the insulation that's going to go around these wires.  Can you tell us what are the different types of insulations and what are the advantages and/or disadvantages of each, and why would we be using them?

JN:  I'll break it down into, what I would call, the four basic categories.  That would be an extruded insulation, insulations that are tapes, fiberglass insulations that are routinely worked with and then, of course, high temp textiles.  High temp textiles, in particular, would be of interest to the audience here in the heat treat metallurgy world.

Extruded insulations can be a variety of thermoplastics.  A term that, I think, Ed has probably mentioned before and we've talked about before is extension grade wire.  That typically has a PVC insulation on it and the reason PVC works for that is that it's cheap and extension grade wire, typically, does not see the sorts of high temp environments that you're going to see in processes.  It's really a signal wire that takes the signal from the probe or from the sensor to the process control device.

DG:  So what kind of temperature tolerances can the extruded wire handle?  Are we talking 300, 400 degrees?  I guess you talk C, I talk F.

Teflon frying pan

JN:  We talk whatever language our customer likes to talk, but we do talk C quite a bit.  So, PVC is quite low, it's in the 200s F.  But, when you're looking at fluoropolymer insulations (and Pelican is really a high temp house, so we focus on the higher temp insulations) you have FEP and PFA, those are in the 200s.  PFA actually goes up to 260.  So, you can see, it's probably not suitable for heat treating applications, smelting and that sort of thing.  The advantages to those compounds would be that you're going to have abrasion resistance.  Think about your Teflon frying pan: it's slick, it's smooth.  So, if you're in an environment where there is some movement, it will be good for that.  And, of course, it will have excellent moisture resistance and chemical resistance.  Those would be the advantages to the extruded wire.  The other advantage would be, because you'll have a thinner wall than you will with the other insulations, you'll have some more flexibility.  So, if you have a type N radius, you can go around a corner easily.

The next step up, in terms of temperature resistance, would be the tapes.  Basically, in that area, you're looking at PTFE tape, mica take and capped-on tape or polyamide tape.  Those will give you slightly higher heat resistances.  The mica, in particular, would give you more.  (Mica, as a matter of fact, is used as a supplement to the PTFE to give it even higher heat resistance.)  Mica will go up to 500 C, PTFE and the polyamides match, in terms of heat resistance, the extruder products around 260.  What they do give you, again if you use the tapes, is the heat resistance you're looking for, some abrasion resistance and the moisture resistance.  You'll have less flexibility because those products are stiffer, but they're also going to be a little bit lighter weight unless you incorporate the mica into it.  Then, when you do that, you're going to end up with an even stiffer wire and it will be a little bit heavier, and all those will be larger in diameter than an extruded wire.  If you look at an environment where you need to poke the wire through a hole and that hole is an eighth of an inch, you need to think really hard if what you're doing is going to work.

DG:  So you've got extruded and you've got tapes.

JN:  The next step after that would be fiberglass.  In the case of fiberglass, you have E glass and S glass.  Of the two, E glass would  have the lower temperature resistance and you're looking at 482 C on the high end.  For S glass, you're up to 704 C.  Now you're starting to talk about insulations that you will see in the heat treat environment; it's quite common, especially on the S glass side where you're looking at the 704, you'll see a lot of people that need 500 C for whatever reason.  The advantage, obviously, to the glass, as I mentioned, is the higher heat resistance.

There are disadvantages.  Think about fiberglass for a minute.  We actually have to saturate the wire to keep it from fraying without it ever really experiencing any abuse.  If we don't saturate it, then the wire can fray, and you can get fiberglass in your fingers even, which is unpleasant.  So, fiberglass has some disadvantages like that.  If you put it in an environment where there is some movement, abrasion, vibration or something like that, it can be problematic.  Also, it's going to be stiffer because it's saturated, typically.  Sometimes you'll even see those saturants even cause problems in a heat treat environment where, if it gets too hot, the saturant can leave an ash behind.  You're going to lose flexibility, as I said.  You're not going to have the abrasion resistance, the chemical resistance or the moisture resistance that you're going to get from an extruded product.

The other one that we see, again, literally miles and miles and miles of, in the heat treat world would be what's called Refrosil and Nextel, (those are both, actually, trade names).  We're talking about vitreous silica and ceramic.  Again, those are, what we call, high temp textiles.  Now, you're looking at products that are in the 1200 C range.  Ceramic goes up to 1204, vitreous silica is in the 870's.  Again, there are some of the same disadvantages with those that you're going to have with glass.  It's going to be somewhat fragile.  We don't saturate those because the saturants are not going to hold up in the environments that they're going to be placed into, so you would have that ash residue left.

Again, it will be stiff, it will be even larger in diameter than the fiberglass, which is larger than tape which is larger than the extruder products.  Of course, you're not going to have the abrasion resistance, the moisture resistance or the chemical resistance.  But it does protect the wire in those elevated temperature environments that are critical for the heat treating industry.

DG:  Let's back up a bit.  I want to understand something you said.  You said, in the fiberglass, it is saturated and in the textiles it's not.  I want to know what you mean by saturated.

JN:  It's either a solvent-based or a water-based saturant that is applied to the wire to protect it.  Think in terms of a varnish.  It would be like a protective coating.  Again, it just keeps the exterior of the wire, the bare wire, from being exposed.  It's a coating, but we call it a saturant.

DG:  High temperature textiles tend to be the stuff we're using, in the heat treat industry, probably most.

JN:  Yes.  Again, when I mentioned the 800 pound gorilla in the room, the 20-gauge K with the vitreous silica or the Refrosil would be an extremely popular product in the heat treating industry, absolutely.

DG:  Let me ask you a very, very fundamental question.  I'm curious of your answer to this.  Why do we insulate wires at all?  Is it done to protect from temperature or is it done simply to protect them from crossing with each other and grounding or shorting out?  Why do we insulate?

"I'll go back to something that I know Ed talked about: the Seebeck effect. You have this loop; if you don't have that loop, then you don't have anything. You don't have the EMF, the electromotive force, that you're looking for."

John Niggle

JN:  It is the second part.  When you look at any wire construction, the two singles have to be insulated from each other.  I'll go back to something that I know Ed talked about: the Seebeck effect.  You have this loop; if you don't have that loop, then you don't have anything.  You don't have the EMF, the electromotive force, that you're looking for.  We do make a wire that is not duplex, but, typically, what you're going to see is a wire that has two singles and then it's duplexed with an insulation over the top.  We do make a wire that the two singles are jacketed in parallel and then no jacket is placed over the top but that is for an application that wouldn't be suitable for the heat treat industry.

DG:  I asked that question, because for those who are unbaptized in this conversation, it's kind of interesting.  So, we're talking about insulation and we're doing a lot of conversation about temperature ranges and, for someone who wouldn't think so, they would say, "Well, that means you're insulating because of temperature."  But, really, the reason you're insulating wire is for electrical.  It's to keep them apart.  It's just how high of temperatures those insulations can handle, not that you're insulating the wire to keep them cool.  Right?

JN:  Absolutely not.

DG:  That may sound very basic, but there may be people that think that, so I want to get that on the table.

JN:  Most of the people in the audience are probably familiar with this already.  Typically, what happens is the wire is stripped so we have exposed ends.  And then those ends, as we mentioned earlier, can be tack welded onto something or they can just be out there.  The thermocouple world, by the way, is an incestuous world where we have customers, we kind of compete with those customers, some of our customers compete with others of our customers but then they buy supplies from each other.  You probably already know that from talking with other people in this industry.  At any rate, the wire is stripped and then it's either tack welded or it's connected to some sort of sensor or probe of some kind.

DG:  It's a tangled web, the whole thermocouple world.  You've got customers, yet you sell to certain suppliers who also sell to those customers.  It can be complicated!  But that's OK, we'll let you guys worry about that; we just want to make sure the thermocouples are good and we'll be in good shape.

Another question for you:  We talked about the process and a lot of different environments about what type of thermocouple you should use, but does the process being monitored influence the type of insulation that should be used?  Obviously, temperature is going to have an impact, but is there anything else?

JN:  Yes.  Let's circle back to what we talked about earlier just a little bit.  When you look at the process, you need to think of what is going to happen to that wire?  Is it going to see, first of all as you mentioned, the temperatures?  That is certainly important so that comes into play with the insulation.  But, we need to think about, Is there movement?  Is there going to be some abrasion?  Is there some sort of activity that could damage the wire somehow?  Then, we need to look at the chemicals, like we talked about.  Do we need some chemical resistance?  Do we need water resistance?  Is it going to be submersed in something?  Those things all need to be considered.

Again, as I mentioned earlier, the actual placement of the wire.  Does it need to be inserted in a hole?  At Pelican, we produce wire down to 40 and actually 44 gauge which, I think, will probably be stunning to most of the people in your audience because, again, 20-gauge K is what these people think about.  In the heat treating industry, what you see is they need a robust wire, something that's going to be able to handle those temperatures and a large conductor like that.

Another thing to think about, actually, is a bend radius.  Are you going to put the wire somewhere where it needs to go around a corner, around a bend?  Then, are you better off using a stranded wire?  A stranded wire is going to have more flexibility.  You can buy a 20-gauge stranded wire, you can buy 24-gauge, 28-gauge, 36-gauge.

DG:  Now, what do you mean by stranded?

JN:  Stranded wire would be instead of just one solid 20-gauge conductor, you have multiple strands that make up that 20-gauge.  But, if you think about it, multiple strands of wire will actually be more flexible.  You'll still get the same results, but it will be more flexible if you need to go around a corner or if you need to insert it into something.

DG:  It's almost like a braided wire as opposed to a solid.

JN:  Yes.  Now braiding is a little bit of a different process.  When we're talking about stranded wire, it's, basically, just spiral.  Braided is more crossed into each other, which, coincidentally, is the way that the fiberglass and the high temp textile insulations are made – those are actually braided.  And, by the way, I'll just toss this out, it's made on equipment that really hasn't changed since the ‘20s.  I'm not talking about the 2020s, I'm talking about the 1920s!  Rumor has it, some of that braiding equipment was, actually, designed by Thomas Edison.  I'm not sure if that's really true.  But that is the process used to apply the fiberglass and high temp textiles.

DG:  So, anything else as far as any other considerations we need to take into consideration when we're talking about choosing insulation?  If not, that's fine.

JN:  I think I covered them, Doug.

DG:  At Pelican Wire, your company, I know you guys deal with a broad number of markets, I'm sure, one of them being heat treat.  What do you see as any special demands or special concerns that are, maybe, unique or, at least, inherent in the heat treat market?

". . . what you see is insulations that are higher in temperature resistance, as well. In some cases, as I mentioned earlier, in ovens where there is a saturant involved, we could see ash. Some people ask that saturant not be applied to the fiberglass and that's certainly something that can be done."

John Niggle

JN:  For the heat treat market, again, I'll go back to what I said earlier, we see a lot of 20-gauge K used.  It's because of the higher heat requirements, the higher heat that is involved with the processes of heat treating.  Secondly, what you see is insulations that are higher in temperature resistance, as well.  In some cases, as I mentioned earlier, in ovens where there is a saturant involved, we could see ash.  Some people ask that saturant not be applied to the fiberglass and that's certainly something that can be done.

Sometimes we're even asked to not put tracers.  We go back to what we talked about earlier with the metallurgy- you have two legs, a positive and a negative leg.  Well, how do those end users tell those legs apart if they look similar, if they're an alloy of some kind?  So, we put a tracer wire in there so you have a red leg and a yellow leg, in the case of type K, or sometimes you just have a red leg depending on what they ask for.  Those tracers can, actually, cause problems, too, if the ovens are hot enough and they are in there for long enough times.  We even have customers who ask us not to put tracers in their wire, for that matter.

Accuracy, of course, is extremely important.  I know that Ed, in a previous episode, talked about standard limits, special limits and all that sort of thing.  Typically, you're going to see special limits used in the heat treat industry and, in some cases, we're asked even for special calibration points.  In previous podcasts, I've heard you talk with other people about AMS2750 and how that comes into play.  It is extremely critical for the folks in the heat treating industry and something that clearly a thermocouple wire producer has to understand.

Episode 1 of 3 of AMS2750 series

DG:  Let's say you've got a customer that calls you and wants to talk about their thermocouple needs, let's say there is some sort of special need.  What would you suggest they have, in hand, when they call you?  What do you need to know from them to help you do a better job with their thermocouple needs?

JN:  Honestly, the first question we do ask is:  What temperature are you going to be running this at?  How hot are we going to be?  We, absolutely, need to know that.  That helps us narrow down the alloy that we might be looking at, whether it's type K, type J, type E, or whatever.  And then, of course, it's a natural thing to dial in the insulation after that.  Quite honestly, one of the things that frustrates me is when people say, "I need Teflon."  Well, OK.  Do you need FEP or do you need PFA?  Those are both fluoropolymers like Teflon is.  We need to talk about temperature resistance, so don't tell me you just need Teflon.  We do need some specifics when it comes to that sort of thing.  Again, we talked earlier about stranding and stranded wire.  Do you need some flexibility?  What gauge size do you think you need?  How robust does this wire need to be?  Those are some of the key factors we need to know about.

DG:  Let's say, for example, somebody does want to get a hold of you or Ed, your colleague who was on the first two episodes, how is best to do that?  How can we get a hold of Pelican Wire?

JN:  Our web address is www.pelicanwire.com, about a simple as it possibly gets.  Our email addresses are, actually, quite simple, as well.  If anybody wants to email me, it's jniggle@pelicanwire.com.  You can contact me directly, if you want to, or we have a sales inbox and that is simply sales@pelicanwire.com.  We do have a phone number, but it seems a lot of people don't care about phone numbers as much these days.  But the number is 239-597-8555.

DG:  I have one, unrelated, question for you that I know the world is wanting to know:  How is it having a company in Naples, Florida, that's what I want to know?

JN:  I'll tell you what, Doug, the answer today will be different than the answer in October or December.  It's actually quite nice.  We moved down here 8 years ago in 2013.  I moved from the Midwest and didn't really feature myself owning palm trees, but I own palm trees, which is pretty darn cool.  We are, as the crow flies, about 3 miles from the water, where I live anyhow, 20 minutes by car.  Our office and manufacturing facility are, actually, on the very edge of the everglades.  You can see the picture in the background behind me.  That's our building.  That's actually facing east.  That is a sunrise over the everglades.  We're on the very edge of the everglades.  There is a lake right next to our building and then, after that, it's everglades all the way over to Miami.  And, real quick, our weather pattern comes from the east.  It doesn't come from the Gulf.  This time of year, in the summer at about 3:00 in the afternoon, about the time that we're doing this call right now, a thunderstorm blows up and it comes from the east over the everglades and it moves to the west.  The trees blow that direction, you can see it coming.  It's interesting.  During the wintertime, I have to tell everyone, you'd probably be jealous, but it is truly paradise.

DG:  Yes!  I've been to Naples, ate at a nice restaurant down there, years ago, but it was very nice.

You guys are also employee-owned, right?

JN:  That's correct, yes.  The company is over 50 years old.  The founder of the company passed away in 2008 and, before he passed away, he converted the company to an employee-owned operation.  So, we've been employee-owned since 2008.  We've purchased a couple other companies since then that folded into, what we call, the Wire Experts Group.  Pelican Wire is part of that.  We have a sister company out in Colorado.  We bought another facility in Chicago and folded that into our company in Colorado.  So, yes, we're employee-owned and it works out really well for the employee owners, I'll tell you that much.

DG:  That's great.  John, it's been a pleasure talking with you.  Thanks for taking the time.  I appreciate your expertise.  Hopefully, we will see you out on the pavement somewhere in the real world.

JN:  I'll, actually, be seeing you at the heat treat show in about 3 weeks.

DG:  That's about right, yes.

JN:  Hopefully, some of the people that are listening we will see, as well.

Doug Glenn <br> Publisher <br> Heat Treat Today

Doug Glenn
Publisher
Heat Treat Today


To find other Heat Treat Radio episodes, go to www.heattreattoday.com/radio and look in the list of Heat Treat Radio episodes listed.

Heat Treat Radio #64: Thermocouple 101 with John Niggle, Pelican Wire (Part 3 of 3) Read More »

Heat Treat Radio #62: Thermocouples 101 with Ed Valykeo, Pelican Wire (Part 2 of 3)

Heat Treat Today publisher Doug Glenn has a second conversation with long-time thermocouple industry expert Ed Valykeo from Pelican Wire about T/C accuracy and classifications. Listen to learn more.

This is the second episode in a series of three on Thermocouples 101. Check out the first episode of the series here.

Below, you can either listen to the podcast by clicking on the audio play button, or you can read an edited transcript.

 



The following transcript has been edited for your reading enjoyment.

Doug Glenn (DG):  Ed, welcome back.  I'm glad you were brave enough to come back.  Last time, Ed, we talked about a lot of good basic thermocouple stuff.  We talked about, basically, Thermocouples101 which I mentioned last time, was one of the best and most well read articles on our website, which is great.  We covered a lot of different things last time.  I was just reviewing it, and it's interesting, we were talking about several different men as you gave a good history of thermocouples starting back in the early 1800's and talking about guys like Alessandro Volta, where we get the word volt, and Thomas [Johann] Seebeck and the Seebeck effect or the Seebeck coefficient, and things of that sort.  We talked about all the different noble thermocouples, J, K, E, N, and T, and we talked about the N leg and the P leg on all of those which was all good.  It was very interesting.  If you didn't listen to the first episode, you ought to go back and listen to it.  It's really a pretty good summary of thermocouples, a basic primer on thermocouples.  We also did some things like vocabulary for ourselves; we learned what an EMF was, electromotive force and things of that sort.  It was very good.

This time, I think we want to move on to, what we could commonly classify or in a big picture classify as, standardization and accuracy discussion.  But, before we do, I've got a quick follow-up question from the last episode.  We had mentioned that an EMF is produced when two dissimilar metals are joined together or placed together.  There is a very, very, small electric current that's created.  My question is:  Can you do that with any metal?  Is it possible?  Or do you have to have only certain types?

Ed Valykeo (EV):  Theoretically, yes, you could probably join any two different metals and produce some sort of voltage.  However, the accuracy of that, and if doesn't mean anything, probably not.  The thermocouple base metal thermocouples that we talked about last time, are industry known, used worldwide and, quite honestly, have been perfected over many, many years.  So, yes, you could generate a volt probably from any two metals, but, really, to produce an accurate thermocouple, something you can measure temperature with, you're going to want to stick to the thermocouple types that we talked about.

And again, today, we're talking about the base metal thermocouples which are known as Type K, Type J, Type T, Type E and Type N.  Those are the base metal thermocouples.

DG:  Let's talk a little bit about standardization of these things, and accuracy.  My understanding, Ed, is that there are one or more organizations out there in the world that deal with certifying, qualifying, or giving us standards for these thermocouples.  Can you tell us a little bit about those organizations?  Then, we'll jump in and talk more specifically about the classifications and accuracy.

EV:  Sure. One of the bodies that we use is ASTM.  In ASTM-E230, are all the thermocouple tables for the different types of thermocouples, not just the base metal, but also noble metal.  It's a fairly lengthy book.  All the thermocouples are based on the ITS-90 scale and that is the EMF output of each one of these thermocouples at prescribed temperatures.  We could go into more detail with that if you'd like, but there are a number of ways that they have extremely accurate temperature medium to measure the thermocouple output.  But, that's what the tables in ASTM-E230 are based on, the ITS-90 scale.

When we talk about ASTM, there are also a couple of other standards that we use, and we'll probably get into a little bit later in the conversation when we talk about calibrating the thermocouples themselves.  So ASTM-E220 and ASTM-E207 are the two that are used in calibration of the thermocouples.

DG:  But, basically, the organization that does that, I don't know if we want to call them a lab or not, but the organization that does is it ASTM.

EV:  ASTM is one of the bodies that publishes the books that I call the standards for thermocouples.  I think I won't be mistaken, but ITS-90 is really more an IST list.  They control the ITS-90.

DG:  Let's move into the accuracy standards, then.  I think you mentioned the ASTM-E230.  Is there anything else we need to talk about as far as the accuracy standards, or did we already hit it?

EV:  Certainly, in the ASTM-E230, they spell out the different types of thermocouples, as I mentioned, the base metal thermocouples, but the accuracy of each one of those is listed in the ASTM-E230.

DG:  What about classification?  Let's talk about the guidelines for classifying these different thermocouples.

EV:  Again, ASTM-E230, and there are other publications, but, again, we use ASTM here.  The classification of the thermocouples are also spelled out in ASTM-E230 and basically, we talk about special limits of error, standard limits of error and extension grade thermocouple.  Again, those can be found in E230.

DG:  So, when we classify those, are we classifying them based on temperature deviations or the temperature tolerances?  Is that, basically, what it is?

EV:  Yes.  It's based on temperature tolerance.  I'd like to share a quick rule of thumb for classification of those thermocouples.  So, special limits of error, basically from zero degrees Fahrenheit to 500 degrees Fahrenheit, it's + or - 2 degrees, and above 500 degrees it is + or - .4%.  For example, at 1000 degrees, you're looking at + or - 4 degrees; if you have 2000 degrees Fahrenheit, the tolerance at 2000 would be + or - 8 degrees for special limits of error.

On the other side of that, you've got standard limits of error, and, basically, you could just double that.  From zero to 500 degrees Fahrenheit, you're talking + or - 4 degrees; at 1000 degrees would be + or - 8 degrees and at 2000 degrees, + or -16 degrees.

Where there is some confusion, and maybe some people don't understand thermocouples, is when we talk about extension grade.  There are actually two types of extension grade.  There are standard limits of error and special limits of error extension grade.  Extension grade is just exactly as it sounds.  It carries that signal from your sensor all the way back to instrumentation rather than run maybe a little more expensive wire all the back to your instrumentation, you're going to put extension grade to continue that circuit back to the instrumentation.  Extension grade is the same metals as the thermocouples.  If you're using Type K sensor, then you're going to want to use Type K extension grade, and so on, for the rest of the base metal thermocouples.  The difference is that the extension grade material is only guaranteed to meet the tolerances up to 400 degrees Fahrenheit.  If you look at ASTM-E230, the tolerances only go, on extension grade, to 400 degree Fahrenheit.  And, actually, Type T is a little bit different; Type T only goes to 200.

DG:  In the heat treat industry, that's not really going to do us much good, right?  I mean, most of our processes are well above 400.

EV:  It is.  That's why you would never use an extension grade as the actual sensor.  This is some of the confusion out in the industry: “Well, I can just take my extension grade, create a junction and use it to measure temperature.”  You probably could up to 400 degrees, but it's not guaranteed above that temperature, and you could get yourself in trouble.

DG:  So, you run extension grade outside of the furnace because, obviously, you're not above 400, so you can use extension grade to run it.  I think last time we talked about no more than 100 feet rule of thumb.

Extension grade is basically this: Here's your extension cord that you can run from your regular wire, either your standard limit of error or special limit of error, from that to the box.

EV:  Exactly.  And so, the key to understanding extension grade is the tolerances on that extension grade are the same – say if you have special limits extension grade – it's the same as your special limits thermocouple wire, + or - 2 degrees, in this case, up to 400.  It's guaranteed to meet special limits of error and then the same thing on the standard limit side.  You just double those tolerances.  Again, it's really the temperature that it is guaranteed to.

DG:  Very good.  So those are the different classifications.  We've got special limits of error, which is a tighter temperature tolerance, and then we've got standard limits of error, which is a little less tight, and they we've got our extension grade which is only classified up to 400 degrees anyhow.

I know some heat treat processes require very, very tight temperature tolerances, especially in things like aluminum brazing and things of that sort.  Is it possible to get anything better than special limits of error?

EV:  It is.  The first thing I want to say is that they're not really recognized within ASTM, these tighter tolerances.  But, in the industry, certainly in heat treating and in the pharmaceutical side where they typically use Type T, we've had many requests for tighter tolerance material.  Some people call it quarter limit material or half limit material, there's a bunch of different names that it goes by.  So, we go to our manufacturer's of the wire and request that and, most of the times, it's a no quote. It really comes down to more of a selection process.

For us here at Pelican Wire, we have a pretty good sized stocking program of bare conductor and sometimes what we can do is mix and match to try and meet the tighter tolerance material. There are a number of ways that some of the manufacturers, in fact, the heat treaters, will request special limits materials, that must meet + or - 2 degrees up to 1000 degrees and then .2% after that.  It can be done and we do it on occasion.

DG:  Let's follow up on that a little bit.  How do you determine the accuracy of a lot of wire, or a spool of wire?  How do you go about doing that?

EV:  Let me back up just a little bit and start with the actual wire producer themselves: There are not any left in the States, so, basically, all the thermocouple wires are melted overseas, whether it be Germany, France, Sweden.  When they melt, they try to meet special limits of error.  Now you're talking each leg has to be melted separately; they don't melt them all at one time, right?  So, each “melt” or “heat”, they are shooting to make special limits of error.

This is where some of the testing specifications come into play.  ASTME-207 is a test method for single thermal element thermocouple wire.  I don't want to confuse our listeners, but, again, if you think about a melter that just melted or heated a melt of wire and they process it down to wire, they only have one conductor.  They want to know if that one conductor is going to potentially meet special limits of error.  There is a testing specification that ASTM has (ASTME-207) that you can test a single leg thermocouple wire to see if it's going to meet special limits of error.  What they do is they calibrate the single leg, they get their values (the EMF output), and they have the second other leg and they do the same thing.  They, then, mathematically add the EMF of those two and go back and look at the standards to see if it's going to fall within the special limits of error.

That's how the melters, the folks that are melting the individual thermocouple legs, are doing it.  We users, we are an insulator wire, we put the two legs together and now we have a thermocouple.  The way we test those thermocouples is by using an ASTME-220, which is a comparison method.  We're taking a known standard and we're calibrating the thermocouple wire against that standard and getting the temperature deviation from that.  That's how we verify that the wire is meeting the tolerance that is requested by our customers, whether it's special limits of error, standard limits of error or even extension grade.

DG:  When you say "a standard", what does that test actually look like?  Are you taking a thermocouple that you know is good, sticking it in a hot furnace and your test thermocouple or are you just doing it through current testing or something like that?

EV:  Good question.  We actually use SPRTs (resistance thermocouples) high accuracy, that we use as our standard.  They're calibrated at an outside firm, so we know what the output of that resistance thermometer is, and we calibrate our sample against that.  The three things you need to do a temperature calibration is the temperature medium, the reference thermometer and the equipment to capture that output or measure the voltage that's being produced.  Having those, we have our reference standard that we know the EMF or the temperature output of.  Now, we put our thermocouple in the furnace and we compare the two.  That's how you get your deviation.

DG:  There are labs, I understand, that do these certifications and things of that sort, that certify the accuracy of the thermocouple.  Now, Pelican Wire does that.  You do have a lab and you do certifications, right?

EV:  We do.  We calibrate the thermocouples and we produce a test report showing the deviation of the thermocouple for the customer.

DG:  Earlier, we were talking about standards and how there's the organization ASTM.  How about for these labs?  Do the labs have to meet some sort of outside third party certification?

EV:  There is nothing that they have to do.  I will say that there are a number of standards.  We're ISO9001, but we're also seeking accreditation for 17025 so that our lab is accredited to IECISO17025, which just proves that we are a quality lab.  We have our quality systems in place.  We have our uncertainty budgets for all the equipment we use.  A customer can feel confident that the calibration report that we provide is as accurate as possible.

DG:  I think covers most of the things we wanted to cover in this episode.  We talked about the standardization, the special limits of error, the standard limits of error, who are the bodies out there that do the certifications/classifications, if you will.  I think we covered a good bit.

I think we were going to do one more episode, Ed, and I think we're going to talk about insulating materials.  I understand that one of your colleagues is going to be there to talk about that with us, John Niggle.

EV:  Yes.  John Niggle will join the next podcast and talk a little bit about how now that we have the thermocouple wire, what kind of insulations do we put on that wire.  It depends on the medium that it's going to be used in, the heat treater or whoever.

Doug Glenn <br> Publisher <br> Heat Treat Today

Doug Glenn
Publisher
Heat Treat Today

 

 

 

 

 

 

 


To find other Heat Treat Radio episodes, go to www.heattreattoday.com/radio and look in the list of Heat Treat Radio episodes listed.

 

 

Heat Treat Radio #62: Thermocouples 101 with Ed Valykeo, Pelican Wire (Part 2 of 3) Read More »

Heat Treat Radio #61: Thermocouples 101 with Ed Valykeo, Pelican Wire (Part 1 of 3)

Heat Treat Today publisher Doug Glenn sits down with Ed Valykeo from Pelican Wire in the first of a three-part series on all-things thermocouples. This first episode covers the history, types, vocabulary, and other basics of understanding how thermocouples work.

Below, you can either listen to the podcast by clicking on the audio play button, or you can read an edited transcript.

 



The following transcript has been edited for your reading enjoyment.

Doug Glenn (DG):  Ed, why don't you take a minute, as we typically do on these interviews, to talk briefly about you and your background especially your qualifications for talking about thermocouples.

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Ed Valykeo (EV):  I've actually been in the wire and cable industry for a little over 40 years now.  I actually first started in the industry as, well maybe not a grunt, but certainly I was called a “melter's helper.”  I worked at a company called Hoskins Manufacturing in Ann Arbor, Michigan where we actually melted the raw materials to make thermocouple wire, resistance wire, and a whole host of other things.  I was actually the guy that, after we got done pouring that molten metal into the molds to make the ingots, was cleaning up all the mess that happens after you pour and you're pulling those ingots.

That's really where my career started, with Hoskins.  As a matter of fact, it kind of ran in the family.  My dad retired at Hoskins with 42 years of service with Hoskins, so it was kind of a natural progression that, eventually after I got out of the service, I ended up joining Hoskins.  I was there about 18 years at Hoskins Manufacturing, again, starting out right at the bottom.  I worked my way up to becoming an associate engineer working in the R&D department.  That's where my career really started focusing a little more on thermocouples.  I enjoyed working with thermocouples.  We were developing some new products using thermocouple wire and things like that.

Ever since then, I've kind of stayed in thermocouple arena at some of the other places I've worked.  After I left Hoskins, I started working for companies that insulated wire.  So, we were taking the wire, like we made at Hoskins, and we were putting a whole host of insulations on it from ceramic braid to extruded products and things like that.  And, again, both the companies, and even the one I'm currently employed with at Pelican, but before that I was working for a company out in New Hampshire called PMC, are real similar, it's just we insulated wire.  So, we purchased the raw materials (raw wire from Hoskins or whoever) and then insulated it.

DG:  For the unbaptized in this topic, what are thermocouples, how do they work, how do they come about, and then are the modern-day thermocouples any different than the thermocouples of old?

EV:  I always start out with a little bit of history about thermocouples, whenever I'm talking about them, just to give people background.  Thermocouples were introduced in the early 1800's with the most significant developments taking place in Europe.

One of the very first gentleman that worked on it was Alessandro Volta.  You can probably recognize the name because Volta actually is the volt, today, which everybody recognizes, not just with thermocouples but, obviously, in the electrical industry too.  He basically built a couple thermopiles using metals, silver and zinc and some cloth in between them, soaking them in salt water, and discovered that it would produce a voltage.  That's kind of how it got started.  The significance of that discovery was that there is a source of steady and reliable current flow from using dissimilar metals and saltwater and things like that.

Thomas Johann Seebeck, Baltic German physicist, who, in 1822, found the relationship between heat and magnetism.

Over the years, many others have experimented with the phenomenon.  Probably the most famous, anybody that's in the thermocouple industry will hear it a lot, in 1821, Thomas [Johann] Seebeck announced that he had discovered that when two dissimilar metals were placed in a closed loop and one of those junctions was exposed to a change in temperature, electrical current was produced.  This production of the electromotive force and electromatic force is the electric current is known as "the Seebeck effect" or "Seebeck coefficient."  It was, obviously, much later, before everything was understood and correct mathematics, but Seebeck's name will always and forever be associated with the discovery of thermoelectricity and thermocouples.  Again, even to this day, even ASTM books reference Seebeck coefficient.

Some other gentlemen that we involved, again you'll recognize some of these, were Michael Faraday, Georg Ohm, Claude Pouillet, and Antoine [César] Becquerel.  It was Becquerel, actually, that suggested using Seebeck's discovery for measuring high temperatures.  He proposed the strength of the current generated was proportional to the change in temperature in exactly the principle behind the thermocouple.  We're measuring temperature, whether it's 200 degrees or 2300 degrees.  That's how the modern day thermocouple got started way back in the early 1800's.

DG:  And the modern-day thermocouples are, essentially, the same as that?  Have there been any major changes?

EV:  In reality, Type J was the first thermocouple to really be experimented with.  After Type J, then some additional thermocouple types came on board.  People experimented with other metallurgical compositions to develop different millable outputs.

DG:  Let me understand:  Type J, what that basically the first type of thermocouple that was developed?

EV:  Let me back up a little bit.  Actually, the early metal thermocouples were based on what we can call noble metals.  Noble metals are rare earth elements such as platinum, rhodium, tungsten and uranium.  The problem with the noble metals is that noble metals are much more expensive than our base metal thermocouples, or what we call base metal thermocouples, today.  Base metal thermocouples, today, typically the compositions are just a handful of elements.  You have iron, nickel, chromium, copper and things like that, which is considerably cheaper than the noble metals, the platinum and rhodium and things like that.

DG:  I want to learn this history a little bit, because it's just kind of fascinating to me.  So, the very first ones were made of noble metals, primarily. So, they would put those together and then, basically, we said, "This is great but it's way too expensive.  Can we get the same effect, if you will, (the difference in voltage, or whatever, between dissimilar metals), if we use a little less expensive metals?"

EV:  Right.

DG:  You’ve said there is a difference voltage when there's a difference in temperature.

EV:  The EMF (electromotive force) generated by the thermocouple is linear.  So, at 200 degrees, it produces this amount of voltage, at 300 degrees, it produces this much.  All the thermocouples are, basically, the same principle.  It's very linear.  That's one thing that is good about a thermocouple- the EMF output is linear.  You aren't producing a millivoltage at 200 degrees and then at 300 it goes down and then at 500 it goes back up; it's linear proportional to the temperature.

CLICK the image to access the article!

DG:  I have heard in the past, and you mentioned it here, maybe we can discuss it a little bit:  noble metal versus base metal.  Obviously, we know noble metals, you mentioned what those are.  Those are expensive; they work to do the same thing.  Base metals, though, tend to be what?  Which metals?

EV:  As I already mentioned, the nickel, chromium, copper, and others.

DG:  And those are, in fact, just less expensive, right?  Essentially, they do the same thing but they're less expensive.

EV:  Exactly.  But, there are some other differences, too, between the noble metals and the base metal thermocouples.  When you're talking noble metals, the platinum and the rhodium, and things like that, they can handle much higher temperatures than even the base metal thermocouples.

DG:  I'm going to make an assumption, but probably the vast majority of the thermocouples used in the heat treat industry are probably base metal, although, I'm sure they've got some specialized ones for high temperature, which probably jump into noble metals.

EV:  Absolutely.  A lot of the base metal thermocouples are used in the load sensors where they're putting multiple sensors in and then the oven may be controlled by a noble metal.

DG:  The different types of thermocouples.  You mentioned, and I've forgotten the letter already, that there are different types.  Was it Type J you mentioned?

EV:  Yes, Type J.

DG:  OK.  We've done a study recently asking about what's the most popular one in the heat treat industry, but I know we listed down there J, E, K, N, and T.  Can you run us through those and tell us what are the differences, and whatnot?

EV:  J, E, K, N and T are the most common noble metal thermocouples.  Obviously, you've got two dissimilar metals or, what we refer to in thermocouples, two legs of the thermocouple – the positive leg and the negative leg.  So, for instance, on a Type J thermocouple, you're using iron as a positive leg, which is basically pure iron, (there are some coatings on the iron to help against oxidation and things like that), and the other leg is a copper nickel alloy.  That makes up the two legs of the Type J thermocouple.

If we look at Type K thermocouple, the negative leg is the KN which is, basically, just high nickel with a little bit of chromium; the KP leg, or the positive, of Type K is higher content nickel chromium.  There are also some other minor elements.

With Type T, the positive leg is pure copper.  The TN leg is, again, a copper nickel alloy.  So, when we talk about Type E, what is interesting is that with the Type E thermocouple, you're actually taking the Type KP leg and matching it with the TN leg.  So, again, it's just a mismatch or some hodgepodge of some legs.

DG:  So, you're using some lingo that I'm just picking up on and I want to make sure our listener's are, as well.  You talk about a P and an N leg.  Obviously, you didn't say it, but you're talking about a positive leg and a negative leg.

EV:  Yes, I'm sorry.  KP and KN.  So it's K positive and K negative leg.

DG:  Great.  So, with the Type E, you're taking a few and switching them around and matching them up and seeing what you can come up with.

EV:  Yes, that's the E, and I already mentioned the T.  N is a relatively newcomer to the thermocouple industry.  I say new, but it's still probably 40 or 50 years, I'm not sure when it was developed.  But, again, the Type N is similar to the Type K where the KP leg is a nickel and the KN leg is nickel and some silicon.  So, it's just a little bit different composition from the Type K thermocouple.  But, there are some differences.

Some of the differences, when you're looking at the different types of thermocouples, for example, Type E has the highest EMF output of any of the thermocouples.  Your question might be, "Well, why wouldn't we just use Type E because it has the highest output?"  What the higher EMF output means is that the sensitivity is a little bit greater in the Type E thermocouple.  Then why wouldn't we use that throughout all the industries?  Well, the short answer is, a couple things:  Type E has a limited temperature range, because, again, you're using that TN leg which is copper nickel alloy and the melting point of a copper nickel alloy is much lower than a nickel chromium alloy.  So, that's some of the differences, and with all the thermocouple types, also.

Each one has their own EMF output at certain temperatures but one of the biggest considerations is, really, the environment that you're using the thermocouples in.  Type K has good oxidation resistance; Type J, not so much, because you've got a pure iron leg which is going to oxidize much faster.  That's some of the differences between the individual thermocouple types.

DG:  I assume that if there's oxidation, or any type of corrosion or anything of that sort, it's going to change the EMF, it's going to change the reading and therefore that thermocouple, out the door she goes.

EV:  Absolutely.  And there have been even some recent changes in some of the specifications that some of the heat treaters are using nowadays where they finally realize that these thermocouples do deteriorate over time and so they start limiting the amount of uses that each thermocouple can be used in, in a bunch of different applications, but heat treating mainly.

DG:  Let's pause for just a second and do a little vocabulary.  You've mentioned EMF a couple of different times.  Could we have just a brief review of that just to make sure?  Also, I've heard about millivolts.  Are those two things related?  If so, how?

EV:  EMF stands for electromotive force.  It is, basically, when two dissimilar metals are put in contact with each other, a small voltage is generated.  When we're talking about millivolts, that's exactly what we're looking at: a millivolt is 1/1000 of a volt.  It's a very small amount.  If you look at some of the millivolt outputs for some of these thermocouples, at 200 degrees, for example, you're putting out .560 of a millivolt.  So, these are small.

DG:  And you're saying that it was the Type E that has the highest millivolt of all, so the current that is produced between those dissimilar metals is the highest, but you can't always use that one because in certain temperature ranges you're going to melt one of the legs.

EV:  Exactly.

DG:  The millivolts are measured by what?  I mean, it goes into an instrument that is able to read that?  What is that instrument?

EV:  Actually, some DVMs (digital volt meters) have the capacity to measure in the millivolt range.  So, it could be as simple as a digital voltmeter.  But, in the industry, we have temperature controllers, things like that, that you hook a thermocouple up to and it measures the EMF and then it converts it into a temperature.

DG:  It will measure that millivolt and then tell us what the temperature is?

EV:  Right.  With the instrumentation nowadays, it has the formulas in its memory, or whatever, and can convert that millivolt into an actual temperature that you actually read on a meter.

DG:  We've got an EMF which is measured in a millivolt.  It's going to travel across a long wire, I assume, to some place where it's going to be read.  Let's talk about that wire a little bit.  The impact of this, whatever EMF is being created, millivolt, what about that wire?  Tell me about it and what do we need to be careful of, etc?

EV:  We're actually saving that for another podcast, but I will touch on it a little bit.  So, there are limitations on the length of the thermocouple.  There are a lot of different mindsets, but probably the one I've heard the most is no longer than 100 feet.  So, you have your thermocouple sensor and that arrangement, the configuration, can be a number of ways.  At PMC Corp. we insulate the wire.  You could just take that insulation off at the end, weld the junction there, stick it and [. . .] then run it to a meter.

But in other industries, you may have it in a ceramic tube because of the temperature it's being used at.  You have a ceramic tube with a connector at the end, you may run what we consider an extension wire from that point all the way back to your instrumentation.  Again, the general rule of thumb, is 100 feet.

DG:  Let's talk about that wire with the different types of thermocouples.  What do we need to be sensitive to?  What do we need to be careful about?

EV:  Again, temperature range is probably the first consideration, but then also the environment that it's in.  Again, each thermocouple has its limitations on the environment.  Some are good in a vacuum, other thermocouples are not good in a vacuum.  Some thermocouples are good just in air, (like Type K), but Type J is not so good.  It still can be used in air but it will oxidize faster.

Like I said, in an environment of a vacuum, some thermocouple elements will actually leech out or evaporate out and that definitely would cause a problem with the EMF output and would have an erroneous reading.  Certain acids you can use some thermocouples in, others you can't.

DG:  With all of this pyrometry stuff going around, especially the AMS2750 revision, there are a lot of places where the tightness of the tolerance on the temperature really needs to be paid attention to.  Are some thermocouples inherently tighter tolerance, where they can go down to + or –2, or less than that?

[blockquote author="Ed Valykeo, Pelican Wire" style="2"]Special limits of error is the tightest tolerance, and that's according to ASTM.  But, there are some customers and some companies that want tighter tolerance material.  So, when we talk about that, that's really a special order.  Now you have to back all the way back up to the melters that melt these elements and make the thermocouple wire.  It's on them to produce something that is a tighter tolerance. [/blockquote]

EV:  Again, that was something we were going to touch on a little bit later, maybe on another podcast, because it can be a whole category on its own.

But, yes.  If you think about in general, overall, when we're thinking about the different thermocouple types, they basically all have the same tolerances according to ASTM.  The rule of thumb, that we kind of use, is from say 200 degrees to 500 degrees, the tolerance on all thermocouples are + or - 2 degrees if you want special limits of air material.

Now, there are other tolerances.  In the thermocouple industry, you’ll here – at least calibration-wise – you'll hear special limits of error, standard limits of error and extension grade.  Special limits of error is the tightest tolerance, and that's according to ASTM.  But, there are some customers and some companies that want tighter tolerance material.  So, when we talk about that, that's really a special order.  Now you have to back all the way back up to the melters that melt these elements and make the thermocouple wire.  It's on them to produce something that is a tighter tolerance.  Once that metal is poured in that mold and it's processed down the wire, it is what it is.  When they calibrate that wire, you can't really do a lot with it to change the EMF output, per se, other than there are some heat treat operations that can, what they call, stabilize, and there are processes to oxidize thermocouple wire, and things like that, but you're pretty much stuck with EMF right from the melt.

DG:  And it's dependent on the material composition or quality of the material.

EV:  Absolutely.  In some cases, they may melt 10 melts to get 2 special limit of air thermocouple types.  I don't think it's quite that bad, bur from my early melting days, we've had to downgrade many a melt because it didn't quite meet the tolerances.

DG:  Just reviewing, we talked about the basic history, how they got started.  We talked about the difference between noble versus base metal thermocouples.  We talked about the different types.  We defined EMF, electromotive force.  We talked about millivolt a little bit.  We talked about the wire, the differences in what we need to pay attention to as far as wire, and some other considerations like temperature range, calibration tolerance and environment.

EV:  Just so you know, the only base metal thermocouples there are, at least what ASTM recognizes, are the Type J, E, K, T and N.  We covered all the base metal thermocouples.

DG:  Just out of curiosity, a noble metal thermocouple, what are those?

EV:  There is a fairly large list of those.  You've probably heard of thermocouple Type R or Type S thermocouple.  Those are all made with noble metal thermocouples.  It's not really considered a base metal, but tungsten uranium thermocouples.  Those are in more the noble metal category Type C.  There is even development of some other additional noble metals:  gold is used.  Thermocouples are made out of gold.

DG:  Those could be expensive.  Of course, some of those other metals are more expensive than gold, so, who knows?

Well, that's very interesting.  So, J, E, K, N and T are all base metal thermocouples.

I want to make sure that we give appropriate credit to your company.  We talked about the fact that you're from Pelican Wire, part of the wire expert group.  I want to make sure that our listeners know that they can go check out your website which is pelicanwire.com.  You're not obligated to do so, but would you like to give out any other information where they can get a hold of you?

EV:  Yes.  Through the Pelican website, you can certainly get a hold of me.  Our number is on the website.  It's 239-597-8555 and it goes through a central board.  If anyone wants me, they can just ask for me through the operator.

Doug Glenn <br> Publisher <br> Heat Treat Today

Doug Glenn
Publisher
Heat Treat Today

 

 

 

 

 

 

 

 

 

 

 

 

 


To find other Heat Treat Radio episodes, go to www.heattreattoday.com/radio and look in the list of Heat Treat Radio episodes listed.

 

 

Heat Treat Radio #61: Thermocouples 101 with Ed Valykeo, Pelican Wire (Part 1 of 3) Read More »

Thermocouples: Know Your Limits

OCAre you a heat treater who makes thermocouples? How do you stay within limits? What do you need to know when using specific thermocouple materials? Read all about it in this Heat Treat Today Original Content article by Ed Valykeothermocouple specialist at Pelican Wire, Naples, FL.


Ed Valykeo
Thermocouple Specialist
Pelican Wire

We are often asked, what is the difference between special limits of error, standard limits of error, and extension grade thermocouple wire? Today’s discussion will review base metal thermocouple tolerances for special, standard, and extension grade wire. First, we will look at the difference between a thermocouple wire producer and the different types of thermocouple wire users. Then, we will look at emf (electromotive force) data for single leg thermoelements and how to determine temperature deviation. Finally, we will touch on how thermocouple wire is manufactured at the wire producer.

Thermocouples

Since thermocouple materials are supplied with different levels of accuracy depending on the standard being used, ANSI/ASTM E230 identifies accuracy requirements for standard limits of error, special limits of error, and extension grade.

The two tables below list the accuracy requirements for standard, special, and extension grade thermocouples and thermocouple wire.

A thermocouple is a sensor for measuring temperature in which a pair of wires of dissimilar metals are joined at one end. The other end is connected to an instrument that measures the difference in potential created at the junction of the two metals.

From this definition, we know that a thermocouple must have two wires of dissimilar metals. For example, the positive leg (KP) of a Type K thermocouple consists of nickel and chromium, the negative leg (KN) is nickel, aluminum, and silicon. Type J consists of iron in the positive leg (JP) and copper nickel in the negative leg (JN). It has taken decades for thermocouple wire producers to perfect the chemical composition of each thermoelement to achieve desired emf outputs. When these elements are melted, the electromotive force generated can be predicted.

A thermocouple wire producer is where a thermocouple gets its start. Raw chemical elements such as nickel, copper, chromium, manganese, and silicon are melted to form individual thermoelements. The process of melting metals into a usable wire size is done in several ways. A typical method is to melt and pour to form ingots; ingots are then broken down into bar form, and then the bars are hot rolled into rod before the rod is cold drawn to the desired wire size. Producers supply thermocouple materials in rod, wire, and strip form. There are only a few thermocouple wire producers left in the world today.

Measuring Electromotive Force (emf)

As mentioned above the first step in the life of a thermocouple is the melting step. Chemical elements are gathered and weighed to the desired recipe. The goal is to hit the desired emf curve for a single thermoelement. The process is repeated for the other leg of the thermocouple. Each thermoelement leg is calibrated to get emf data. Once emf data for each leg is known the data can be matched to hit the desired calibration i.e., special, standard or extension grade limits of error. Examples 1 & 2 are emf data provided by a thermocouple wire manufacture. This data is typically posted on each thermoelement spool.

If the emf data is known for each thermoelement, it is easy to compute the total emf output and temperature deviation in the case that these two spools are combined to make a thermocouple.  Below, Example 3 shows how the two individual thermoelements are combined and the resulting emf, and temperature deviations are computed.

Measured emf output of single thermoelement

Step 1: Algebraically add the emf outputs for both thermoelements at each temperature point. (KP + KN)

Step 2: Take the total emf output of both the KP and KN and subtract value from the tables listed in ASTME230 Standard Specification and Temperature-Electromotive Force Tables for desired thermocouple types.

Step 3: Take the delta value and divide by 0.022mv.  (For Type K, the nominal millivolts (mv) per degree is 0.022)

The results show that as a thermocouple, the material meets special limits of error.

Factoid:  One quick rule of thumb for Type K Special Limits is ±2.0°F up to 500°F and then ±0.4%.

Buying and Using Bare Wire

It is important to understand thermocouple wire producers sell bare wire in matched sets. By selling in matched sets the producer can guarantee the total emf output falls within special, standard, extension grade limits of error. As mentioned earlier, wire producers melt thermoelements to a precise “metallurgical recipe.” Even though these recipes have been proven out over time, there are still factors which affect the emf output. For example, impurities in raw materials, condition of the furnace and melting practices all contribute to emf results. Since thermocouple wire producers know the emf output of each thermoelement they can mix and match melts to minimize any scrap.

Caution should be taken if bare wire thermocouples are going to be fabricated from positive and negative legs that have not been matched by the wire producer. Any one individual thermoelement can have emf output that, when matched with the opposite leg, could cause the total emf output to fall outside the required tolerances.

If we required special limits of error thermocouples the results of matching the KP and KN leg in Example 4 below, shows the material would not meet special limits at 200 and 1,000 degrees.

The example of KP and KN shown in Example 4 does not meet special limits of error at 200ºF and 1000ºF. What about standard or extension grade tolerances?

Reviewing Table 1, we can see that the tolerance for standard limits of error is ± 2.2ºC or ± 0.75%. By applying note 2 the tolerance for standard limits of error at 200ºF is ±4.0ºF so this combination of KP and KN would meet the tolerances for standard limits at 200ºF. At 1000ºF the tolerance for standard limits is computed as 1000ºF X .75% or ±7.5ºF. This combination does in fact meet the standard limit tolerance at 1000ºF.

What about extension grade? Would the above KP and KN meet extension grade tolerances?  Let us refer to Table 2. Table 2 shows that from 32ºF to 400ºF for special limit extension grade the tolerance is ±2.0ºF. Our matched KP and KN above has a temperature deviation at 200ºF of -2.35ºF.  This match would not meet the requirements of special limit extension grade at 200ºF. However, this combination would meet the special limits requirement at 400ºF. What about standard limits extension grade? This combination would in fact meet the tolerances for standard limit extension grade.

Factoid: The tolerances for special limits, standard limits, and extension grade, thermocouples and thermocouple wire are the same! The only difference is that EX, JX, KX, and NX extension grade have a maximum temperature range of 400ºF. Maximum temperature range of TX is 200ºF.

Types of Thermocouple Users

One type of thermocouple wire user, whom we will call an intermediate user in this article, receives the bare wire from the producer and performs additional processing. This processing typically consists of adding an insulation of fiberglass, high temperature textile, extruded thermoplastic or tape to the individually matched pairs, then commonly adding an outer jacket over both thermoelements. There are any number of custom constructions that can be part of this processing, including but not limited to shielding, metal over-braid, multi-pair cabling and combinations or layers of the above insulations. The bare wire can also be incorporated into a mineral insulated cable. Careful consideration is taken to ensure only the two thermoelements matched originally by the bare wire producer are used in the processing. After the insulation process, the wire is then ready to be sent to another type of thermocouple wire user or consumer.

Very commonly, an intermediate user, like Pelican Wire, sends the processed bulk wire to temperature sensor manufacturers. Although not an end user, these sensor manufacturers would still be considered users of thermocouple wire. However, they are distinguished from intermediate users, because of the assembly or fabrication work they perform with the wire. As stated previously, it is crucial the wire be sent to the sensor manufacturers in matched pairs to ensure the calibration accuracy of the wires.

Simply put, an end user is an entity which uses a thermocouple sensor for measuring and monitoring temperature in a manufacturing, or laboratory environment. Examples of this are heat treating metals, curing composites, food & drug processing, monitoring in the oil & gas sector and power generation. The critical nature of the outcomes of these processes point to the importance of accuracy and reliability in a thermocouple and thermocouple wire. An important element of this is understanding calibration of thermocouple wire and the Limits of Error classifications.

There is more information that cannot be covered in this discussion. If you are an end user with questions regarding this subject it would be advisable to contact an experienced thermocouple wire user who processes and does assembly work regularly with the wires for additional guidance.

 

About the Author: Ed Valykeo, a 40-year veteran in the wire industry, many with Hoskins, is a thermocouple specialist who has worked with Pelican for 10 years.

 

All tables provided by Ed Valykeo at Pelican Wire.

 

 

 

Thermocouples: Know Your Limits Read More »

Considerations for Base Metal Thermocouple Wire Diameters

OC

Ed Valykeo
Thermocouple Specialist
Pelican Wire

John Niggle
Business Development Manager
Pelican Wire

“What size wire should I use in my thermocouple assembly?” While this is a pretty direct question, the answer is more complex. In this fascinating Technical Tuesday article, learn how both the type of thermal processing as well as the stability and performance of the thermocouple contribute to selecting the right size wire. Read more in this Heat Treat Today Original Content article by John NiggleBusiness Development Manager, and Ed ValykeoThermocouple Specialist, at Pelican Wire, Naples, FL.


This article will discuss influences that should be considered when choosing the wire diameter in a base metal thermocouple circuit. It is important to keep in mind each thermal process will dictate the type and size of thermocouple. It is also important to understand there are several factors which influence the life expectancy of a thermocouple circuit.

We often get asked, “What size wire should I use in my thermocouple assembly?” The quick and simple answer is, “Use the largest practical size.” While this may be true, the individual thermal process should dictate the proper wire size.

The selection of a specific wire size for a given thermal process is related to the question of “expendability.” A thermocouple not exposed to harsh environments or excessive temperatures should have a long and useful life. Thermocouples exposed to corrosive atmospheres and elevated temperatures should be considered expendable. In general, if a thermocouple wire is deemed expendable then the wire should be no larger than necessary. If the thermocouple wire is exposed to excessive temperatures, or harsh environments, a larger diameter wire may be required.

There are several factors that affect the stability of thermocouple alloys:

  • Evaporation – Especially at higher temperatures certain elements evaporate more readily than others.
  • Diffusion – Alloying elements from one leg to the other.
  • Oxidation – In most cases oxidation in clean air is beneficial for thermocouple performance. As oxide film thickens with time and temperature, the overall composition of the thermoelement changes.
  • Contamination – Changes in wire composition can affect thermocouple drift. Contamination from sulfur, iron, and furnace refractories can be sources of contamination.

Each of the above factors can induce EMF (electromotive force) drift, caused by a change in alloy composition. EMF drift is the potential for the thermocouple to lose its accuracy over time. Typically, this change takes place on the surface of the wires. Since smaller diameter wire has increasing ratios of surface to volume exposure, they are more rapidly affected by surface effects. The rate at which this phenomenon progresses accelerates as the temperature increases.

(Source: Pelican Wire)

It is important to keep in mind each base metal thermocouple type has its advantages and disadvantages. The environment and temperature range contribute to the overall thermocouple performance. Using a thermocouple in the wrong environment or incorrect temperature range could increase the opportunity for adverse surface effects, regardless of the wire size.

There are other considerations when choosing a wire size in a thermocouple circuit:

  • Stem Loss – Stem conduction is heat conduction along the length of a wire. When the heat source end and the cold junction end of the wire are at different temperatures, stem conduction occurs. This temperature discrepancy produces a reading different from the actual heat source temperature. Using a larger gauge conductor could produce an error due to stem loss conduction.
  • Resistance – The industry standard is to keep total loop resistance of your circuit under 100 ohms. Loop resistance is determined by multiplying the length in feet by the resistance per double feet. Double feet is the resistance per foot of each thermocouple element. Decreasing the wire size results in the increase of resistivity of each thermoelement, which affects total circuit resistance.
  • Flexibility – Some thermocouple assemblies are run through conduit or inserted in protection tubes. As you increase the wire diameter you lose some flexibility.

Useful thermocouple life is difficult to predict, even when most of the details of an application are known.  The best test for any application is to install, use, and evaluate the performance of a design that is thought likely to succeed.  Thermocouple type descriptions are good source for determining recommendations, and prohibitions for thermocouple use.

Keeping in mind these recommendations, as well as having a better understanding on what affects thermocouple performance, should help you select the proper wire diameter for your specific application.

 

About the Authors: John Niggle has been the business development manager at Pelican Wire since 2013 and has prior sales experience in process instrumentation. Ed Valykeo, a 40-year veteran in the wire industry, many with Hoskins, is a thermocouple specialist who has worked with Pelican for 10 years.

 

Considerations for Base Metal Thermocouple Wire Diameters Read More »

18 Quick Heat Treat News Chatter Items to Keep You Current

Heat Treat Today offers News Chatter, a feature highlighting representative moves, transactions, and kudos from around the industry.

 

Equipment Chatter

  1. TAV VACUUM FURNACES SPA sold two horizontal all metal high vacuum heat treatment furnaces to a well-known Chinese heat treater working in the manufacturing industry.
  2. Honeywell announced that Global Control Pte Ltd, a global heating system original equipment manufacturer (OEM), is incorporating Honeywell technologies, including the ControlEdge™ HC900 controller, into its heat treatment solutions to help its customers improve their asset performance, reduce their inventory and lifecycle costs, and save energy.
  3. Grieve Corp. announces 1250°F (667°C) inert atmosphere oven currently used for heat treating firearms components at a customer’s facility.
  4. Tenova, a company specializing in innovative solutions for the metals and mining industries, started up the most productive Electric Arc Furnace in history, a Tenova Consteel® EAF, at Acciaieria Arvedi, Cremona (Italy) on September 17 this year.
  5. ECM Technologies announces the release of a new furnace system which will replace current sealed quench (SQ) or integral quench (IQ) style furnaces.
  6. Hubbard-Hall has completed the first phase of a three-year Digital Initiative Strategy.  This phase focuses on creating a more engaging user experience, with use of Web Chat and On-Demand Portal technologies.
  7. Gasbarre Thermal Processing Systems is pleased to announce the recent commissioning of a Vacuum Oil Quench Furnace, which included 2 BAR gas quench capabilities to an international manufacturer.
  8. Kanthal is adding a 60 kW heater to its range of flow heaters to meet demands for higher power in industries like aluminum and glass.


Personnel Chatter

  1. Hubbard-Hall Inc. welcomes Joshua McClellan as application engineer-cleaning and Becky Cavazuti as customer engagement key accounts manager. These roles are critical in expanding Hubbard-Hall’s services in metal finishing operations and achieving customer’s goals with less cost, complexity, and chemical consumption.

    Group picture with Joshua and Becky from Hubbard-Hall.
  2. Hubbard-Hall Inc. welcomes Fernando Carminholi as Business Development Manager.
  3. Wire Experts Group, the parent company to Pelican Wire of Naples, Florida and Rubadue Wire of Loveland, Colorado has named Trent Dunn as the new WEG Marketing Manager, with overall responsibility for the marketing departments of all business units, including the parent organization.
  4. The Heat Treating Society of ASM International welcomes to the board Steven Ferdon, director engineering technology, Cummins Incorporated. Chuck Faulkner, commercial development manager-heat treatment, Quaker Houghton, and Marc Glasser, director of metallurgical services, Rolled Alloys, were reappointed for a second three-year term.


Company Chatter

  1. Brian Fitzpatrick, District 1 US Congressman, Bucks County, Pa., at the Solar Manufacturing plant.

    Custom Electric Manufacturing was acquired by Sweden-based Kanthal in 2018 and will now go to market under the Kanthal brand. The transition will be effective as of January 1, 2021. View a video with Jon Hartmayer and Victor Strauss about the brand transition.

  2. Brian Fitzpatrick, District 1 US Congressman, Bucks County, PA., toured the Solar Manufacturing plant in Sellersville, PA.
  3. Advanced Heat Treat Corp. (AHT), a recognized leader in heat treat services and metallurgical solutions, announced a new logo for their UltraOx® heat treatment today. The new logo features an ox as the term ‘ox’ is often used as an abbreviation of the term ‘oxide’ – one of the three steps of this protective heat treatment.


Kudos Chatter

  1. Lindsey Newcomb, Marketing Manager at Advanced Heat Treat Corp. (AHT), was recently selected for a “2020 20 under 40 list,” furthering the understanding/awareness of heat treat among the general public.
  2. In August, 2020, Solar Atmospheres of Western Pennsylvania (SAWPA) participated in a Boeing Supplier Assessment. The on-site, preventative engagement resulted in zero findings and Solar, once again, achieving preferred status for Heat Treating, Hardness, and Non-Destructive Liquid Penetrant Testing.
  3. Advanced Heat Treat Corp. recognized in the 2020 Courier Employers of Choice. These honorees demonstrate the diversity of career options in and continued commitment to healthy communities in Cedar Valley, IA.

 


Heat Treat Today is pleased to join in the announcements of growth and achievement throughout the industry by highlighting them here on our News Chatter page. Please send any information you feel may be of interest to manufacturers with in-house heat treat departments especially in the aerospace, automotive, medical, and energy sectors to editor@heattreattoday.com.

 

18 Quick Heat Treat News Chatter Items to Keep You Current Read More »

Heat Treat Tips: Atmospheres, Gas Chambers, and Thermocouples

One of the great benefits of a community of heat treaters is the opportunity to challenge old habits and look at new ways of doing things. Heat Treat Today’s 101 Heat Treat Tips is another opportunity to learn the tips, tricks, and hacks shared by some of the industry’s foremost experts.

For Heat Treat Today’s latest round of 101 Heat Treat Tipsclick here for the digital edition of the 2019 Heat Treat Today fall issue (also featuring the popular 40 Under 40).

Today’s tips come to us from Nel Hydrogen covering atmospheric solutions and Wisconsin Oven Corporation with a tip on gas chamber issues. Additionally, Pelican Wire provides 4 quick tips on Thermocouples.

Heat Treat Today welcomes you to submit your own heat treat tip for Heat Treat Today's 2020 Fall issue to benefit your industry colleagues. You can submit your tip(s) to karen@heattreattoday.com  or editor@heattreattoday.com.


Heat Treat Tip #11

Compliance Issues? Try On-Site Gas Generation

On-site gas generation may help resolve compliance issues. Growth and success in thermal processing may have resulted in you expanding your inventory of reducing atmosphere gases. If you are storing hydrogen or ammonia for Dissociated Ammonia (DA), both of which are classed by the EPA as Highly Hazardous Materials, expanding gas inventory can create compliance issues. It is now possible to create reducing gas atmospheres on a make-it-as-you-use-it basis, minimizing site inventory of hazardous materials and facilitating growth while ensuring HazMat compliance. Modern hydrogen generators can serve small and large flow rates, can load follow, and can make unlimited hydrogen volumes with virtually zero stored HazMat inventory. Hydrogen is the key reducing constituent in both blended hydrogen-nitrogen and DA atmospheres—hydrogen generation (and optionally, nitrogen generation) can be used to provide exactly the atmosphere required but with zero hazardous material storage and at a predictable, economical cost. (Nel Hydrogen)

Generate H2 and N2 on-site – saving money, improving safety, and reducing carbon footprint.


Heat Treat Tip #12

Oven Chamber Failing the Test? Try This!

When having difficulties passing a temperature uniformity test, check the pressure of the heating chamber. This can be done with a pressure gauge that reads inches of water pressure. The best uniformity is achieved when the pressure is neutral or slightly positive (0” to +.25” wc). If the pressure is negative (even slightly), it can draw a stream of outside cold air into the chamber, causing cold spots. For the best results and ease of analysis, permanently mount a gauge to read the pressure. Any issues with pressure can be easily recognized and corrected. (Wisconsin Oven Corporation)


Heat Treat Tip #70

Type N Thermocouple (Nicrosil / Nisil)

Type N Thermocouple (Nicrosil/Nisil): The Type N shares the same accuracy and temperature limits as the Type K. Type N is slightly more expensive and has better repeatability between 572°F to 932°F (300°C to 500°C) compared to Type K. (Pelican Wire)


Heat Treat Tip #71

Know Your Thermocouple Wire Insulations

Know your thermocouple wire insulations. When is Teflon® not Teflon®? Teflon® is a brand name for PTFE or Polytetrafluoroethylene owned by Chemours, a spin-off from Dupont. FEP is Fluorinated Ethylene Propylene. PFA is Perfluoroalkoxy Polymer. All three are part of the Fluoropolymer family but have different properties. Of the three compounds, PTFE has the highest heat resistance, PFA second highest and FEP third. The higher the heat resistance the more expensive the insulation. Keep that in mind when specifying the insulation and only pay for what you need. (Pelican Wire)


Heat Treat Tip #72

Resistance Temperature Detectors (RTDs)

Resistance Temperature Detectors (RTDs) are replacing thermocouples in applications below 1112°F (600°C) due to higher accuracy and repeatability. Typical constructions are multiconductor cables with nickel-plated copper conductors. (Pelican Wire)


Heat Treat Tip #74

When to Use Type K Thermocouples

Type K thermocouples should only be used with the appropriate Type K thermocouple wire. Type K measures a very wide temperature range, making it popular in many industries including heat treating. An added benefit with Type K is that it can be used with grounded probes, ungrounded probes, and exposed or uncoated wire probes which are attached to the probe wall, measure without penetration, and have a quick response time respectively. (Pelican Wire)


Heat Treat Tip #100

The Right Furnace Atmospheres Will Pay Dividends

Precision blended gas system provides the atmosphere needed at the most economical cost.

Save money on your furnace atmospheres by employing the driest and leanest furnace atmosphere blends possible. Furnace atmospheres are a compromise between keeping it simple and supplying exactly the atmosphere to meet the unique requirements of each material processed. Organizations have different priorities when it comes to atmospheres—heat treat specialists may want to be able to run as many different materials as possible using a limited array of atmosphere types, while captive heat treating operations often want exactly the atmosphere approach to maximize the benefits for their specific processes/products.

The dewpoint (water content) of the atmosphere in the furnace is a key factor in its performance. At high temperatures, water in the atmosphere can break down, releasing oxygen that can cause oxidation. You must maintain a high degree of reducing potential to achieve the surface finish and processing results desired. If the furnace atmosphere gas is wet, you’ll need a gas blend richer with hydrogen than you would if your atmosphere blend had a lower dewpoint (less water vapor content). Since hydrogen costs 10 times more than nitrogen, it is more economical to run a leaner atmosphere than a richer atmosphere. By running the driest atmosphere blend possible, you may find that you can lean down your atmosphere (consistent with the metallurgical needs of your product/process) by reducing the proportion of hydrogen and increasing the nitrogen. In doing so, you may recognize meaningful savings.

Check your furnace atmosphere raw materials and process and obtain the driest atmosphere possible. Control your atmosphere dewpoint by adding humidity as needed to the driest starting blend possible rather than accepting a wet atmosphere and trying to process your parts. You’ll achieve the best compromise of excellent results at the lowest cost. (Nel Hydrogen)


 

Heat Treat Tips: Atmospheres, Gas Chambers, and Thermocouples Read More »

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