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Heat Treat Basics (Video): Steel Metallurgy from MetallurgyData.com #2

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MetallurgyData.com has produced a video series entitled Steel Metallurgy. Preview this episode at –http://www.metallurgydata.com/index.php/metallurgy-for-non-metallurgists-2/steel-metallurgy/. The preview runs under 4 minutes with the full video being just over 19 minutes long. The full video can be purchased for $4.99 from www.metallurgydata.com.


This is the second in a series of blogs titled ‘Metallurgy for the Non-Metallurgist’. The first blog looked at materials (https://www.heattreattoday.com//2016/08/metallurgy-for-non-metallurgists-from-metallurgydata-com/). In this second post we will look at the fundamentals of steel metallurgy.

Steel is primarily iron with up to 1% carbon, plus other alloying additions (generally totalling less than 5%).

A steel composition can be thought of as a recipe; different amounts of each ingredient make up your final product. In steel these ingredients are known as alloying additions and can affect the steel in different ways. We can affect the:

Properties of steels.
Properties of steels.
  • strength
  • hardness
  • toughness
  • ductility
  • fatigue
  • formability
  • machinability
  • weldability, and
  • corrosion resistance.

The addition of carbon to iron is probably the most important addition in steels which makes ‘The Iron Carbon Equilibrium Diagram’ very useful. Equilibrium means that enough time has been allowed on heating and cooling for any reactions to fully complete.

iron-carbon-diag-cropped
Typical Iron Carbon Diagram

In a steel <723°C, different structures are present and depending on the carbon content we can have at <0.8% Carbon – ferrite and pearlite, at 0.8% carbon – pearlite and >0.8% carbon – pearlite and cementite.

While the iron carbon diagram describes the structures of steel under equilibrium conditions, two further diagrams can be used when faster cooling rates are used; these are the CCT (continuous cooling transformation) diagram and the TTT (time temperature transformation) diagram. Both of these diagrams are helpful in selecting the optimum steel and process parameters.

When we cool a steel at faster cooling rates we can achieve additional structures, these can be bainite and martensite. CCT and TTT help determine the structures achieved.

In metallurgy the hardenability of a steel is a key parameter and when we talk about hardenability in steels we are often describing how deep into the steel we can achieve hardening. If a steel is described as having a low hardenability this will mean that the steel will produce a shallower depth of hardness. Hardenability is not to be mistaken for hardness; when describing the hardness we are often looking at the microstructure achieved during cooling. For a given steel it can be assumed that the quicker the cooling rate the greater the chance of achieving a harder structure and if that steel has a high hardenability this hard structure will be present deeper into the thickness.

In metals there are atomic defects called dislocations, these dislocations reduce the strength of the metal. The principle of strengthening mechanisms is to reduce the ability of these dislocations to move through the metal, this can be achieved by:

Atomic dislocations within the metal potentially reduce the metal's strength.
Atomic dislocations within the metal potentially reduce the metal’s strength.
  • Grain Size; the grains can interact with the dislocations preventing further movement. If we reduce the grain size we can increase the number of grains interacting with the dislocations, preventing movement and thus strengthening the metal.
  • Cold work introduces a large amount of strain into the metal; this strain interacts with the dislocations strain field, impeding the movement of the dislocations.
  • Solid solution strengthening is applied when we add other chemical elements to a metal. Addition of these elements can either be called interstitial or substitutional solid solution strengthening and will cause distortion in the atomic structure, restricting the dislocation movement and strengthening the steel.
  • Dispersion or precipitation strengthening is highly related to the structure of the metal and takes place when a phase is finely precipitated through a softer matrix. This precipitate acts as a barrier to dislocation movement.

The next in the series will be Steel Making and Casting.

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Heat Treat Basics: Metallurgy for Non-Metallurgists from MetallurgyData.com #1

Guest post by www.MetallurgyData.com

This is the first in a series of blogs titled Metallurgy for the Non-Metallurgist, in this first blog we will look at materials.

Engineering materials can be divided in to 4 key areas, Metals, Polymers, Composites and Ceramics.

Metals – Metals are the widest used of the four materials. Even if a material is not made of metal, metal will have been used at some point during its manufacture.

Metals can be divided into two sub groups; ferrous and non-ferrous. In ferrous metals the main constituent is iron and this group consists of steels and cast irons. Considering the amount of strength that is achievable in steel and cast irons, it is a cheap material. This is because iron is one of the most plentiful elements in the earth’s crust.

Non-ferrous metals include any other metals, some examples include aluminum, copper, zinc, titanium, and nickel.

Metals can be strengthened by adding more than one metal together such as copper and tin to make bronze. In this example the two combined have far greater strength than each of the individual metals (the sum is greater than the parts). We can also change the properties of metals by adding non-metallic elements like carbon.

When we produce steel we use the same principle as bronze, we take one element iron, which is the bulk of all steels and add another chemical element (alloying addition), these could include carbon, manganese, nickel, copper, molybdenum, boron, chromium, niobium, titanium, vanadium. In this way we can tailor a steel to a specific application.

When we add alloying additions to the metal it distorts the atomic structure, this makes it more difficult for the atoms to move around and makes the metal stronger. Depending on the type and amount of an alloying element we can make a metal much stronger.

Polymers – Polymers are widely used in many different industries and can be natural (wool, silk, natural rubber) or synthetic (synthetic rubber, nylon, polystyrene).

Plastics are probably the most used polymer and are made up from hydrogen and carbon (hydrocarbons). These are a by-product from the petroleum industry and due to this they are an abundant, and therefore a cheap material.

The carbon and hydrogen which make up the plastics are the key to how they work, because these can form together to produce long chains, this enables plastics to be versatile and easily processed.

Composites – A composite is a combination of two or more materials and consists of a binder and a reinforcement. They have been used for centuries in the form of concrete, and in Roman text from 25BC different aggregates are discussed for use in lime mortars. In 1853 steel bars were first added to concrete making one of our widest used composites: reinforced concrete. In concrete, cement is the matrix and the stone or aggregate is the reinforcement.  The other main composites are fibre glass and carbon fibre.

Ceramics – Ceramics have been used for thousands of years and the most common two are glass and clay. Clay was the first material that we learnt to transform into another state using fire. This was done about 29000 years ago when clay was formed into decorative figures. Much later clay was used to form items like jugs and bowls.

Glass which is mainly made from sand, was mastered by the Romans who unlocked the secret of blown glass by mixing it with minerals. The Romans were the first people to use glass for windows.

MetallurgyData.com have produced an ‘Introduction to materials’ Video – to view this free video visit – http://www.metallurgydata.com/index.php/metallurgy-for-non-metallurgists-2/introduction-to-materials/

The next series in this blog will be ‘Steel metallurgy’.

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