Morgan Advanced Materials

A Braze New World: Sending Non-precious Braze Alloys into Space

The space industry is growing fast and is predicted to be worth over a trillion dollars by 2040.

Keith Ferguson, Senior Business Development Manager at Morgan Advanced Materials’ Braze Alloys Business, explains how braze alloys play their part in safe, reliable and sustainable space exploration. 


A Braze New World

The saying goes, “one small step for man, one giant leap for mankind.” This famous phrase uttered by Neil Armstrong is the perfect advertisement for space exploration and its importance to the future.

Less than a century old, space exploration has come on leaps and bounds since the first artificial satellite, Sputnik 1, was propelled into space in 1957. Since then, the world has witnessed marvels such as landing on the moon, the space shuttle program of the 1970s, and the launch of the International Space Station.

The importance of these missions and their subsequent value is immeasurable. Many might not realize on a day-to-day basis how space exploration has improved lives and the global economy to no end. This includes simple weather forecasting, broadcasting TV and radio, predicting natural disasters, monitoring for fertile land, forecasting sea level patterns, and even aiding research in muscular atrophy.

It’s little wonder then that this industry has significant value. The space industry was reportedly worth $384 million USD in 2017, growing at a rate of 7.4 percent. According to Morgan Stanley, it sees the industry growing to be worth $1.1 trillion USD by 2040.

However, there are challenges. Many believe that the millions of dollars and resources used to explore space could be better used on immediate threats to society like clean water, famine, poverty and more. Outside of external opinion though, there are internal operational challenges. Namely, space exploration needs to become safer and more sustainable.

A huge part of solving this challenge is in brazing alloys.

A Brief History on Brazing in Space

In simple terms, brazing joins two metals by heating and melting a filler (alloy) that bonds to the two pieces of metal and joins them. The filler must have a melting temperature below that of the metal pieces.

The use of braze alloys in space equipment is mission critical, as they allow sensors to be mounted as close as possible to engines to measure and monitor output and feed data back to operators. Indeed, they’ve already aided successful missions. Two of Morgan Advanced Materials’ braze alloys, RI-46 and RI-49, were specifically engineered and used by NASA on the Space Shuttle Main Engine, also known as the RS25.

Braze Alloys (Morgan in Space)

RI-46 specifically was developed as a replacement for the existing Nioro braze alloy, which is comprised of 82/18 Au/Ni (gold/nickel). RI-46 contains much less gold, adding in copper and manganese instead. This helped make the braze alloy significantly less dense and provided crucial weight savings, but also still operable from a wide range of temperatures, between -400°F to 1292°F (-240°C to 700°C).

These alloys have not only been critical for past space missions, but also for future missions. RI-46 and RI-49 have been adopted for NASA’s Space Launch System (SLS), a vehicle that is planned to take a crewed mission to Mars.

As alluded to already, developing new braze alloys is as much about performance as well as sustainability.

The Need for Non-Precious Alloys

It needs no mention that space exploration is a costly exercise. According to NASA, the average cost to launch a Space Shuttle is $450 million per mission. The Space Shuttle Endeavour, the orbiter built to replace the Space Shuttle Challenger, cost an eye-watering $1.7 billion USD.

Wire Form Braze Alloys (Morgan in Space)

Bringing costs down is clearly required to keep space missions feasible. One key part of cost reduction is in reducing the use of precious metal braze alloys.

Precious metals like gold and palladium are becoming increasingly scarce. Of course, the cost of producing alloys from these precious metals is also increasing as a result.

However, there can be a reluctance to come away from using precious metal alloys. Years of research, development, and data mean these alloys are tested and reliable. When dealing with missions and equipment that run into the hundreds of millions of dollars and, more importantly, the lives of crew members, reliability becomes an overarching objective, and failures must be prevented.

To solve this issue, Morgan’s Braze Alloys business has been researching and developing non-precious metal alloys over many years. As seen from the RI-46 and RI-49 alloys, these solutions are just as strong as their equivalent high precious-metal counterparts, but at a fraction of the cost.

Non-precious metal alloys can be made from metals like nickel, chromium, and cobalt. Their success has already been seen in the aerospace sector, and now research is being pioneered into making them fit for going into orbit and beyond.

Space, for All to Enjoy

Space travel is not just for highly trained astronauts and public benefit; there is also a growing commercial aspect. Satellite TV and radio have already been mentioned, but billionaire entrepreneurs such as Richard Branson and Elon Musk have also been pioneering private space travel. The hope is that civilians might one day be able to enjoy outer space as well, albeit at potentially high prices.

Achieving this dream is of course hinged on safety and reliability, given that lives will be at stake. The key to improving these factors is being able to place sensors as close as possible to the spacecraft’s engine.

By enabling sensors to be placed near the spacecraft’s engine, mission control and crew can then accurately read and measure data and output. This includes fuel efficiency, temperature, gas flow and monitoring for fire detection or abnormalities. If these sensors are placed too far away from the engines, then data readings become inaccurate and missions can be compromised.

Recent news highlights why sensor technologies are critical, as a two-man space crew had to abort their flight to the ISS after a post-rocket launch failure. The Soyuz spacecraft started to experience failure 119 seconds into the flight, and seemingly, problems were reported by the crew first, not by mission control. The crew described feelings of weightlessness, an indication of a problem during that stage of the flight. Luckily, they aborted, ejected their capsule from the rocket, and returned safely to Earth.

While the cause of the failure is still to be identified at the time of writing, clearly, such a situation should not be happening. Any problems should be picked up by mission control, and not be reliant on crew judgment.

Active Alloys join ceramic sensors to engines. (Morgan in Space)

The challenge though is that some sensors are made from ceramic due to the need to resist corrosion and high temperatures, typically up to 1742°F (950°C ). However, these ceramic sensors then need to be joined to metallic parts of the engine.

This is where “active alloys” come in. Unlike regular braze alloys that join metal to metal, these alloys can join metal to ceramic, or even ceramic to ceramic. Industry standard active alloys like Incusil®-ABA and Ticusil® from Morgan’s range were developed up to 40 years ago but are still in use today. New alloys are also currently in development to withstand much higher temperatures.

A Never-Ending Journey

Morgan Metals and Joining Center of Excellence in Hayward, California (Morgan in Space)

Much like how there is still so much to learn and explore about space, so too is Morgan’s journey with braze alloys. Morgan Advanced Materials is not just committed to making the space industry more sustainable and safer, but it is helping with applications across all industries.

A key pillar of this is through Morgan’s highly specialized Metals and Joining Centre of Excellence (CoE), based in Hayward, California, as well as Morgan’s Brazing Department.

With highly trained researchers and scientists, Morgan’s Braze Alloys business can custom cater alloys to specific applications, run trials to test materials, braze cycles and fixturing. The whole operation, from powder atomization, to preform fabrication and brazing trials, can be looked after from start to finish.

Flexicore® (Morgan in Space)

One of the latest developments being pioneered at the Metals and Joining CoE is Flexicore®. This new technology transforms traditionally brittle alloys (such as AMS4777) into a flexible wire form. In many cases, this will be far superior to pastes in terms of repeatability and ease of use. Along with the operational benefits, Flexicore® will also allow for the use of nickel-based alloys to replace precious-metal alloys. Again, this will help to bring costs down for operators and manufacturers.

Watch This Space

Space travel, as Richard Branson predicts for his own Virgin Galactic programme, is only two or three flights away. We’re truly not far away from entering a new world, and brazing alloys will have their say on how the space industry turns out.

Morgan’s Braze Alloy solutions, like RI-46 and RI-49, as well as others like Palniro-1 and Palniro-7, can already be found across the various programmes and spacecraft. Through more research and development, who knows where this important industry could lead us to.


Morgan Advanced Materials plc is a global engineering company headquartered in Windsor, UK , and is a world leader in advanced materials science and engineering of ceramics, carbon, and composites, engineering high-specification materials, components, and sub-assembly parts to solve challenging technical problems. Markets that Morgan work in include healthcare, petrochemicals, transport, electronics, energy, defense, security and industrial.

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Quartz, Alumina Combine for Innovative Aerospace Castings

A global materials engineering company which designs and manufactures a wide range of high specification products recently released an innovative new material for use in production of turbine engine blades that combines the best of two key materials to improve strength and processing time for the investment casting industry.

The new material, developed by Morgan Advanced Materials, is known as LEMA™. In this Technical Tuesday feature, Eric Larson, Director of Technology and Process Improvement at the Technical Ceramics Business of Morgan Advanced Materials, explains how LEMA™ combines the best aspects alumina and silica (quartz) to provide an effective solution for manufacturers. Content is compiled by Jennifer Kachala, Product Engineer at Morgan’s Technical Ceramic’s business.


Quartz and alumina – the best of both worlds for turbine engine blades

The commercial aerospace industry is on the cusp of significant technological change. High fuel prices, stricter regulations on emissions, and intense competition from low-cost carriers are all driving a quest for more efficient aero-engines and components, where even small advantages can drive major benefits.

Turbine blades are no exception, with a recent report by Market Research Future suggesting that the market for commercial aircraft turbine blades is set to grow at a CAGR of 6 percent by 2023.

Not only is the investment casting industry preparing to meet this demand, but it’s also looking to gain advantages in every aspect of manufacturing, including for the support rods used in the production of turbine engine blades. The two most commonly used materials to cast these are quartz (silica) and alumina.

Both have advantages – and weaknesses. Quartz is the traditional material of choice and has the benefit of being chemically weak and fast to leach, which both accelerates and simplifies production. On the other hand, it is mechanically quite weak which can lead to processing issues and defects during investment casting of difficult metals like super-alloys.

In contrast, alumina rods have about four times the mechanical strength of quartz and are acknowledged for their strength and load-bearing capabilities. However, alumina is so chemically strong it can take several days to fully leach out the material, resulting in longer production times.

While both appear to offer almost opposite properties, they share one common advantage: neither create trace elements which can cause contamination in the process and compromise the quality and performance of parts.

So, neither quartz nor alumina is the perfect material. But what if there was a way of combining the best properties of each to create something new?

The Making of LEMA™

This was the challenge Morgan Advanced Materials set for itself in 2015, resulting in LEMA™, a range of proprietary alumina-based materials that provide double the mechanical strength of quartz while providing significantly improved leaching times, compared with typical high purity alumina.

Like most new inventions, the solution was reached after significant experimentation. The challenge lay in combining two materials and finding the right balance – a complex task, especially as the materials in question were so different.

In search of an answer, Morgan’s laboratories started with a method borrowed from glass science where two distinct phase-separate materials can be used to improve mechanical properties such as toughness or to provide a leaching path through the chemically-weaker glass. In the end an alumina-silicate ceramic was created with a leaching path of silica across the grain boundaries. Particle size distribution and processing parameters were adjusted until the desired mechanical strength was achieved.

Following a period of extensive live testing and refinement, LEMA™ was first introduced to the market in 2017.

Turbocharged Leaching Times, No Loss of Strength

Combining the mechanical properties of alumina with the chemical weakness of quartz, LEMA™ exhibits many unique and valuable properties. It’s almost twice as strong as quartz, and it has a slightly lower thermal expansion coefficient than alumina, which can help with metal leakages sometimes encountered with alumina rods during casting. In addition, LEMA™ is made of pure materials to ensure that the material satisfies the demand for trace element certification.

LEMA™ “crumbles out” when flushed, making it easier to remove during the leaching process. Moreover, like-for-like LEMA™ 250 parts will experience approximately a 20 percent mass reduction after 20 hours (at 300°F [149°C]) and 185 psi). Under the same conditions, a comparable alumina part does not demonstrate any mass loss.

In addition to its advantageous chemical and mechanical properties, LEMA™ also delivers significant commercial benefits. It can reduce investment casting times in turbine engine blades by accelerating leaching by up to 20 percent, solving many of the delays and production challenges which have long been frustrating the global investment industry.

Importantly, as there is less need for autoclave time during the leaching process, manufacturers are spared some of the costly investment in additional equipment. Recognizing the benefits, the industry has already begun to embrace LEMA™; major aerospace manufacturers have used LEMA™ to achieve the desired quality while also reducing costs.

LEMA™ offers a powerful solution for the investment casting of turbine blades, just as the industry is facing an increased demand for these critical components. By bringing together the best aspects of both quartz and alumina, it doesn’t just represent the best of both worlds: it represents a major breakthrough for the industry.

 

Photo credit and caption: iStock / Jet engine turbine (3D xray blue transparent)

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Carbon Science Center to Pioneer Research for Multiple Applications

A global leader in materials science recently celebrated the grand opening of its new multi-million dollar development center which will pioneer research into carbon materials and technologies.

Neil Sharkey, Vice President for Research at Penn State

Morgan Advanced Materials has opened the doors to its Carbon Science Center of Excellence (CoE) research and development facility at Penn State UniversityThe CoE, which is a collaboration between the manufacturer and the university, will focus on carbon-based materials used in a wide range of industries and engineering applications, including aerospace, healthcare, industrial, power generation and more.

Among many projects, the company is working on electrified rail products including carbon current collectors used at the top of train carriages to connect to overhead wires.

“The work undertaken at our facility with Morgan will be truly revolutionary,” said Neil Sharkey, Vice President for Research at Penn State. “The electrified rail carbon strips that Morgan is already working on, for example, will change how train transport works, making it both safer and more reliable, and decreasing downtime. Our partnership with Morgan places us at the forefront of developing new methodologies, in line with Morgan’s mission and values as well as our own. Their existing expertise and insights will help our researchers and students turn new ideas into commercially viable solutions. The Center itself is a huge attraction for other businesses to join the Innovation Park, furthering job creation and economic development in Pennsylvania.”

Located at the Penn State Innovation Park, Morgan’s CoE is close to the university staff, students and facilities. Penn State’s reputation as a world-renowned institution for carbon and materials science-focused research and its collaborative approach to working with business was key when choosing a partner for the project. The partnership brings together resources, experience, and knowledge from both sides, with researchers and scientists on site, many of whom have existing ties to Penn State.

Despite specializing in carbon science materials, the CoE will be utilized by Morgan’s wider businesses and, to date, has also become the home of research projects for the company’s Thermal Ceramics, Technical Ceramics, and Braze Alloys businesses.

“We’re incredibly proud to have launched this ground-breaking Center of Excellence with Penn State,” said Mike Murray, Chief Technology Officer at Morgan Advanced Materials. “It marks an important milestone in both organizations’ history, as we both strive for excellence and understanding of the properties and uses of carbon. With brilliant science minds on our doorstep, we hope the synergies created between us can accelerate our engineering and solutions for our customers, while benefitting more and more industries going forward.”

“Our Centers of Excellence ensure Morgan remains at the forefront of materials development on a global scale,” said Pete Raby, Chief Executive Officer at Morgan Advanced Materials. “In addition to helping us to create world-leading materials, our partnership with Penn State also allows us to recruit some of the best talent in carbon science and provide unrivaled training to our technologists and engineers.”

Photo credit and caption: INVENT PENN STATE / From left to right: Vern Squier, president and CEO of the Chamber of Business & Industry of Centre County; Andrew Goshe, global technical director at Morgan Advanced Materials; Neil Sharkey, Penn State vice president for research; Pete Raby, CEO at Morgan Advanced Materials; Phil Armstrong, CoE lead at Morgan Advanced Materials; and Nick Jones, Penn State executive vice president and provost, celebrate the opening of the Carbon Science Research Centre for Excellence with a ribbon-cutting ceremony. 

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Braze Alloy Service Shortens Lead Time for Medical, Aerospace Components

A global leader in materials manufacturing, headquartered in Windsor, Berkshire, United Kingdom, has recently shortened lead time for its braze alloy service in the U.S., specifically in support of mission critical components used in aerospace, medical and industrial applications.

Morgan Advanced Materials, which manufactures specialist products, using carbon, advanced ceramics, and composites, announced that its Braze Alloys business has enhanced service for customers using its braze alloy solutions. The FTSE 250 company can provide precious and non-precious braze alloys, pre-sintered preforms (PSPs), and braze inhibitors like Stopyt, that prevent the unwanted flow of molten brazing filler metals.

Braze Alloys manufactures braze alloys in configurations that are specific to customers’ requirements. A large number of assemblies that are made using Morgan materials are designed to tight specifications, while the alloys themselves can be developed to suit requirements. Many applications of braze alloys are used in research and development projects and information and data are needed quickly for small-run orders. To facilitate this urgency from contract braze houses, Morgan has created a dedicated resource to handle these inquiries, while reducing lead times on commonly used alloys.

Adam Ebert, Business Development Manager at Morgan’s Braze Alloys Business

“One of Morgan’s strongest competencies is its superior materials research and development. This is a key reason for why our braze alloys are so popular and trusted,” said Adam Ebert, Business Development Manager at Morgan’s Braze Alloys Business. “We’re keen to continue delivering our knowledge and our braze alloys in as quick a timeframe as possible. This has seen us reduce our lead times on some of the most common braze alloy products, including our popular Nioro alloys, as well as gold-copper alloys and copper-silver alloys. We’re now aiming for a three-day turnaround on any product across the whole of the US.”

Morgan launched its Metals and Joining Center of Excellence (CoE), located in Hayward, California, in October 2017 to deliver new material science and process solutions.

 

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