harb nayar

Fueling Efficiency: Retrofit Heat Treat Furnace with Combustible Burner Technology

The automotive industry is going electric — electric vehicles are a popular choice for consumers. To continue sustainable efforts for a healthier planet, heat treaters need to seriously consider energy recovery technologies for their equipment and processes. In this Technical Tuesday article, Harb Nayar, founder, president, and CEO at TAT Technologies, examines the use of combustible burner technology (CBT), specifically CBT technology retrofitted on conveyor furnaces that utilize some level of combustible produced by synthetic or generated atmospheres, and that have peak temperatures above 1400ºF (760ºC).


Annealing, brazing, and even powder metal (PM) sintering, metal injection molding, and additive manufacturing offer the automotive industry components with the precision to meet their demanding standards. For example, the nature of PM manufacturing produces minimal waste, both from a material and an environmental perspective. But most in-house and commercial heat treaters fail to capture and reuse energy or convert emissions with environmentally unfriendly pollutants by use of efficient and available gas-neutralizing equipment. These devices capture and thermally combust hydrocarbons, carbon monoxide, and noxious gases such as ammonia.

Figure 1. CBT unit (model based on LBT-I unit)

The reality is that rather than just neutralize these emissions, heat treaters can use them to heat their parts, even before preheating. The focus of this article is to examine the use of combustible burner technology (CBT) and more specifically, CBT technology retrofitted on conveyor furnaces for processes that has the following:

Here’s a 20-second video of “dancing” flames exiting a conveyor furnace that is sintering PM parts in a N2-H2 atmosphere at 2050°F (1,000+ lb./hr.). Source: TAT Technologies

Recovering Latent Heat Energy

A typical conveyor furnace found on the shop floor has three distinct zones, a preheat zone, a high heat zone, and a cooling zone. Since it is desirable in these units to have a forward atmosphere flow (toward the entrance end of the furnace and opposite the direction of part travel), combustibles emitted while processing the parts exit at the entrance and are typically burned off before entering the room or exhaust system. Often, flames can be seen burning at the front of the furnace. 

Combustible burner technology, aka lubricant burner technology (LBT), is a thermal technology that was originally developed to address issues in the PM industry (Figure 2). This technology can be supplied with or retrofitted on the front of a conveyor furnace to recover latent combustion energy from combustibles (e.g., H2, CO, CH4) or hydrocarbon vapors (e.g., wax lubricants used for PM parts). The energy can be reused to heat parts before entering the preheat zone. This means that the preheat zone itself can be significantly shortened.  

Retrofit Example — PM Sintering Furnace

PM processing is very specific and often more difficult to adopt compared to other continuous atmosphere furnaces. Given the large percentage of PM parts used by the automotive industry, it offers a good example of how heat treaters can achieve energy and cost savings via energy recovery technology.

A Close Look at the Process

Sintering is commonly performed in continuous atmosphere furnaces. In the sintering process, powder metal is combined with a binder, often solid wax (Acrawax®) or stearate-based lubricants are used in the compaction process to make green parts. Delubrication (aka delube, debindering) then takes place in the preheat section of the furnace. There are three phases during PM sintering:

Typical door-to-door time varies between one to five hours, depending upon the material being sintered.

The most common atmosphere used in sintering processes is N2 with 7–20% H2. In other shops, the atmosphere used is Endothermic gas, which has (approximately) 40% H2, 20% CO, with the balance primarily N2 or dissociated ammonia (DA) with a composition of 75% H2 and 25% N2. In some sintering operations, a mixture of DA and N2 is used.

The atmosphere with all the combustibles travels from the high heat section to the preheat section and finally exits from the front of the furnace where the various pollutants are burned off before entering the exhaust system. The total amount of combustibles varies between 10% and 50% depending on the type of atmosphere and material being sintered.

For example, CBT units have been installed for the delubing of tungsten-based alloy parts prior to sintering in high temperature pusher furnaces.

Capturing Latent Energies

During the PM sintering process, users can capture this latent heat to transfer this energy into the green parts prior to the preheat section. The following are approximations of the latent combustion energy available:

  • H2: approximately 0.1 KW per cubic foot of H2 or 0.35 KW per cubic meter of H2
  • CO: approximately 0.12 KW per cubic foot of CO or 0.4 KW per cubic meter of CO
  • Wax lubricant: approximately 5 KW per lb. or 11 KW per kg of lubricant going into the furnace

How CBT Works

The CBT unit retrofits to the flange of the preheat muffle of the sintering furnace. In its reaction chamber, the furnace atmosphere gases enter from the heating sections carrying the various combustibles. These are circulated in the chamber in which preheated air at 1000–1600°F is introduced through vents in the roof of the chamber (Figure 1).

When the furnace atmosphere and air mix, a combustion reaction takes place with flames being produced over the incoming load of parts that are traveling on the belt towards the preheat section. Heat from theses flames helps vaporize the lubricant and any oils present at a high rate. The lubricant vapors flowing out of the parts are instantly and continuously consumed within the CBT chamber before leaving to enter the exhaust system in the front of the furnace. However, the energy released from the burning lubricants and oil vapors remains, adding to the energy from combustion within the CBT chamber. Enough total heat is generated to heat the parts and the belt to temperature above 930ºF (500ºC) before entering the preheat section. This “recovered” heat energy is essentially free as it is generated from the combustibles and lubricant and oils (e.g., H2 for oxide reduction and lubricant for ease of compaction).

Figure 4. Illustration of the energy generated within the CBT reaction chamber. Parts are moving from right to left. Source: TAT Technologies

Another Case Study Illustration

Energy recovery in a CBT reaction chamber from fully combusting H2 coming from the preheat section of the furnace at a flowrate of 400 CFH (11.3 m3/h) and lubricant coming with the green parts at a rate of 7.2 lbs (3.3 kg) per hour is approximately 235,000 Btu/hr (248 MJ/hr) which is equivalent to an energy savings of approximately 70 KWh of electricity.

Additional Heat Treat Applications

Many other heat treating processes benefit from CBT technology. Some examples follow next.

Annealing often utilizes continuous furnaces.

  • The percentage of H2 in the atmosphere is generally much higher — in some cases 100%.
  • Materials and annealing practices vary from plant to plant.
  • Prior to annealing, the material often has surface oxidation and/or some type of coating (e.g., oils, dry lubricants).
  • The goal is to avoid decarburization and produce an acceptable microstructure, which highly depends on the time/temperature cycle.

Brazing is another thermal process that benefits from CBT technology. 

  • Brazing of most automotive parts is done in either in Exothermic or Endothermic gas or N2-H2 or H2-Ar atmospheres.
  • Materials being brazed are typically low carbon steels or stainless steels. In some instances, other special materials are used.
  • The goal is to have clean, oxide, and soot-free joint surfaces just before the filler metal (commonly copper or nickel-based alloys) melts, flows into the gap between the parts by capillary action, and solidifies producing a homogeneous part.

Summary

Figure 5. Photo shows the main body of a CBT unit. Different product models vary in length and flow capacity, but all produce improvements in product throughput up to 25–50%. Source: TAT Technologies

Heat recovery units like CBT are essential for not only neutralizing harmful furnace gases but oils or other types of organic compounds. This technology allows latent heat energy to be utilized, increasing efficiency and saving energy. Benefits include:

  1. Emission control. Using combustion technology, heat treaters are able to convert potentially harmful pollutants from reaching the exhaust system.
  2. Increased productivity. The technology increases throughput up to 50% depending upon the model used since incoming parts are heated prior to entering the preheat section of the furnace.
  3. Energy savings. The power requirements in the preheat section are reduced and throughput increases up to 50% depending upon the model used.
  4. Improved heat transfer. Parts can be heated to a higher temperature in a shorter amount of time for faster removal of organic materials prior to subsequent reduction of metal oxides.
  5. Decreased unit cost. The energy consumption is lowered and overall cost of parts produced in reduced.
  6. Environmental benefits. Ambient temperature in the front-loading area by 10–30°F is lowered since the burn off flames are significantly smaller. Processes being run are less sensitive to air infiltration in the vicinity of the furnaces.

About the Author:

Herb Nayar
President & CEO
TAT Technologies
Source: TAT Technologies


Harb is an inquisitive learner and dynamic entrepreneur who will share his current interests in the powder metal industry, and what he anticipates for the future of the industry, especially where it bisects with heat treating.


For more information: Contact Harb at harb.nayar@tat-tech.com.



Find Heat Treating Products And Services When You Search On Heat Treat Buyers Guide.Com


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Exo Gas Composition Changes, Part 2: Cool Down and Use in Heat Treat Furnaces

In Part 1, the author underscored the importance of understanding the changes in gas composition through three steps of its production: first, the production in the combustion chamber; second, the cool down of gas to bring the Exothermic gas (Exo gas) to below the ambient temperature; and third, the introduction of the gas to the heat treat furnace. Read Part 1, published in Heat Treat Today’s August 2023 Automotive Heat Treat print edition, to understand what Exo gas is and to learn about the composition of gas in the first step.


Harb Nayar
Founder and President TAT Technologies LLC Source: TAT

As the author demonstrated in Part 1, Exo gas composition changes in its chemistry for heat treatment; this first step is how the gas composition changes when it is produced in the combustion chamber. The composition of reaction products, temperature, Exothermic energy released, various ratios, and final dew point are all factors that need to be considered to protect metal parts that will be heat treated in the resulting atmosphere.

Now, we’ll turn to Steps 2 and 3.

Step 2: Composition of Exo Gas after Exiting the Reaction Chamber Being Cooled Down

The two examples that follow demonstrate how lean and rich Exo under equilibrium conditions change as they are cooled from peak equilibrium temperature in the combustion chamber down to different lower temperatures (Table B). This cool down brings the Exo down to below ambient temperatures to avoid water condensation.

Example 1: Lean Exo Gas with a 9:1 Air to CH₄ Ratio

The first column highlighted in blue shows the composition of the lean Exo gas as generated in the reaction chamber with an air to natural gas ratio of 9:1. The peak temperature as generated in the combustion chamber is 3721°F. The next four columns show how the composition changes when the lean Exo gas is slowly cooled from 3721°F to 2000°F, 1500°F, 1000°F, and 500°F under equilibrium condition. The following key changes take place as the temperature of the lean Exo is lowered from the peak temperature to 500°F:

  1. Hydrogen volume almost triples from 0.67% to 1.97%.
  2. H₂O volume decreases slightly from 19.1% to 17.5%, but still is very high at all temperatures.
  3. Oxidation-reduction potential (ORP) changes as the H₂ to H₂O ratio increases from 0.035 to 0.111. At all temperatures, it is very low.
  4. CO and the CO to CO₂ ratio drop in a big way, making lean Exo from being decarburizing at higher temperatures to being highly decarburizing at lower temperatures.
  5. The percentage of N₂ remains at 70.34 at all temperatures.
  6. There is no C (carbon, i.e., soot) or residual CH₄ at all temperatures.
  7. For all practical purposes, at an air to natural gas ratio of 9:1, the Exo gas as generated is predominantly an N₂ and H₂ (steam) atmosphere with some CO₂ and small amounts of H₂ and CO.
Table B. Air to Natural Gas at 9:1 and 7:1, cooled to various temperatures

Example 2: Rich Exo Gas with a 7:1 Air to CH₄

The column under ratio of seven is highlighted as red to show the composition of the rich Exo gas as generated in the reaction chamber with an air to CH₄ ratio of seven. The peak temperature is 3182°F — significantly lower than that for lean Exo. The next four columns show how the composition changes when the rich Exo gas is slowly cooled from 3182°F to 2000°F, 1500°F, 1000°F, and 500°F. The following key changes take place as temperature of the rich Exo is lowered from the peak temperature to 500°F:

  1. Hydrogen volume almost doubles from 5.58% at peak temperature to 9.91% at 1000°F, and then it drops to 5.70% at 500°F. The overall volume of H₂ in rich Exo is significantly higher than in lean Exo.
  2. H₂O volume decreases slightly from 17.9% to 15.1%, but it is still very high at all temperatures.
  3. Oxidation-reduction potential (ORP) changes as the H₂ to H₂O ratio increases from 0.312 at peak temperature to 0.737 at 1000°F before decreasing to 0.377 at 500°F. Overall, ORP in rich Exo is significantly higher than that in lean Exo.
  4. CO and the CO to CO₂ ratio drop in a big way, making it mildly decarburizing to more decarburizing
  5. The percentage of N₂ remains at 65– 67%, which is lower than lean Exo.
  6. There is no C (carbon, i.e., soot) at any temperature. However, there is residual CH₄ at 1000°F and lower. This increases rapidly when cooled slowly below 1000°F.
  7. For all practical purposes, the rich Exo gas (at air to natural gas ratio of 7:1) generated is still predominantly a H₂
    and H₂O (steam) atmosphere, but with more H₂; hence, it has somewhat higher oxidation-reduction potential (ORP) than lean Exo and a bit higher CO to CO₂ ratio (less decarburizing than lean Exo).

In summary, rich Exo as generated in the combustion chamber differs from lean Exo as follows:

  1. It has a little less N₂ % as compared to lean Exo.
  2. It has significantly more H₂ , but a little less H₂O than lean Exo. As such, it has a significantly higher H₂ to H₂O ratio (ORP).
  3. It is decarburizing, but less than lean Exo.
  4. It has residual CH₄ at temperatures below 1000°F. Therefore, it must be cooled very quickly to suppress the reaction of developing too much residual CH₄.

Discussion

Let us take the example of rich Exo (an air to natural gas of 7:1) exiting from the reaction chamber in Table B (see column highlighted in red). The total volume is 853.3 SCFH and has H₂O at 152.4 SCFH (17.9% by volume). This is equivalent to dew point of 137°F. Its H₂ content is 47.6 SCFH (5.58% by volume). And the H₂ to H₂O ratio is 0.312.

If this were quenched to close to ambient temperature “instantly,” this composition would be “frozen,” except most of the H₂O vapor will become water. Let us assume the Exo gas was instantly quenched to 80°F (3.6% by volume after condensed water is removed). Rough calculation shows that the final total volume of H₂O vapor has to be reduced from 152.4 SCFH to about 26.0 SCFH in order to meet the 80°F dew point goal. This means 152.4 – 26.0 = 126.4 SCFH of H₂O vapor got condensed to water.

Now the total volume of Exo gas after cooling down to 80°F= 853.35 – 126.4 = 726.95 SCFH, or almost 15% reduction in volume of Exo gas as compared to what was generated in the reaction chamber.

Of course, the composition of Exo gas will not be the same as calculated above. The exact composition after being cooled down depends upon the following:

a. Cooling rate of the reaction products from the peak temperature in the reaction chamber to some intermediate temperature, typically around 1500°F.
b. Cooling rate of the gas from the intermediate temperature to the final (lowest) temperature via water heat exchangers — typically 10–20°F below ambient temperature unless a chiller or dryer is installed on the system.

Depending upon the overall design of the generator, especially how Exo gas coming out of the combustion chamber is cooled and maintained during the period of its use, the expected Exo gas composition should be in the range of the light red columns in Table B — where temperatures are between 1500°F to 1000°F — however:

  1. Total volume closer to 727 SCFH (since a major portion of H₂O was condensed out)
  2. N₂ between 74–77%
  3. Dew point between 80–90°F
  4. CH₄. between 0.1–0.5%
  5. H₂ percentage between 7–9%

Step 3: Composition of Exo Gas after Being Introduced into the Heat Treat Furnace

The cooled down Exo gas will once again change its composition depending upon the temperature inside the furnace where parts are being thermally processed.

As an illustration, let us assume the following composition of the rich Exo gas (with a 7:1 air to natural gas ratio) at ambient temperature just before it enters the furnace:

  • Total volume: 727 SCFH
  • H₂: 8% (58.16 SCFH)
  • Dew Point 86°F or 4.37% (31.77 SCFH)
  • CO: 6% (43.62 SCFH)
  • CO₂: 6% (43.62 SCFH)
  • CH₄ : 0.4% (2.91 SFH)
  • Balance N₂ (%)
  • 75.23% (546.92 SCFH)

Table C shows how the composition changes once it reaches the high heat section of the furnace where parts are being thermally treated. The column highlighted blue shows the composition of Exo gas as it is about to enter while it is still at the ambient temperature. The next three columns show the composition of the Exo gas in the high heat section of furnaces operating at three different temperatures depending upon the heat treat application — 1100°F like annealing of copper, 1500°F like annealing of steel tubes, and 2000°F like copper brazing of steel products. The H₂ to H₂O ratio decreases as temperature increases.

Other general comments on Exo generators:

  1. Generally, they are horizontal.
  2. Size ranges from 1,000 to 60,000 SCFH.
  3. Rich Exo generators use Ni as a catalyst in the reaction chamber. Lean Exo does not.
  4. Lean Exo generators typically operate at a 9:1 air to natural gas ratio. There is no carbon/soot buildup.
  5. Rich Exo generators typically operate at a 7:1 air to natural gas ratio. Below about 6.8 and lower ratios, soot/carbon deposits start appearing that require carbon burnout as part of the maintenance procedure.
Table C. Exo gas compositions in heat treat furnaces

Conclusions

A walkthrough of the entire cycle of gas production to cool down to use in the high heat section of the furnace clearly shows that as temperature changes, so does the Exo gas composition for any air to natural gas ratio.

Having a well-controlled composition of Exo gas requires the following:

  • Well-controlled composition of the natural gas used
  • Air supply with controlled dew point
  • Highly accurate air and natural gas mixing system
  • Highly controlled and maintained cooling system
  • A reliable ORP analyzer or the H₂ to H₂O ratio analyzer as part of the Exo gas delivery system.

Protecting metallic workpieces is paramount in heat treating, and in order to do this, the atmosphere created by Exothermic gas must be understood, both in the cool down phase and within the heat treat furnace. For further understanding of the good progress made in the improvement of Exo generators, see Dan Herring’s work in the reference section below.

References

Herring, Dan. “Exothermic Gas Generators: Forgotten Technology?” Industrial Heating, 2018, https:// digital.bnpmedia.com/publication/?m=11623&i=53 4828&p=121&ver=html5.

Morris, Art. “Exothermic Atmospheres.” Industrial Heating (June 10, 2023), https:// www.industrialheating.com/articles/91142-Exothermic-atmospherees.

About the Author

Harb Nayar is the founder and president of TAT Technologies LLC. Harb is both an inquisitive learner and dynamic entrepreneur who will share his current interests in the powder metal industry and what he anticipates for the future of the industry, especially where it bisects with heat treating.

For more information: Contact Harb at harb.nayar@tat-tech.com or visit www.tat-tech.com


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Staying Up to Speed with Sintering Parts and Additive Manufacturing for Heat Treat

OCThe powder metal industry continues to develop to keep up with production and industry needs. What exactly goes on with powdered metals and additive manufacturing? What is the sintering process? What should heat treaters know about the future of this industry?

In this original content article, three different resources -- an article, a radio broadcast, and a Heat Treat TV episode -- come together to answer these questions and much more.


"Heat Treating, Additive Manufacturing, and Serialization."

Ron Beltz
Director of Strategic Accounts
Bluestreak | Bright AM™

In this article, investigate the processes used to treat the metal powders. Sintering is one such process and others, like annealing and hot isostatic pressing, are examined too. Ron Beltz, director of strategic accounts at Bluestreak | Bright AM’s™  takes a look at these processes and also discusses other elements like software use and serialization. "One of the issues of additive manufacturing is the possibility of internal defects," Beltz explains. "Direct metal laser sintering (DMLS) regularly produces near 100% dense parts, but to provide another level of control to help reduce part failure, hot isostatic pressing (HIP), instead of heat treating, is successfully being used by many aerospace companies and in the casting industry."

Harb Nayar
TAT Technologies
(photo source: tat-tech.com)

Heat Treat Radio #36: "A Discussion with Harb Nayar, Sintering Guru."

Contact us with your Reader Feedback!

Hear from Harb Nayar, president and CEO, TAT Technologies; as he peers into the future of the industry; "The other [change in industry] I think that’s going to emerge is most probably making more and more parts by powder metallurgy from metal powder which are 100% free alloyed." Nayar is confident that the powder metal industry will keep growing, and this interview gives good insights from his depth of knowledge.

Heat Treat TV: Press-and-Sinter Powder MetallurgyHeat Treat TV episode: "Press-and-Sinter Powder Metallurgy."

John Engquist, FAPMI (past president of the Center for Powder Metallurgy Technology), gives some practical basics on what powder metallurgy (PM) is and how sintering helps produce automotive components. "Let's take a look at some PM applications: here we have a notch and pocket plate that are used in one way clutches. . . .made from sinter hardened steel and iron carbon steel. Here we have an automotive planetary carrier system. . . .Here we see stator cores for electric motors . . . ." Listen in on ways to use powdered metal.

These thought-provoking pieces give an opportunity dig a little deeper into sintering and additive manufacturing. Stay on top of education and developments within the powder metal industry.


Find heat treating products and services when you search on Heat Treat Buyers Guide.com


 

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Heat Treat with New Techniques: Using Micro-Ingots in Steel Production

Source: Powder Metallurgy Review

Railroad wheel bearing from AISI 8620 steel (photo source: “Powder Metallurgy Review)

Many of you are likely to have heard Harb Nayar, president of TAT Technologies, LLC, expert in all things sintering, explain innovative ways to produce heat treated products. But perhaps you are wondering, how would “atomised prealloyed steel particles,” that is micro-ingots, work within the realm of heat treat?

This Heat Treat Today Best of the Web feature is pulled from a powder metallurgy (PM) whitepaper in which Harb Nayar describes the PM background, processes, and application in more detail. Read his detailed whitepaper, “The micro-ingot route: A variant of the PM process that could offer new opportunities for the PM industry,” on the web, or download the free PDF.

An excerpt: “This micro-ingot approach, when combined with newer heat treatment technologies, can lead to a redesign of the current macro-ingot products that can potentially help to reduce the weight of the finished product resulting in a longer product life span.”

Read More: “The micro-ingot route: A variant of the PM process that could offer new opportunities for the PM industry,” Powder Metallurgy Review, Autumn/Fall 2020, Vol. 9 No. 3, pages 81-87.

 

 

Heat Treat with New Techniques: Using Micro-Ingots in Steel Production Read More »

2020 Heat Treat Themes for Intellectual Fitness

What have we learned these past six months? Well, for starters, everyone misses being face-to-face! Yet many heat treaters have taken this time to be flexible and innovative, building their intellectual fitness, so to speak.

This article, a Heat Treat Today Original Content piece, highlights some of the major themes which digital opportunities provide to heat treaters. You may note that some of these opportunities are still being offered; please reference company websites to confirm.


“COVID-19 came along… [but] it forced me to look into other projects which may be even more interesting. And I decided to build my intellectual property.”

-Harb Nayar, president of TAT Technologies, LLC on Heat Treat Radio

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Signs of life pre-April 2020 seem to be coming back, though many people are still reckoning with the work constraints. This past quarter, and even into Q3, heat treaters have seen a remarkable initiative to make learning online available. Heat Treat Today did a select study* of what a few of the most recent, heat treat specific events had to offer. The results of the examination demonstrates trends in the types of themes which heat treaters can improve their “intellectual fitness.”

Summary

A few themes stick out as key content: the fundamentals, quality control, additive manufacturing (AM) and 3D printing, and maintenance concerns.

source: Heat Treat Today

These themes were made available to heat treaters in the form of three main presentations: session or lecture format; panel discussion; round table. All platforms engaged in some form of online sessions which colored more lecture/seminar styled with scholarly professionals to addresses given by industry leaders or technical insiders. Larger, lengthier events, such as Furnaces North America and SECO/WARWICK’s e-Seminar incorporated panel discussions in addition to single-speaker sessions. Truly unique was the announced “round table” access at the Ceramics Expo Connect’s session on September 24th, “How to Improve Your Ceramic Products Material Properties Through Raw Material Optimization?”

Within these structures, a few presenters took advantage of the digital opportunity to offer case studies and live demonstrations of certain methods and processes. At the e-Seminar, multiple opportunities for this included “Symptoms of a Burner Issue – How to Solve It” and “Revealing the Secret of Carburizing,” while Buehler’s Wilson Hardness Days (WHD) event promises “live demonstrations of DiaMet software.” Only a few of the events examined offered the opportunity to submit questions before the presentation occurred. Many sessions in this online forum were pre-recorded well in advance, so this might contribute as to why soliciting questions before the presentations wasn’t as widespread.

Four Themes of 2020

The Fundamentals

This one is not surprising. “The Fundamentals” refers to any overview, back-to-the-basics type of session that hits major ideas in the industry which might refine practices, but does not challenge or recreate heat treating theory/practice. An example of this is the technical session on day one of the FNA: “The Importance and the Proper Way to Monitor Polymer Quenches” to be given by Keisuke Kuroda of Idemitsu Lubricants America.

Hubbard-Hall’s webinar on cleaning titled “Optimizing Cleaning in Heat Treat Processes” promised to cover “the influence of contaminations in different heat treatment applications,” something that may not be as exciting as nitrogen gas quenching, but is still essential to know. At WHD, the event notes that “Machine Calibration and Servicing” will be a guaranteed part of the webinar on hardness testing.

Quality Control

Not to be confused with “The Fundamentals,” this theme encapsulates topics about implementing new theory and improving or refining current practice.

At the Ceramics Expo Connect, a session on “Powering a Mobile Future: The Role of Ceramics in Taking Solid State Batteries from Theory to Practice and Improving Lithium Ion Models” demonstrated this theme. If you attend the e-Seminar, you may have heard the panel “Maintenance in the Age of Industrial 4.0 Description,” which also falls into this theme. At a more particular level, Buehler will introduce the new Rockwell Tester at their event.

Additive Manufacturing and 3D Printing

At the cutting edge of industry development, these young applications in the heat treat world have been getting a lot of attention, with other forward-thinking topics on the horizon as well (like IoT and Industry 4.0). Buzz a constant buzz of these processes were apparent, particularly in the FNA 2020 schedule.

One of the technical session at FNA 2020 will be given by Dan Herring, the Heat Treat Dr., titled “Will Additive Manufacturing Add or Take Away Heat Treating?” At the e-Seminar, “3D Printing—Revolution or Evolution” was the title of one provocative panel discussion.

Maintenance

This is another big theme, and rightly so: maintenance concerns can cause problems with the heat treating process which could result in poor results, or dangerous outcomes.

FNA 2020 will be dealing with maintenance questions a lot over the next few days. On a micro-scale, Hubbard Hall’s webinar will be addressing these questions: “How closed cleaning machines contribute to cost efficiency and sustainability” and “How companies overcome specific cleaning challenges.”

Other Themes

“Troubleshooting” and “adapting to COVID-19” also stood out as recurring themes, though many sessions were concerned with these in relation to quality and future planning. Additionally, “COVID-19” in particular was considered during multi-day events as it related to pivoting one’s business strategy whereas single-day events focused on topics which are periphery to COVID-19 like “supply-chain” and “future of heat treat.”

Ok, But Does This Mean Anything?

Heat treaters are adaptive, responding to changes. But beyond picking up the latest item on the block, heat treaters want to make sure that their operations are reliable and excellent, hence the heavy focus on “The Fundamentals” and “Quality Control.” Testing new ideas and refining maintenance strategies are implemented, but it seems that this is typically after heat treaters know that they are performing with excellence in their day-to-day.

 

 

Further information on these events can be found on the company websites.

*The study focused on five of the most well-publicized and widely circulated events in the heat treat industry in August and September of 2020. The study is not meant to be exhaustive, but rather a case study of trends which may serve to be indicative of larger trends in the heat treat industry.

 

 

2020 Heat Treat Themes for Intellectual Fitness Read More »

Heat Treat Radio #36: A Discussion with Harb Nayar, Sintering Guru

Welcome to another episode of Heat Treat Radio, a periodic podcast where Heat Treat Radio host, Doug Glenn, discusses cutting-edge topics with industry-leading personalities. Below, you can either listen to the podcast by clicking on the audio play button, or you can read an edited version of the transcript. To see a complete list of other Heat Treat Radio episodes, click here.

 


In this conversation, Heat Treat Radio host, Doug Glenn, interviews Mr. Harb Nayar, president and founder of TAT Technologies LLC. Harb is both an inquisitive learner and dynamic entrepreneur who will share his current interests in the powder metal industry, and what he anticipates for the future of the industry, especially where it bisects with heat treating.

Click the play button below to listen.


The following transcript has been edited for your reading enjoyment.

Harb Nayar (HN):  My name is Harb Nayar.  I am the president of TAT Technologies, LLC.  It is a very small 10 year old company that focuses on powdered materials and processes, especially sintering.

Doug Glenn (DG):  This experience you've had with powder metals stretches over 50 years.  I understand that people recognize you as “the sintering guru” for the value that you've brought to the industry.  Can you share what intrigued you about the powder metal process and the powder metal industry that began your lifelong interest?

Harb Nayar at TAT Technologies (photo source: tat-tech.com)

HN:  There is no doubt that PM (powder metallurgy) is a very, very unique manufacturing process to make metallic products.  If I have to pick one thing that I would say which is almost becoming a destructive technology in the manufacturing of complex shapes (metallic products), that would be additive manufacturing using metal powders to start with.  And you may ask why it's destructive.  The answer is relatively short and simple.  That it takes a totally different way of manufacturing.  You are adding layer by layer to build a 3-dimensional component and therefore you can make unusual designs and unusual complex shapes out of it.  The PM is used to make 2-dimensional and 3-dimensional parts for a very long time, but this one can make 4 dimensions.  Now you may say there are only 3 dimensions, where are you coming up with the fourth one?  Well, in my opinion, the fourth one in this case is emptiness.  In other words, it can create design.  Within the solid, you have empty spaces, so to speak, and that is what I call the fourth dimension.  This is where the major benefit will be to reduce weight.

Now, to really give you how much design flexibility there is, I'll give a very simple example.  Suppose you are trying to make this one piece, or many pieces, of a globe of the whole world, but you want it to be stainless steel.  And you want to make it in one piece with no welding, but you want to show the hills and the valleys and the ocean and everything else, and you want to keep the interior of this globe empty to keep the weight light.  You can only do this by additive manufacturing and to the best of my knowledge, there is no other way to make it.  That is where I'm emphasizing the fourth dimension – the emptiness.

DG:  Yes.  And now this would have a pretty significant influence on both the aerospace and the automotive industries where lightweighting plays a key role.

HN:  I think lightness, just as in the cellphone business or the semiconductor business where things became smaller and smaller, in the product line it's going to be, can we make it lighter and lighter, if for no other reason than to use less material to begin with.  The other one I think that's going to emerge is most probably making more and more parts by powder metallurgy from metal powder which are 100% free alloyed.  In other words, all the elements are in each metal powdered particle.  In other words, you're starting with a micro ingot as opposed to a big ingot that you normally use to make bars, and then from bars you cut pieces, and then from those pieces you do hard forging or machining.  But here, you will be starting from the other end where each powdered particle now is a micro ingot and the challenge is how you take billions of these micro ingots and make a 20 lb. part out of it.  That’s the other thing that most probably is going to start picking up.

Students taking a hands-on course with TAT Training Center (photo source: tat-tech.com)

Especially the low alloy steel parts.  My personal feeling is that a lot of technology, although it has already been developing, but, it will develop much more rapidly in the next 10 years.  That is where the role of the heat treat people will be actually much bigger, because by doing a heat treat, you can always make an alloy or a material more strong, so to speak, as that's the main function of heat treat.  But in the low alloy steels, the reason you are adding alloy is so that it's more conducive to heat treatment.  Certain alloying elements help you to strengthen the material more than certain other elements.  I think the powder metallurgy technique, each micro ingot is uniformly alloy, where when you start with a big billet, it's not uniformly alloyed.  I think that the role of the PM would be to reduce those dimensional, (like mechanical properties in 3 dimensions are different if you're making something that originally was cast as a billet), where in the metal powder particle, because the distance is so small in each particle, each element is much, much more uniformly dispersed.  And also, there are no stringers that you normally get when you're casting, let’s say, a 7” diameter bar or a 15” square bar, out of which you then make other things.  Not only will the alloys be more uniformly distributed in the micro ingot, but there will be no stringer type of impurities.

DG:  So then, Harb, what is your prognosis for the future of the industry looking forward?

HN:  That is an unusually good question, and also a very complicated question.  But I can make three or four general statements.  One is that powder metallurgy is going to continue to grow.  A lot of people will take issue with me, but in my opinion, with additive manufacturing coming in and with these other developments that I mentioned, in the last 2 – 3 years it has been below 6% growth rate.  It used to be 7 -8% and it began to flatten out a little bit.  I think that AM and this other micro ingot approach, I think that it will swing back to 7, 8 or 9% growth by the middle or latter part of this decade.  And all these changes that are coming will affect heat treat.  The way I see it, in heat treat, the changes will be based on two things: what are they heat treating right now?  For example, if they're heat treating almost exclusively from macro ingots and now they have to worry about the micro ingot type of products, obviously heat treat has to shift somehow.  The second one: how is being heat treated right now?  That's where I feel that oil will be going down and other quenching techniques most probably will be coming up.  Part of that will be influenced by as the PM makes inroads into machine parts or hard forged parts using macro ingots.  The micro ingot will somehow affect the heat treat.

DG:  So those will be the main things: that PM will continue to grow and elimination of oil.

HN:  Well, the PM will continue to grow, but that will then affect the heat treat industry, yes.

DG:  Harb, could you tell us how you got interested in powder metallurgy, and also how you came to be known as the 'sintering guru' in the United States?

The Delhi Iron Pillar (photo source: Harb Nayar)

HN:  Well, it all started when I watched an American movie at 17 years old, in India, in English of course.  At the age of 18, I came to study at Rensselaer Polytechnic Institute in Troy, NY in mechanical engineering.  When I went back to India, I happened to see a monument that's called Delhi Iron Pillar.  I was born in Delhi, I had seen it, but it never impressed me that much.  But when I read the story behind it, that it was made by starting with iron oxide powders, and that got converted into a sponge iron and then sponge iron was hot forged into this 14 ton structure.  It is the largest part known to be made by powder metallurgy and was made around 14 centuries ago and it still has not rusted.  So with all the story behind it, there are still some mysteries behind it, but the main thing is that powder metallurgy impressed me.  It changed my course.

DG:  In fact, seeing the Delhi iron pillar did change Harb's life course.  He went back to school and studied sintering and earned a master's degree in metallurgy at Notre Dame University.  Then he poured himself into the practical, returning to Rensselaer Polytechnic Institute, where he earned his PhD.  Shortly thereafter, Harb worked in a research lab for Copper Range Company where he researched the possibility of making copper strip directly from powder, as opposed to casting it from molten copper.  Unfortunately, that research project never grew legs.  His next employment, however, did bear fruit.  After Copper Range, Harb moved to New Jersey, and here's what happened.

HN:  So after working for Copper Range, I went to New Jersey and worked for an industrial gas company.  It was called Airco Industrial.  It was well known for making nitrogen, oxygen, hydrogen and many, many other gases.  When I was hired, they had no powder metallurgy activity of any kind.  So my first assignment was, can the powder metallurgy be used to be make electrodes, welding rods, etc, because Airco also had a welding products division.  I then did make hardfacing rods and welding rods by powders.

DG:  Although the welding products division was sold, Harb found a new home at Airco researching and developing synthetic gases.  Remember, in the early 70's, there was the energy crisis and a concern that there would be a shortage of industrial gases.  During his time at Airco, Harb was one of the early developers of synthetic gases, or what might be more commonly known today as mixed gases.  After Airco, Harb took some extended time off to raise his young daughters after the untimely passing of their mother.  After the daughters were out of the house, Harb wondered what he should do with himself.  TAT Technologies, the company he currently owns and operates, was just the answer.

Harb, tell us a little about what you're currently doing with TAT Technologies.

HN:  TAT stands for Temperature Atmosphere Time Technology.  Whatever my thermal processing background was, I decided to work on that, but focus only on powder metallurgy to start with, not all the other thermal processes.  In other words, start with sintering to begin with.

I opened a school to teach sintering, just like I learned when I left and came from India.  I started teaching sintering but did it hands-on; not just lectures, but hands-on.  So, I bought a sintering furnace for testing equipment and opened my own lab in 2012.  We started with education and training, then added some R&D to it, then developed equipment that can help to increase the production rate in sintering furnaces by as much as 30 – 40% in existing furnaces.  Slowly, we would begin to work with a very small number of people and that's what we've been doing until 2019.  Then, of course, in 2020, COVID-19 came along.  Just like in the 70's, the bad time, at least it appeared to be a bad time anyway, that there was a natural gas shortage, that gave the birth to Synthetic Atmospheres.  That was my silver lining then.  My silver lining this time is that it forced me to look into other projects which may be even more interesting.  And I decided to build by intellectual property.  So since then, I've received one patent, two are already applied for, two are in the process, and another four or five are waiting in line.

Students engaged in hands-on learning at TAT Training Center (photo source: tat-tech.com)

My future now is in two directions: One is to continue with what we became very good at until 2019 and make it go further, and the other is to, hopefully, develop this new project and figure out a way of commercializing them.  I believe in the old theory “that one in hand is better than two in the bush,” I change it to “keep the one you have in the hand the best you can, and still go after the two in the bush.”  This is what has evolved because of COVID-19.

DG:  Let's stick with TAT for just a moment.  Where do you see it going in the future?

HN:  There are three activities that we plan to pursue based on the patents that are issued or are being issued.  One is a project which promotes production of low alloy steels by powder metallurgy.  I believe there is a very big future in that.  In other words, how to bring out the better properties of a micro ingot compared to a big ingot and how to translate that into better products which require less energy and will cost less to manufacture.  Right now they are being manufactured in one way or another by either machining or by taking a billet, chopping it down to small pieces and then doing hard forging.  I plan to make the starting material, from my hard forging using low alloy steel, would be powders as opposed to a preform that originally was cast somehow somewhere.  That's my one project.  And that will affect heat treat quite a bit.  Presently, most of the heat treat is done on parts which are really made by the big casting approach, ingot casting; these bring all the imperfection from the casting into the final product which is then heat treated.  My question is that if the product was much more uniform, then it may develop somewhat different heat treat approaches and it most probably will reduce, if not eliminate, oil quenching.

DG:  So, why the elimination of oil quenching?

HN:  There are two reasons.  One obviously is just safety as oil tends to catch fire, but the main reason is that if you can distribute the alloys more evenly, there is a high probability you need less total amount of alloying element, which will give you a similar mechanical property because it doesn't have some of these irregularities.  Now that “most probability low alloy steel” with even a lower amount of alloying is going to be more conducive to faster quenching.  In powder metallurgy – gas quenching is already used after sintering – they call it sinter hardening.  In my opinion, heat treat will have to somehow modify its practices to deal with if the same forged product is really made from micro ingots as opposed to a macro ingot.

DG:  Very interesting.  So that is one prospect of three.  What is another one?

Student learning at TAT Training Center (photo source: tat-tech.com)

HN:  In the additive manufacturing, there are two weak points there, that's why it's not taking up as quickly, commercially, I'm talking, R&D, the money, the research, is going at a very high rate, but the actual production where you can see a part going in the automotive is not there yet.  The reason is the shaping process – layer by layer – is somewhat slower.  They have to speed it up quite a bit in order to make it what I call mass production.  That's one, at the moment, still a bottleneck.

The second one is a bottleneck that they are not addressing yet because they feel they have to take care of the other bottleneck first, and that is because wherever there will be high volume of additive manufacturing, there the green part will have some binder in it.  That binder has to be removed prior to sintering.  Therefore, I am going to be focusing on binder, and start getting ready within a couple of years, for mass debinding.

Right now, the debinding is done in small batches only.  I'm going to be ready for production on a mass scale when the shaping people start making the green parts faster.  And it's much more challenging than the debinding in the conventional powder metallurgy because there the amount of binder, or what they call lubricant, by volume is less than 10%, whereas in the additive manufacturing, wherever they use the binder, is always much more than 10%.  That makes it a bigger challenge to get rid of it.  I already have an expertise in how to get rid of the binder in the conventional part of metallurgy, so I will use my dad’s know-how as a stepping stone to develop, what I call mass production, debinding operation.  That's my second project.

The third one came directly out of COVID-19.  I cannot get into it because there are still some patent issues involved here, but I want to replace N95, which is made from what's called unwoven polymer, and I want the filtering portion to be metallic.  That would be my dream project.

DG:  Any last messages for our listeners?

HN:  We are not doing it, but we are open to it, and that is because your main listeners are heat treaters, so I'm open to them – that my background is furnaces and atmospheres and temperature – to anyone if they have problems to reduce the atmosphere cost, let's say.  Or they want to increase the productivity of their furnaces, they could reach me and once I understand their need, I will be willing to work with them on how to accomplish those two goals: cost reduction, atmosphere reduction and the third will be energy production.  I have a pretty good background in all of those three areas when it comes to thermal processes in general.  Even though my focus right now is on sintering, that does not mean I cannot get into annealing or brazing or heat treating or tempering, and so on.

DG: Thanks for taking the time to talk to us, Harb.

HN: Thanks Doug

 

You can reach out to Harb Nayar by email at harb.nayar@tat-tech.com or at www.tat-tech.com.

 

 

Doug Glenn, Publisher, Heat Treat Today
Doug Glenn, Heat Treat Today publisher and Heat Treat Radio host.


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